titanium tetrakis(dimethylammonium)


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-95. ± 25.kcal/molReviewMartinho Simões 
Δfgas-50.2 ± 2.6kcal/molReviewMartinho SimõesThe enthalpy of formation relies on -377.39 ± 0.93 kcal/mol for the enthalpy of formation of Ti(O-i-Pr)4(l)

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-109. ± 25.kcal/molReviewMartinho Simões 
Δfliquid-64.2 ± 1.7kcal/molReviewMartinho SimõesThe enthalpy of formation relies on -377.39 ± 0.93 kcal/mol for the enthalpy of formation of Ti(O-i-Pr)4(l)
Quantity Value Units Method Reference Comment
Δcliquid-1689. ± 25.kcal/molCC-SBMakhailov, Baev, et al., 1986 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap14.0 ± 2.0kcal/molCC-SBLappert, Patil, et al., 1975MS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
12.9 ± 0.72383.Baev, Mikhailov, et al., 1984Based on data from 353. to 418. K. See also Baev and Mikhailov, 2001.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Makhailov, Baev, et al., 1986
Makhailov, V.E.; Baev, A.K.; Sachek, A.I.; Al'khimovich, V.M., Zh. Fiz. Khim., 1986, 60, 2306. [all data]

Lappert, Patil, et al., 1975
Lappert, M.F.; Patil, D.S.; Pedley, J.B., J. Chem. Soc., Chem. Commun., 1975, 830.. [all data]

Baev, Mikhailov, et al., 1984
Baev, A.K.; Mikhailov, V.E.; Baev, A.A., Vestsi Akad. Navuk BSSR Ser. Khim. Navuk, 1984, 75. [all data]

Baev and Mikhailov, 2001
Baev, A.K.; Mikhailov, V.E., Russian Journal of Applied Chemistry, 2001, 74, 9, 1435-1438, https://doi.org/10.1023/A:1013772227611 . [all data]


Notes

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