Benzene, hexafluoro-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-1015.kJ/molSemiStewart, 2004 
Δfgas-956.0 ± 1.2kJ/molCcrCox, Gundry, et al., 1969ALS

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-991.7 ± 1.2kJ/molCcrCox, Gundry, et al., 1969ALS
Quantity Value Units Method Reference Comment
Δcliquid-2041. ± 8.4kJ/molCcrKrech, Price, et al., 1972ΔEr=-489.0 kcal/mol; ALS
Δcliquid-2443.6 ± 1.2kJ/molCcrCox, Gundry, et al., 1969ALS
Quantity Value Units Method Reference Comment
liquid280.79J/mol*KN/AMesserly and Finke, 1970DH
liquid279.91J/mol*KN/ACounsell, Green, et al., 1965DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
225.03298.15Wilhelm, Lainez, et al., 1987DH
222.0300.Gorbunova, Grigoriev, et al., 1982T = 280 to 353 K. Data also given by equation.; DH
221.6298.15Gorbunova, Simonov, et al., 1982T = 280 to 680 K. Data calculated from the equation: Cp(liq) (kJ/kg*K) = 1.19132 - 1.0716x10-3T + 3.59x10-6T2.; DH
221.3298.76Gorbunova, Simonov, et al., 1982, 2T = 284 to 350 K. Value is unsmoothed experimental datum. Cp (298.76 K) given as 1.1892 J/g*K.; DH
221.58298.15Messerly and Finke, 1970T = 13 to 342 K.; DH
221.58298.15Counsell, Green, et al., 1965T = 10 to 310 K.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil353.4 ± 0.3KAVGN/AAverage of 10 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus278.2 ± 0.2KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple278.30KN/AMesserly and Finke, 1970, 2Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple278.14KN/APaukov and Glukhikh, 1967Crystal phase 1 phase; Uncertainty assigned by TRC = 0.15 K; TRC
Ttriple278.25KN/ACounsell, Green, et al., 1965, 2Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Tc517. ± 1.KAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Pc33. ± 3.barAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Vc0.3351l/molN/ADouslin, Harrison, et al., 1969Uncertainty assigned by TRC = 0.0017 l/mol; TRC
Quantity Value Units Method Reference Comment
ρc2.958mol/lN/AHales and Townsend, 1974Uncertainty assigned by TRC = 0.0029 mol/l; Liquid density determined by magnetically balanced float up to 490 K, see J.L.Hales, 1970-128. Critical D by equation due to Riedel.; TRC
ρc2.65mol/lN/AMousa, Kay, et al., 1972Uncertainty assigned by TRC = 0.0264 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap35.9 ± 0.6kJ/molAVGN/AAverage of 9 values; Individual data points

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
354.70.991Aldrich Chemical Company Inc., 1990BS
354. to 355.0.991PCR Inc., 1990BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
31.66353.3N/AMajer and Svoboda, 1985 
36.5293.N/ADouslin and Osborn, 2002Based on data from 275. to 387. K.; AC
34.4333.EBAmbrose, Ewing, et al., 1990Based on data from 318. to 376. K.; AC
31.8425.N/ADavies, Ewing, et al., 1988Based on data from 403. to 516. K.; AC
36.5293.AStephenson and Malanowski, 1987Based on data from 278. to 354. K.; AC
33.2363.AStephenson and Malanowski, 1987Based on data from 348. to 389. K.; AC
32.2399.AStephenson and Malanowski, 1987Based on data from 384. to 462. K.; AC
31.8473.AStephenson and Malanowski, 1987Based on data from 458. to 517. K.; AC
35.7308.N/APatrick and Tomes, 1980Based on data from 293. to 323. K.; AC
36.2292.MMFindlay, 1969Based on data from 278. to 321. K.; AC
32.2378.EBEvans and Tiley, 1966Based on data from 363. to 516. K.; AC
35.1308.N/APatrick and Prosser, 1964Based on data from 293. to 356. K.; AC
35.5308.N/APatrick and Prosser, 1964Based on data from 293. to 358. K. See also Boublik, Fried, et al., 1984.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A (kJ/mol) β Tc (K) Reference Comment
301. to 377.55.090.3016516.7Majer and Svoboda, 1985 

