copper oxide

• Formula: CuO
• Molecular weight: 79.545
• IUPAC Standard InChI: InChI=1S/Cu.O Copy

  
• IUPAC Standard InChIKey: QPLDLSVMHZLSFG-UHFFFAOYSA-N Copy
• CAS Registry Number: 1317-38-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Copper(ii) oxide
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• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Constants of diatomic molecules
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Solid Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Constants of diatomic molecules

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through August, 1975

Notes

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Shirk and Bass, 1970
Shirk, J.S.; Bass, A.M., Absorption and laser-excited fluorescence of matrix-isolated CuO, J. Chem. Phys., 1970, 52, 1894. [all data]

Thompson, Easley, et al., 1973
Thompson, K.R.; Easley, W.C.; Knight, L.B., Spectra of matrix isolated transition metal monoxides. Maganese(II) and copper(II) oxides. Evidence for a ²Π ground state for copper(II) oxide, J. Phys. Chem., 1973, 77, 49. [all data]

Appelblad and Lagerqvist, 1974
Appelblad, O.; Lagerqvist, A., USIP Annual Report, Rpt. May-75, 1974, 1. [all data]

Lagerqvist and Uhler, 1967
Lagerqvist, A.; Uhler, U., The band spectrum of copper oxide, Z. Naturforsch. B, 1967, 22, 551. [all data]

Appelblad and Lagerqvist, 1973
Appelblad, O.; Lagerqvist, A., The spectrum of CuO: rotational analysis of a blue band system, J. Mol. Spectrosc., 1973, 48, 607. [all data]

Appelblad and Lagerqvist, 1974, 2
Appelblad, O.; Lagerqvist, A., The spectrum of CuO: rotational analysis of some blue and red bands, Phys. Scr., 1974, 10, 307. [all data]

Appelblad and Lagerqvist, 1975
Appelblad, O.; Lagerqvist, A., The spectrum of CuO: rotational analysis of a ²Σ^--X²Π_i transition, Can. J. Phys., 1975, 53, 2221. [all data]

Lefebvre, Pinchemel, et al., 1976
Lefebvre, Y.; Pinchemel, B.; Bacis, R., Analyse rotationnelle d'un systeme vert ²Π_i-X²Π_i de la molecule CuO, Can. J. Phys., 1976, 54, 735. [all data]

Antic-Jovanovic, Pesic, et al., 1968
Antic-Jovanovic, A.; Pesic, D.S.; Gaydon, A.G., The spectrum of CuO; study of the orange-red system by use of ¹⁸O, Proc. R. Soc. London A, 1968, 307, 399. [all data]

Cheetam and Barrow, 1967
Cheetam, C.J.; Barrow, R.F., Adv. High Temp. Chem., 1967, 1, 7. [all data]

Smoes, Mandy, et al., 1972
Smoes, S.; Mandy, F.; Vander Auwera-Mahieu, A.; Drowart, J., Determination by the mass spectrometric Knudsen cell method of the dissociation energies of the group IB chalcogenides, Bull. Soc. Chim. Belg., 1972, 81, 45. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Constants of diatomic molecules, References

• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  S°solid	Entropy of solid at standard conditions
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°solid	Enthalpy of formation of solid at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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