Tricyclo[3.3.1.1(3,7)]decane-1-carbonitrile

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-5.02 ± 0.62kcal/molCcbAbboud, Jimenez, et al., 1992 
Δfgas-1.80 ± 0.50kcal/molCcbMeier, Dogan, et al., 1987 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-21.1 ± 0.60kcal/molCcbAbboud, Jimenez, et al., 1992ALS
Δfsolid-19.96 ± 0.42kcal/molCcbMeier, Dogan, et al., 1987ALS
Quantity Value Units Method Reference Comment
Δcsolid-1525.8 ± 0.50kcal/molCcbAbboud, Jimenez, et al., 1992ALS
Δcsolid-1526.96 ± 0.42kcal/molCcbMeier, Dogan, et al., 1987ALS

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
52.25298.15Meier, Dogan, et al., 1987DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tfus458.KN/AFoulon, Amoureux, et al., 1984Crystal phase 1 phase; Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Δsub16.1 ± 0.2kcal/molVAbboud, Jimenez, et al., 1992ALS
Δsub16.1kcal/molN/AAbboud, Jimenez, et al., 1992DRB
Δsub16.1 ± 0.2kcal/molMEAbboud, Jimenez, et al., 1992Based on data from 294. to 312. K.; AC
Δsub18.16 ± 0.27kcal/molVMeier, Dogan, et al., 1987ALS
Δsub18.2kcal/molN/AMeier, Dogan, et al., 1987DRB

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
16.0 ± 0.2303.MEAbboud, Jimenez, et al., 1992Based on data from 294. to 312. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
3.59458.Foulon, Amoureux, et al., 2000AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
4.694280.Foulon, Amoureux, et al., 1984CAL
7.827458.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Abboud, Jimenez, et al., 1992
Abboud, J.-L.M.; Jimenez, P.; Roux, M.V.; Turrion, C.; Lopez-Mardomingo, C., Structural effects on the thermochemical properties of organic compounds. III. Enthalpies of combustion, vapour pressures and enthalpies of sublimation, and standard enthalpies of formation in the gaseous phase, of adamantane-1-carboxylic acid methyl ester and of adamantane-1-carbonitrile, J. Chem. Thermodyn., 1992, 24, 1299-1304. [all data]

Meier, Dogan, et al., 1987
Meier, M.; Dogan, B.; Beckhaus, H.; Ruchardt, C., Heats of formation and heats of isomerization of isocyanides, New J. Chem., 1987, 11, 1-6. [all data]

Foulon, Amoureux, et al., 1984
Foulon, M.; Amoureux, J.P.; Sauvajol, J.L.; Cavrot, J.P.; Muller, M., Different aspects of an interesting glassy crystal: 1-cyanoadamantane, J. Phys. C, 1984, 17, 24, 4213, https://doi.org/10.1088/0022-3719/17/24/005 . [all data]

Foulon, Amoureux, et al., 2000
Foulon, M.; Amoureux, J.P.; Sauvajol, J.L.; Cavrot, J.P.; Muller, M., Different aspects of an interesting glassy crystal: 1-cyanoadamantane, J. Phys. C: Solid State Phys., 2000, 17, 24, 4213-4229, https://doi.org/10.1088/0022-3719/17/24/005 . [all data]


Notes

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