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
353.40 to 516.674.631271563.21-15.19Douslin, Harrison, et al., 1969, 2Coefficents calculated by NIST from author's data.
277.89 to 321.003.987511153.509-64.352Findlay, 1969Coefficents calculated by NIST from author's data.
310.4 to 361.944.143561220.117-58.543Counsell, Green, et al., 1965Coefficents calculated by NIST from author's data.
278.4 to 387.194.160541229.449-57.503Douslin and Osborn, 1965Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
49.2263.AStephenson and Malanowski, 1987Based on data from 215. to 278. K. See also Douslin and Osborn, 2002.; AC
49.8253.IP,AScott and Osborn, 1979Based on data from 238. to 268. K.; AC
46.0316.BCounsell, Green, et al., 1965, 2AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
11.585278.30Messerly and Finke, 1970DH
11.590278.25Counsell, Green, et al., 1965DH
11.59278.3Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
41.63278.30Messerly and Finke, 1970DH
41.65278.25Counsell, Green, et al., 1965DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Benzene, hexafluoro- = (Chlorine anion • Benzene, hexafluoro-)

By formula: Cl- + C6F6 = (Cl- • C6F6)

Quantity Value Units Method Reference Comment
Δr70.3 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Δr64.9 ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Δr113.J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr37. ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B
Δr36. ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

C6H6+ + Benzene, hexafluoro- = (C6H6+ • Benzene, hexafluoro-)

By formula: C6H6+ + C6F6 = (C6H6+ • C6F6)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr50.6kJ/molPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KN/AMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.300.PHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; Entropy change calculated or estimated; M

C6H7N+ + Benzene, hexafluoro- = (C6H7N+ • Benzene, hexafluoro-)

By formula: C6H7N+ + C6F6 = (C6H7N+ • C6F6)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr47.3kJ/molPHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KN/AMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr15.kJ/molPHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M

C6F6- + Benzene, hexafluoro- = (C6F6- • Benzene, hexafluoro-)

By formula: C6F6- + C6F6 = (C6F6- • C6F6)

Quantity Value Units Method Reference Comment
Δr39. ± 19.kJ/molN/ANakajima, Taguwa, et al., 1993gas phase; Vertical Detachment Energy: 1.760±0.040 eV; B
Δr43.5 ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1990gas phase; B,M
Quantity Value Units Method Reference Comment
Δr111.J/mol*KPHPMSHiraoka, Mizuse, et al., 1990gas phase; M
Quantity Value Units Method Reference Comment
Δr10. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1990gas phase; B

Fluorine anion + Benzene, hexafluoro- = (Fluorine anion • Benzene, hexafluoro-)

By formula: F- + C6F6 = (F- • C6F6)

Quantity Value Units Method Reference Comment
Δr115. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr99.2J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr85.4 ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

Iodide + Benzene, hexafluoro- = (Iodide • Benzene, hexafluoro-)

By formula: I- + C6F6 = (I- • C6F6)

Quantity Value Units Method Reference Comment
Δr46.0 ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr72.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr24. ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

Bromine anion + Benzene, hexafluoro- = (Bromine anion • Benzene, hexafluoro-)

By formula: Br- + C6F6 = (Br- • C6F6)

Quantity Value Units Method Reference Comment
Δr58.2 ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr81.2J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr34. ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

C6F6+ + Benzene, hexafluoro- = (C6F6+ • Benzene, hexafluoro-)

By formula: C6F6+ + C6F6 = (C6F6+ • C6F6)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr30.kJ/molPHPMSHiraoka, Mizuse, et al., 1990gas phase; M
Quantity Value Units Method Reference Comment
Δr83.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1990gas phase; M

(Chlorine anion • Benzene, hexafluoro-) + Benzene, hexafluoro- = (Chlorine anion • 2Benzene, hexafluoro-)

