Magnesium, bis(η⁵-2,4-cyclopentadien-1-yl)-

• Formula: C₁₀H₁₀Mg
• Molecular weight: 154.4914
• IUPAC Standard InChI: InChI=1S/2C5H5.Mg/c2*1-2-4-5-3-1;/h2*1-5H; Copy

  
• IUPAC Standard InChIKey: USZGMDQWECZTIQ-UHFFFAOYSA-N Copy
• CAS Registry Number: 1284-72-6
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Dicyclopentadienyl magnesium; Bis(cyclopentadienyl)magnesium; Magnesocene; wm
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• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • UV/Visible spectrum
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2 (l) +  (cr) =  (cr) +  (g)

By formula: 2C₅H₆ (l) + Mg (cr) = C₁₀H₁₀Mg (cr) + H₂ (g)

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Chipperfield, Sneyd, et al., 1979
Chipperfield, J.R.; Sneyd, J.C.R.; Webster, D.E., J. Organometal. Chem., 1979, 178, 177. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Hull, Reid, et al., 1967
Hull, H.S.; Reid, Allen Forrest; Turnbull, Alan G., Heat of formation and bond energy of bis(cyclopentadienyl)magnesium, Inorg. Chem., 1967, 6, 4, 805-807, https://doi.org/10.1021/ic50050a032 . [all data]

Turnbull, 1967
Turnbull, AG, Thermochemistry of biscyclopentsdienyl metal compounds, Aust. J. Chem., 1967, 20, 12, 2757-621, https://doi.org/10.1071/CH9672757 . [all data]

Hull, Reid, et al., 1967, 2
Hull, H.S.; Reid, A.F.; Turnbull, A.G., Inorg. Chem., 1967, 6, 805. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Notes

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• Symbols used in this document:
  

  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°solid	Enthalpy of formation of solid at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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