OCS+


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

COS+ + Acetylene = (COS+ • Acetylene)

By formula: COS+ + C2H2 = (COS+ • C2H2)

Quantity Value Units Method Reference Comment
Δr116.kJ/molPD/KERDGraul S.T. and Bowers, 1991gas phase; ΔrH>=
Δr140.kJ/molPDissOrlando, Friedman, et al., 1990gas phase
Δr140.kJ/molPDissOrlando, Friedman, et al., 1990gas phase
Δr141. ± 22.kJ/molPDissOrlando, Friedman, et al., 1990gas phase; ΔrH<

(COS+ • Carbonyl sulfide) + Carbonyl sulfide = (COS+ • 2Carbonyl sulfide)

By formula: (COS+ • COS) + COS = (COS+ • 2COS)

Quantity Value Units Method Reference Comment
Δr6.7kJ/molPIOno, Osuch, et al., 1981gas phase

COS+ + Carbonyl sulfide = (COS+ • Carbonyl sulfide)

By formula: COS+ + COS = (COS+ • COS)

Quantity Value Units Method Reference Comment
Δr72.0kJ/molPIOno, Osuch, et al., 1981gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

COS+ + Carbonyl sulfide = (COS+ • Carbonyl sulfide)

By formula: COS+ + COS = (COS+ • COS)

Quantity Value Units Method Reference Comment
Δr72.0kJ/molPIOno, Osuch, et al., 1981gas phase

(COS+ • Carbonyl sulfide) + Carbonyl sulfide = (COS+ • 2Carbonyl sulfide)

By formula: (COS+ • COS) + COS = (COS+ • 2COS)

Quantity Value Units Method Reference Comment
Δr6.7kJ/molPIOno, Osuch, et al., 1981gas phase

COS+ + Acetylene = (COS+ • Acetylene)

By formula: COS+ + C2H2 = (COS+ • C2H2)

Quantity Value Units Method Reference Comment
Δr116.kJ/molPD/KERDGraul S.T. and Bowers, 1991gas phase; ΔrH>=
Δr140.kJ/molPDissOrlando, Friedman, et al., 1990gas phase
Δr140.kJ/molPDissOrlando, Friedman, et al., 1990gas phase
Δr141. ± 22.kJ/molPDissOrlando, Friedman, et al., 1990gas phase; ΔrH<

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Graul S.T. and Bowers, 1991
Graul S.T.; Bowers, M.T., Dynamics of Metastable Dissociation and Photodissociation of the Gas Phase Cluster Ion (OCS.C2H2)+, J. Phys. Chem., 1991, 95, 21, 8328, https://doi.org/10.1021/j100174a055 . [all data]

Orlando, Friedman, et al., 1990
Orlando, T.M.; Friedman, A.; Maier, J.P., Photodissociation Spectroscopy of the [OCS C2H2]+ Cluster, J. Chem. Phys., 1990, 92, 12, 7365, https://doi.org/10.1063/1.458222 . [all data]

Ono, Osuch, et al., 1981
Ono, Y.; Osuch, E.A.; Ng, C.Y., Molecular beam photoionization study of OCS, (OCS)2, (OCS)3, and OCS.CS2, J. Chem. Phys., 1981, 74, 1645. [all data]


Notes

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