Methyl rhenium pentacarbonyl


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-180.9 ± 2.1kcal/molReviewMartinho Simões 
Δfgas-181.2 ± 1.4kcal/molReviewMartinho Simões 
Δfgas-181.1 ± 1.3kcal/molReviewMartinho SimõesSelected data. Average of the values from Brown, Connor, et al., 1974 and Al-Takhin, Connor, et al., 1983

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-197.7 ± 2.0kcal/molReviewMartinho Simões 
Δfsolid-197.9 ± 1.4kcal/molReviewMartinho Simões 
Δfsolid-197.8 ± 1.2kcal/molReviewMartinho SimõesSelected data. Average of the values from Brown, Connor, et al., 1974 and Al-Takhin, Connor, et al., 1983

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub16.7 ± 0.5kcal/molHAL-HFCAl-Takhin, Connor, et al., 1983Another value has been reported for the enthalpy of sublimation: 15.6 ± 0.24 kcal/mol Hieber, Braun, et al., 1960; MS
Δsub16.7 ± 0.5kcal/molCAl-Takhin, Connor, et al., 1983, 2AC
Δsub15.6 ± 0.24kcal/molN/APilcher and Skinner, 1983See also Lalage, Brown, et al., 1974.; AC

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
15.6347.5AStephenson and Malanowski, 1987Based on data from 315. to 380. K. See also Hieber, Braun, et al., 1960, 2.; AC
15.5313. to 383.N/AHieber and Wagner, 1958AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H3O5Re (cr) = 5Carbon monoxide (g) + rhenium (cr) + Methane (g)

By formula: C6H3O5Re (cr) = 5CO (g) + Re (cr) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr100.7 ± 2.0kcal/molHAL-HFCBrown, Connor, et al., 1974Please also see Pedley and Rylance, 1977.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A., J. Organometal. Chem., 1974, 81, 403. [all data]

Al-Takhin, Connor, et al., 1983
Al-Takhin, G.; Connor, J.A.; Skinner, H.A., J. Organomet. Chem., 1983, 259, 313. [all data]

Hieber, Braun, et al., 1960
Hieber, W.; Braun, G.; Beck, W., Chem. Ber., 1960, 93, 901. [all data]

Al-Takhin, Connor, et al., 1983, 2
Al-Takhin, Ghassan; Connor, Joseph A.; Skinner, Henry A., Enthalpies of formation of decacarbonyldirhenium and some pentacarbonylrhenium derivatives, Journal of Organometallic Chemistry, 1983, 259, 3, 313-320, https://doi.org/10.1016/0022-328X(83)87182-4 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Lalage, Brown, et al., 1974
Lalage, D.; Brown, S.; Connor, Joseph A.; Skinner, Henry A., The enthalpies of formation of CH3Mn(CO)5 and of CH3Re(CO)5, and the strengths of the CH3«58872»Mn and CH3«58872»Re bonds, Journal of Organometallic Chemistry, 1974, 81, 3, 403-409, https://doi.org/10.1016/S0022-328X(00)88209-1 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Hieber, Braun, et al., 1960, 2
Hieber, Walter; Braun, Gerhard; Beck, Wolfgang, Über Organometallcarbonyle, II. Organorheniumpentacarbonyle, Chem. Ber., 1960, 93, 4, 901-908, https://doi.org/10.1002/cber.19600930422 . [all data]

Hieber and Wagner, 1958
Hieber, Walter; Wagner, Gerhard, Über Organomanganpentacarbonyle, I, Justus Liebigs Ann. Chem., 1958, 618, 1, 24-30, https://doi.org/10.1002/jlac.19586180104 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]


Notes

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