antimony pentafluoride


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert L. Brown and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil422.6KN/APCR Inc., 1990 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Fluorine anion + antimony pentafluoride = (Fluorine anion • antimony pentafluoride)

By formula: F- + F5Sb = (F- • F5Sb)

Quantity Value Units Method Reference Comment
Δr489.95kJ/molN/ACheck, Faust, et al., 2001gas phase; MnH2-(t); ; ΔS(EA)=5.4
Quantity Value Units Method Reference Comment
Δr447.69kJ/molN/ACheck, Faust, et al., 2001gas phase; MnH2-(t); ; ΔS(EA)=5.4

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
1.30 ± 0.20NBIERussell, Herschberger, et al., 1985Negative ions not directly observed; see also Compton and Reinhardt, 1980
3.8872N/ACheck, Faust, et al., 2001MnH-(q); ; ΔS(acid)=20.9; ΔS(EA)=4.2

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Russell, Herschberger, et al., 1985
Russell, J.A.; Herschberger, J.F.; McAndrew, J.J.; Cross, R.J.; Saunders, M., Molecular Beam Studies of the Dynamics of Organic Electron Transfer Reactions, J. Chem. Phys., 1985, 82, 5, 2240, https://doi.org/10.1063/1.448318 . [all data]

Compton and Reinhardt, 1980
Compton, R.W.; Reinhardt, P.W., Reactions of fast cesium atoms with polymers of antimony pentafluoride and gold pentafluoride, J. Chem. Phys., 1980, 72, 4655. [all data]


Notes

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