Monochlorine monoxide

• Formula: ClO
• Molecular weight: 51.452
• IUPAC Standard InChI: InChI=1S/ClO/c1-2 Copy

  
• IUPAC Standard InChIKey: NHYCGSASNAIGLD-UHFFFAOYSA-N Copy
• CAS Registry Number: 14989-30-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Information on this page:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Constants of diatomic molecules
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
• Data at other public NIST sites:
  • Microwave spectra (on physics lab web site)
  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CAS Reg. No. 80424-04-0 • 4294967295) +  = CAS Reg. No. 80424-04-0

By formula: (CAS Reg. No. 80424-04-0 • 4294967295ClO) + ClO = CAS Reg. No. 80424-04-0

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through September, 1976

Notes

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Distelrath and Boesl, 2000
Distelrath, V.; Boesl, U., Mass selective gas phase study of ClO, OClO, ClOO and ClAr by anion-ZEKE-photoelectron spectroscopy, Faraday Disc. Chem. Soc., 2000, 115, 161-174, https://doi.org/10.1039/a909618c . [all data]

Gilles, Polak, et al., 1992
Gilles, M.K.; Polak, M.L.; Lineberger, W.C., Photoelectron Spectroscopy of the Halogen Oxide Anions FO-, ClO-, BrO-, IO-, OClO-, and OIO-, J. Chem. Phys., 1992, 96, 11, 8012, https://doi.org/10.1063/1.462352 . [all data]

Basco and Morse, 1973
Basco, N.; Morse, R.D., The vacuum ultraviolet absorption spectrum of ClO, J. Mol. Spectrosc., 1973, 45, 35. [all data]

Pannetier and Gaydon, 1948
Pannetier, G.; Gaydon, A.G., Band spectrum of ClO in flames, Nature (London), 1948, 161, 242. [all data]

Porter, 1950
Porter, G., The absorption spectroscopy of substances of short life, Discuss. Faraday Soc., 1950, 9, 60, https://doi.org/10.1039/df9500900060 . [all data]

Andrews and Raymond, 1971
Andrews, L.; Raymond, J.I., Argon matrix infrared spectrum of the ClO radical, J. Chem. Phys., 1971, 55, 3087. [all data]

Chi and Andrews, 1973
Chi, F.K.; Andrews, L., Argon matrix Raman spectra of dichlorine monoxide and its photolysis products monochlorine monoxide and chlorine-monochlorine monoxide. Infrared matrix spectra of monochlorine monoxide and dimeric monochlorine monoxide, J. Phys. Chem., 1973, 77, 26, 3062, https://doi.org/10.1021/j100644a007 . [all data]

Amano, Hirota, et al., 1968
Amano, T.; Hirota, E.; Morino, Y., Microwave spectrum of the ClO radical, J. Mol. Spectrosc., 1968, 27, 257. [all data]

Amano, Saito, et al., 1969
Amano, T.; Saito, S.; Hirota, E.; Morino, Y., Microwave spectrum of the ClO radical, J. Mol. Spectrosc., 1969, 30, 275. [all data]

Carrington, Dyer, et al., 1967
Carrington, A.; Dyer, P.N.; Levy, D.H., Gas-phase electron resonance spectrum of ClO, J. Chem. Phys., 1967, 47, 1756. [all data]

Carrington, Levy, et al., 1967
Carrington, A.; Levy, D.H.; Miller, T.A., Stark effect in gas-phase electron resonance. The dipole moments of ClO, BrO, SH, and ¹ΔSO, J. Chem. Phys., 1967, 47, 3801. [all data]

Uehara and Morino, 1970
Uehara, H.; Morino, Y., Gas-phase EPR spectra of rotationally excited states of SH and ClO free radicals, J. Mol. Spectrosc., 1970, 36, 158. [all data]

Uehara, Tanimoto, et al., 1971
Uehara, H.; Tanimoto, M.; Morino, Y., Hyperfine interactions in the gas-phase E.P.R. spectra of ³⁵ClO (²Π_3/2) in the J=5/2 and J=3/2 levels, Mol. Phys., 1971, 22, 799. [all data]

Coxon and Ramsay, 1976
Coxon, J.A.; Ramsay, D.A., The A²Π_i-X²Π_i band system of ClO: reinvestigation of the absorption spectrum, Can. J. Phys., 1976, 54, 1034. [all data]

Coxon, Jones, et al., 1976
Coxon, J.A.; Jones, W.E.; Skolnik, E.G., Rotational analysis of emission bands of the A²Π_i-X²Π_i system of ³⁵ClO, Can. J. Phys., 1976, 54, 1043. [all data]

Briggs, 1972
Briggs, A.G., Vibrational reassignments in the A²Π-X²Π system of ClO, Nature (London), 1972, 239, 13. [all data]

O'Hare and Wahl, 1971
O'Hare, P.A.G.; Wahl, A.C., Dissociation energy, ionization potential, electron affinity, dipole and quadrupole moments of chlorine monoxide (ClO,²Π) from ab initio molecular orbital calculations, J. Chem. Phys., 1971, 54, 3770. [all data]

Notes

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• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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