Benzenamine, 4-butyl-N-[(4-methoxyphenyl)methylene]-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
477.298.15Shinoda and Mizuno, 1982T = 293 to 333 K. Data given graphically. Cp value is a graphical estimate.
490.300.Janik, Janik, et al., 1975T = 100 to 340 K. Cp value estimated from graphical data.
475.3298.15Shinoda, Maeda, et al., 1974T = 2 to 330 K. Nematic liquid crystal.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple295.3KN/AJanik, Janik, et al., 1975, 2Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple294.0KN/AJanik, Janik, et al., 1975, 2Metastable crystal phase; Uncertainty assigned by TRC = 0.1 K; TRC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
18.033295.3Janik, Janik, et al., 1975Data also given for metastable modification 294.0 K, H = 14757 J/mol S = 50.21 J/mol*K; DH

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
61.04295.3Janik, Janik, et al., 1975Data; DH

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
320.137liquid, Nematicliquid, isotropicShinoda and Mizuno, 1982DH

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
13.1486294.45crystaline, IliquidShinoda, Maeda, et al., 1974liq = Nematic liquid crystal. c,I = metastable crystal form.; DH
15.9377295.65crystaline, IIIliquidShinoda, Maeda, et al., 1974liq = Nematic liquid crystal. c,III = stable crystal form.; DH
0.2841320.14liquidliquidShinoda, Maeda, et al., 1974DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
44.65294.45crystaline, IliquidShinoda, Maeda, et al., 1974liq; DH
53.91295.65crystaline, IIIliquidShinoda, Maeda, et al., 1974liq; DH
0.89320.14liquid, Nematicliquid, isotropicShinoda, Maeda, et al., 1974DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shinoda and Mizuno, 1982
Shinoda, T.; Mizuno, M., On the pre-transition phenomenon of n-(p-methoxybenzylidene)-p-n-butylaniline (MBBA), Tokyo Kogyo Shikensho Hokoku, 1982, 77(4), 215-217. [all data]

Janik, Janik, et al., 1975
Janik, J.A.; Janik, J.M.; Mayer, J.; Sciesinska, E.; Sciesinski, J.; Twardowski, J.; Waluga, T.; Witko, W., Calorimetric and infrared study of the phase situation in solid MBBA [N-(p-methoxybenzylidene)-p-(n-butyl)aniline], J. Phys. (Paris) Colloq., 1975, (1), 159-165. [all data]

Shinoda, Maeda, et al., 1974
Shinoda, T.; Maeda, Y.; Enokido, H., Thermodynamic properties of N-(p-methoxybenzylidene)-p-n-butyl-aniline (MBBA) from 2K to its isotropic-liquid phase, J. Chem. Thermodynam., 1974, 6, 921-934. [all data]

Janik, Janik, et al., 1975, 2
Janik, J.A.; Janik, J.M.; Mayer, J.; Sciesinska, E.; Sciesinski, J.; Twardowski, J.; Waluga, T.; Witko, W., Calorimetric and infrared study of the phase situation in solid MBBA [N-(p-methoxybenzylidene)-p-(n-butyl)aniline], J. Phys., Colloq., 1975, 1, 159. [all data]


Notes

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