Dipotassium


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas123.68kJ/molReviewChase, 1998Data last reviewed in December, 1983
Quantity Value Units Method Reference Comment
gas,1 bar249.71J/mol*KReviewChase, 1998Data last reviewed in December, 1983

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1300.1300. to 6000.
A 22.6587931.01331
B 53.55520-5.786221
C -56.326681.157994
D 16.00840-0.078852
E 0.34951512.42895
F 116.1901134.1629
G 265.4874307.2290
H 123.6832123.6832
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1983 Data last reviewed in December, 1983

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

K8+ + Dipotassium = (K8+ • Dipotassium)

By formula: K8+ + K2 = (K8+ • K2)

Quantity Value Units Method Reference Comment
Δr84.9kJ/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K9+ + Dipotassium = (K9+ • Dipotassium)

By formula: K9+ + K2 = (K9+ • K2)

Quantity Value Units Method Reference Comment
Δr53.1kJ/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K11+ + Dipotassium = (K11+ • Dipotassium)

By formula: K11+ + K2 = (K11+ • K2)

Quantity Value Units Method Reference Comment
Δr65.7kJ/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K13+ + Dipotassium = (K13+ • Dipotassium)

By formula: K13+ + K2 = (K13+ • K2)

Quantity Value Units Method Reference Comment
Δr68.6kJ/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K3+ + Dipotassium = (K3+ • Dipotassium)

By formula: K3+ + K2 = (K3+ • K2)

Quantity Value Units Method Reference Comment
Δr66.5kJ/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K4+ + Dipotassium = (K4+ • Dipotassium)

By formula: K4+ + K2 = (K4+ • K2)

Quantity Value Units Method Reference Comment
Δr57.7kJ/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K6+ + Dipotassium = (K6+ • Dipotassium)

By formula: K6+ + K2 = (K6+ • K2)

Quantity Value Units Method Reference Comment
Δr79.9kJ/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K5+ + Dipotassium = (K5+ • Dipotassium)

By formula: K5+ + K2 = (K5+ • K2)

Quantity Value Units Method Reference Comment
Δr76.1kJ/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K7+ + Dipotassium = (K7+ • Dipotassium)

By formula: K7+ + K2 = (K7+ • K2)

Quantity Value Units Method Reference Comment
Δr90.8kJ/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K10+ + Dipotassium = (K10+ • Dipotassium)

By formula: K10+ + K2 = (K10+ • K2)

Quantity Value Units Method Reference Comment
Δr59.0kJ/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K12+ + Dipotassium = (K12+ • Dipotassium)

By formula: K12+ + K2 = (K12+ • K2)

Quantity Value Units Method Reference Comment
Δr68.6kJ/molPDissBrechignac, Cahuzac, et al., 1990gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Brechignac, Cahuzac, et al., 1990
Brechignac, C.; Cahuzac, P.; Carlier, F.; De Frutos, M.; Leyniger, J., Cohesive Energies of (K)n+ 5<n<200 from Photoevaporation Experiments, J. Chem. Phys., 1990, 93, 10, 7449, https://doi.org/10.1063/1.459418 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References