By formula: (Cl- • C6F6) + C6F6 = (Cl- • 2C6F6)

Quantity Value Units Method Reference Comment
Δr57.7kJ/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M

(Iodide • Benzene, hexafluoro-) + Benzene, hexafluoro- = (Iodide • 2Benzene, hexafluoro-)

By formula: (I- • C6F6) + C6F6 = (I- • 2C6F6)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr90.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M

(Bromine anion • Benzene, hexafluoro-) + Benzene, hexafluoro- = (Bromine anion • 2Benzene, hexafluoro-)

By formula: (Br- • C6F6) + C6F6 = (Br- • 2C6F6)

Quantity Value Units Method Reference Comment
Δr51.0kJ/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M

(Fluorine anion • Benzene, hexafluoro-) + Benzene, hexafluoro- = (Fluorine anion • 2Benzene, hexafluoro-)

By formula: (F- • C6F6) + C6F6 = (F- • 2C6F6)

Quantity Value Units Method Reference Comment
Δr31.kJ/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr52.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M

Au- + Benzene, hexafluoro- = C6AuF6-

By formula: Au- + C6F6 = C6AuF6-

Quantity Value Units Method Reference Comment
Δr100. ± 17.kJ/molN/AHo and Dunbar, 1999gas phase; B

Chromium ion (1+) + Benzene, hexafluoro- = (Chromium ion (1+) • Benzene, hexafluoro-)

By formula: Cr+ + C6F6 = (Cr+ • C6F6)

Quantity Value Units Method Reference Comment
Δr79.1kJ/molRAKRyzhov, 1999RCD

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stewart, 2004
Stewart, J.J.P., Comparison of the accuracy of semiempirical and some DFT methods for predicting heats of formation, J. Mol. Model, 2004, 10, 1, 6-10, https://doi.org/10.1007/s00894-003-0157-6 . [all data]

Cox, Gundry, et al., 1969
Cox, J.D.; Gundry, H.A.; Harrop, D.; Head, A.J., Thermodynamic properties of fluorine compounds. 9. Enthalpies of formation of some compounds containing the pentafluorophenyl group, J. Chem. Thermodyn., 1969, 1, 77-87. [all data]

Krech, Price, et al., 1972
Krech, M.; Price, S.J.W.; Yared, W.F., Determination of the heat of formation of hexafluorobenzene, Can. J. Chem., 1972, 50, 2935-2938. [all data]

Messerly and Finke, 1970
Messerly, J.F.; Finke, H.L., Hexafluorobenzene and 1,3-difluorobenzene. Low-temperature calorimetric studies and chemical thermodynamic properties, J. Chem. Thermodynam., 1970, 2, 867-880. [all data]

Counsell, Green, et al., 1965
Counsell, J.F.; Green, J.H.S.; Hales, J.L.; Martin, J.F., Thermodynamic properties of fluorine compounds. Part 2. Physical and thermodynamic properties of hexafluorobenzene, Trans. Faraday Soc., 1965, 61, 212-218. [all data]

Wilhelm, Lainez, et al., 1987
Wilhelm, E.; Lainez, A.; Berkane, M.; Roux-Desgranges, G.; Roux, A.H.; Grolier, J.-P.E., Hydrocarbon/fluorohydrocarbon solutions: thermodyanmic studies on an important class of materials, Calorim. Anal. Therm., 1987, 18, 95-99. [all data]

Gorbunova, Grigoriev, et al., 1982
Gorbunova, N.I.; Grigoriev, V.A.; Simonov, V.M.; Shipova, V.A., Heat capacity of liquid benzene and hexafluorobenzene at atmospheric pressure, Int. J. Thermophysics, 1982, 3, 1-15. [all data]

Gorbunova, Simonov, et al., 1982
Gorbunova, N.I.; Simonov, V.M.; Shipova, V.A., The enthalpy of benzene and hexafluorobenzene in the temperature range of 290-680 K and pressure range 0.1-20.0 MPa, Proc. Symp. Thermophys. Prop. 8th(2), 1982, 409-14. [all data]

