1,1'-diadamantane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub113.8 ± 1.4kJ/molMEKarpushenkava, Kabo, et al., 2007Based on data from 393. to 443. K.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
109.1 ± 1.3417.8MEKarpushenkava, Kabo, et al., 2007Based on data from 393. to 443. K.

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference
70. ± 10.561.ACKarpushenkava, Kabo, et al., 2007

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

1,1'-diadamantane = 2,2'-diadamantane

By formula: C20H30 = C20H30

Quantity Value Units Method Reference Comment
Δr4.64 ± 0.50kJ/molEqkSlutsky, Engler, et al., 1973liquid phase; solvent: Cyclohexane

2,2'-diadamantane = 1,1'-diadamantane

By formula: C20H30 = C20H30

Quantity Value Units Method Reference Comment
Δr4.64 ± 0.50kJ/molEqkSlutsky, Engler, et al., 1973liquid phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Karpushenkava, Kabo, et al., 2007
Karpushenkava, Larisa S.; Kabo, Gennady J.; Bazyleva, Ala B.; Blokhin, Andrey V.; Kabo, Andrey G.; Zaitsau, Dzmitry H.; Pimerzin, Andrey A.; Sarkisova, Viktoria S., Thermodynamic properties of 1,1´-biadamantane, Thermochimica Acta, 2007, 459, 1-2, 104-110, https://doi.org/10.1016/j.tca.2007.03.018 . [all data]

Slutsky, Engler, et al., 1973
Slutsky, J.; Engler, E.M.; Schleyer, P.v.R., Equilibration of biadamantane isomers, J. Chem. Soc. Chem. Commun., 1973, 685-686. [all data]


Notes

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