Silane, ethenyltrimethyl-
- Formula: C5H12Si
- Molecular weight: 100.2343
- IUPAC Standard InChIKey: GCSJLQSCSDMKTP-UHFFFAOYSA-N
- CAS Registry Number: 754-05-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Silane, trimethylvinyl-; (Trimethylsilyl)ethylene; Trimethylvinylsilane; Vinyltrimethylsilane; CH2=CHSi(CH3)3; Vinyltrimethysilane
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Condensed phase thermochemistry data
Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°liquid | 312.2 | J/mol*K | N/A | Lebedev, Lebedev, et al., 1981 | |
S°liquid | 313.4 | J/mol*K | N/A | Rabinovich, Lebedev, et al., 1975 |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
198.0 | 298.15 | Lebedev, Lebedev, et al., 1981 | T = 5 to 330 K. |
198.3 | 300. | Rabinovich, Lebedev, et al., 1975 | T = 50 to 300 K. |
Phase change data
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 328. | K | N/A | PCR Inc., 1990 | BS |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 141.57 | K | N/A | Lebedev, Lebedev, et al., 1981, 2 | Uncertainty assigned by TRC = 0.02 K; TRC |
Ttriple | 141.65 | K | N/A | Rabinovich, Lebedev, et al., 1975, 2 | Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 33.1 ± 0.6 | kJ/mol | C | Voronkov, Baryshok, et al., 1988 | AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
7.660 | 141.57 | Lebedev, Lebedev, et al., 1981 | DH |
7.657 | 141.65 | Rabinovich, Lebedev, et al., 1975 | DH |
7.66 | 141.7 | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
54.0 | 141.57 | Lebedev, Lebedev, et al., 1981 | DH |
54.06 | 141.65 | Rabinovich, Lebedev, et al., 1975 | DH |
IR Spectrum
Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compiled by: Coblentz Society, Inc.
- SOLUTION (10% CCl4 FOR 3800-1335, 10% CS2 FOR 1335-450 CM-1); DOW KBr FOREPRISM-GRATING; DIGITIZED BY COBLENTZ SOCIETY (BATCH I) FROM HARD COPY; 2 cm-1 resolution
- SOLUTION (10% IN CCl4 FOR 3800-1000, 5% IN CS2 FOR 1300-400, AND 10% IN CCl4 FOR 600-210 CM-1); PERKIN-ELMER 521 (GRATING); DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 2 cm-1 resolution
Mass spectrum (electron ionization)
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-IW-6976 |
NIST MS number | 238939 |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lebedev, Lebedev, et al., 1981
Lebedev, B.V.; Lebedev, N.K.; Khotimskii, V.S.; Durgar'yan, S.G.; Nametkin, N.S.,
Thermodynamics of polymerization of vinylorganosilanes,
Dokl. Akad. Nauk, 1981, SSSR 259, 629-633. [all data]
Rabinovich, Lebedev, et al., 1975
Rabinovich, I.B.; Lebedev, B.V.; Tsvetkova, L.Ya.; Nametkin, N.S.; Durgar'yan, S.G.; Khotimskii, V.S.; Kiparisova, Y.G.,
Thermodynamics of polymerization of vinyltrimethylsilane,
Vysokomol. Soedin., 1975, A17, 1421-1425. [all data]
PCR Inc., 1990
PCR Inc.,
Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]
Lebedev, Lebedev, et al., 1981, 2
Lebedev, B.V.; Lebedev, N.K.; Khotimskii, V.S.; Durgar'yan, S.G.; Nametkin, N.S.,
Thermodynamics of polymerization of vinylorganosilanes,
Dokl. Akad. Nauk SSSR, 1981, 259, 629. [all data]
Rabinovich, Lebedev, et al., 1975, 2
Rabinovich, I.B.; Lebedev, B.V.; Tsvetkova, L.Ya.; Nametkin, N.S.; Durgar'yan, S.G.; Khotimskii, V.S.,
Thermodynamics of polymerization of vinyltrimethylsilane,
Vysokomol. Soedin., Ser. A, 1975, 17, 1421. [all data]
Voronkov, Baryshok, et al., 1988
Voronkov, M.G.; Baryshok, V.P.; Klyuchnikov, V.A.; Danilova, T.F.; Pepekin, V.I.; Korchagina, A.N.; Khudobin, Yu.I.,
Thermochemistry of organosilicon compounds,
Journal of Organometallic Chemistry, 1988, 345, 1-2, 27-38, https://doi.org/10.1016/0022-328X(88)80231-6
. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions Tboil Boiling point Ttriple Triple point temperature ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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