OCS+
- Formula: COS+
- Molecular weight: 60.075
- CAS Registry Number: 12169-37-8
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: COS+ + C2H2 = (COS+ • C2H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 116. | kJ/mol | PD/KERD | Graul S.T. and Bowers, 1991 | gas phase; ΔrH>= |
ΔrH° | 140. | kJ/mol | PDiss | Orlando, Friedman, et al., 1990 | gas phase |
ΔrH° | 140. | kJ/mol | PDiss | Orlando, Friedman, et al., 1990 | gas phase |
ΔrH° | 141. ± 22. | kJ/mol | PDiss | Orlando, Friedman, et al., 1990 | gas phase; ΔrH< |
By formula: (COS+ • COS) + COS = (COS+ • 2COS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.7 | kJ/mol | PI | Ono, Osuch, et al., 1981 | gas phase |
By formula: COS+ + COS = (COS+ • COS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 72.0 | kJ/mol | PI | Ono, Osuch, et al., 1981 | gas phase |
Ion clustering data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: COS+ + COS = (COS+ • COS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 72.0 | kJ/mol | PI | Ono, Osuch, et al., 1981 | gas phase |
By formula: (COS+ • COS) + COS = (COS+ • 2COS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.7 | kJ/mol | PI | Ono, Osuch, et al., 1981 | gas phase |
By formula: COS+ + C2H2 = (COS+ • C2H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 116. | kJ/mol | PD/KERD | Graul S.T. and Bowers, 1991 | gas phase; ΔrH>= |
ΔrH° | 140. | kJ/mol | PDiss | Orlando, Friedman, et al., 1990 | gas phase |
ΔrH° | 140. | kJ/mol | PDiss | Orlando, Friedman, et al., 1990 | gas phase |
ΔrH° | 141. ± 22. | kJ/mol | PDiss | Orlando, Friedman, et al., 1990 | gas phase; ΔrH< |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Graul S.T. and Bowers, 1991
Graul S.T.; Bowers, M.T.,
Dynamics of Metastable Dissociation and Photodissociation of the Gas Phase Cluster Ion (OCS.C2H2)+,
J. Phys. Chem., 1991, 95, 21, 8328, https://doi.org/10.1021/j100174a055
. [all data]
Orlando, Friedman, et al., 1990
Orlando, T.M.; Friedman, A.; Maier, J.P.,
Photodissociation Spectroscopy of the [OCS C2H2]+ Cluster,
J. Chem. Phys., 1990, 92, 12, 7365, https://doi.org/10.1063/1.458222
. [all data]
Ono, Osuch, et al., 1981
Ono, Y.; Osuch, E.A.; Ng, C.Y.,
Molecular beam photoionization study of OCS, (OCS)2, (OCS)3, and OCS.CS2,
J. Chem. Phys., 1981, 74, 1645. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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