Gorbunova, Simonov, et al., 1982, 2
Gorbunova, N.I.; Simonov, V.M.; Shipova, V.A., Thermodynamic properties of hexafluorobenzene, Dokl. Akad. Nauk, 1982, SSSR 266, 850-853. [all data]

Messerly and Finke, 1970, 2
Messerly, J.F.; Finke, H.L., hexafluorobenzene and 1,3-difluorobenzene low temperature calorimetric studies and chemical thermodynamic properties, J. Chem. Thermodyn., 1970, 2, 867-80. [all data]

Paukov and Glukhikh, 1967
Paukov, I.E.; Glukhikh, L.K., Low temperature specific heats and absolute entropies of hexafluorobenzene and pentafluorochlorobenzene, Zh. Vses. Khim. O-va. im. D. I. Mendeleeva, 1967, 12, 236-7. [all data]

Counsell, Green, et al., 1965, 2
Counsell, J.F.; Green, J.H.S.; Hales, J.L.; Martin, J.F., Thermodynamic properties of fluorine compounds Part 2.-Physical and thermodynamic properties of hexafluorobenzene, Trans. Faraday Soc., 1965, 61, 212. [all data]

Douslin, Harrison, et al., 1969
Douslin, D.R.; Harrison, R.H.; Moore, R.T., Pressure-Volume-Temperature Relations of Hexafluorobenzene, J. Chem. Thermodyn., 1969, 1, 305-19. [all data]

Hales and Townsend, 1974
Hales, J.L.; Townsend, R., Liquid Densities from 293 to 490 K of Eight Fluorinated Aromatic Comp., J. Chem. Thermodyn., 1974, 6, 111-6. [all data]

Mousa, Kay, et al., 1972
Mousa, A.H.N.; Kay, W.B.; Kreglewski, A., The critical constants of binary mixtures of certain perfluoro-compounds with alkanes, J. Chem. Thermodyn., 1972, 4, 301-11. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Douslin and Osborn, 2002
Douslin, D.R.; Osborn, A., Pressure measurements in the 0.01-30 torr range with an inclined-piston gauge, J. Sci. Instrum., 2002, 42, 6, 369-373, https://doi.org/10.1088/0950-7671/42/6/301 . [all data]

Ambrose, Ewing, et al., 1990
Ambrose, D.; Ewing, M.B.; Ghiassee, N.B.; Sanchez Ochoa, J.C., The ebulliometric method of vapour-pressure measurement: vapour pressures of benzene, hexafluorobenzene, and naphthalene, The Journal of Chemical Thermodynamics, 1990, 22, 6, 589-605, https://doi.org/10.1016/0021-9614(90)90151-F . [all data]

Davies, Ewing, et al., 1988
Davies, D.R.; Ewing, M.B.; Hugill, J.A.; McGlashan, M.L., The critical temperature, the critical pressure, and the dependence of vapour pressure on temperature for dodecafluorocyclohexane and hexafluorobenzene, Can. J. Chem., 1988, 66, 4, 760-762, https://doi.org/10.1139/v88-131 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Patrick and Tomes, 1980
Patrick, C.R.; Tomes, F., The vapour pressures and excess free energies of mixing of the systems hexafluorobenzene-carbon tetrachloride and hexafluorobenzene-perfluoromethylcyclohexane, Journal of Fluorine Chemistry, 1980, 15, 4, 267-278, https://doi.org/10.1016/S0022-1139(00)81462-1 . [all data]

Findlay, 1969
Findlay, T.J.V., Vapor pressures of fluorobenzenes from 5 to 50.deg.C, J. Chem. Eng. Data, 1969, 14, 2, 229-231, https://doi.org/10.1021/je60041a012 . [all data]

Evans and Tiley, 1966
Evans, F.D.; Tiley, P.F., Vapour pressures and critical constants of hexafluoro-, pentafluoro-, chloropentafluoro-, and bromopentafluoro-benzene, J. Chem. Soc., B:, 1966, 134, https://doi.org/10.1039/j29660000134 . [all data]

Patrick and Prosser, 1964
Patrick, C.R.; Prosser, G.S., Vapour pressures and related properties of hexafluorobenzene and of pentafluorobenzene, Trans. Faraday Soc., 1964, 60, 700, https://doi.org/10.1039/tf9646000700 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Douslin, Harrison, et al., 1969, 2
Douslin, D.R.; Harrison, R.H.; Moore, R.T., Pressure-Volume-Temperature Relations of Hexafluorobenzene, J. Chem. Thermodyn., 1969, 1, 3, 305-319, https://doi.org/10.1016/0021-9614(69)90050-0 . [all data]

Douslin and Osborn, 1965
Douslin, D.R.; Osborn, A., Pressure Measurements in the 0·01-30 Torr with an Inclined-Piston Gauge, J. Sci. Instrum., 1965, 42, 6, 369-373, https://doi.org/10.1088/0950-7671/42/6/301 . [all data]

Scott and Osborn, 1979
Scott, D.W.; Osborn, A.G., Representation of vapor-pressure data, J. Phys. Chem., 1979, 83, 21, 2714-2723, https://doi.org/10.1021/j100484a007 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Role of Binding Energies in A-.B and A.B- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A- + B = A + B- Involving Perfluoro Compounds: SF6, C6F11CF3, J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., High Symmetric Structure of the Gas Phase Ion Cluster X-..C6F6 (X = Cl, Br, I), J. Phys. Chem., 1987, 91, 20, 5294, https://doi.org/10.1021/j100304a032 . [all data]

Meot-Ner (Mautner), Hamlet, et al., 1978
Meot-Ner (Mautner), M.; Hamlet, P.; Hunter, E.P.; Field, F.H., Bonding Energies in Association Ions of Aromatic Molecules. Correlations with Ionization Energies, J. Am. Chem. Soc., 1978, 100, 17, 5466, https://doi.org/10.1021/ja00485a034 . [all data]

Meot-Ner (Mautner) and El-Shall, 1986
Meot-Ner (Mautner), M.; El-Shall, M.S., Ionic Charge Transfer Complexes. 1. Cationic Complexes with Delocalized and Partially Localized pi Systems, J. Am. Chem. Soc., 1986, 108, 15, 4386, https://doi.org/10.1021/ja00275a026 . [all data]

Nakajima, Taguwa, et al., 1993
Nakajima, A.; Taguwa, T.; Hoshino, K.; Sugioka, T.; Naganuma, T.; Ono, F.; Watanabe, K.; Nakao, K., Photoelectron Spectroscopy of (C6F6)n- and (Au-C6F6)- Clusters, Chem. Phys. Lett., 1993, 214, 1, 22, https://doi.org/10.1016/0009-2614(93)85449-X . [all data]

Hiraoka, Mizuse, et al., 1990
Hiraoka, K.; Mizuse, S.; Yamabe, S., Stabilities and Structures of C6F6-(C6F6) and C6F6+(C6F6), J. Phys. Chem., 1990, 94, 9, 3689, https://doi.org/10.1021/j100372a061 . [all data]

Hiraoka, Mizuse, et al., 1987, 2
Hiraoka, K.; Mizuse, S.; Yamabe, S., A Determination of the Stability and Structure of F-(C6H6) and F-(C6F6) Clusters, J. Chem. Phys., 1987, 86, 7, 4102, https://doi.org/10.1063/1.451920 . [all data]

Ho and Dunbar, 1999
Ho, Y.P.; Dunbar, R.C., Reactions of Au+ and Au- with benzene and fluorine-substituted benzenes, Int. J. Mass Spectrom., 1999, 183, 175-184, https://doi.org/10.1016/S1387-3806(98)14245-8 . [all data]

Ryzhov, 1999
Ryzhov, V., Binding Energies of Chromium Cations with Fluorobenzenes from Radiative Association Kinetics, Int. J. Mass Spectrom., 1999, 185/186/187, 913. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References