Benzene, fluoro-
- Formula: C6H5F
- Molecular weight: 96.1023
- IUPAC Standard InChIKey: PYLWMHQQBFSUBP-UHFFFAOYSA-N
- CAS Registry Number: 462-06-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Fluorobenzene; Monofluorobenzene; Phenyl fluoride; UN 2387; Fluorobenzenes
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -36.04 ± 0.34 | kcal/mol | Ccr | Good, Scott, et al., 1956 | Corrected for CODATA value of ΔfH; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -741.86 ± 0.29 | kcal/mol | Ccr | Good, Scott, et al., 1956 | Corrected for CODATA value of ΔfH; ALS |
ΔcH°liquid | -747.2 | kcal/mol | Ccb | Swarts, 1919 | Not corrected for CODATA value of ΔfH; ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 49.221 | cal/mol*K | N/A | Scott, McCullough, et al., 1956 | DH |
S°liquid | 46.61 | cal/mol*K | N/A | Stull, 1937 | Extrapolation below 91 K, 42.55 J/mol*K.; DH |
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
34.964 | 298.15 | Roux, Grolier, et al., 1984 | DH |
34.981 | 298.15 | Scott, McCullough, et al., 1956 | T = 14 to 350 K.; DH |
35.031 | 298.1 | Stull, 1937 | T = 90 to 320 K.; DH |
Phase change data
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 358.0 ± 0.3 | K | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 230.96 | K | N/A | Goates, Ott, et al., 1976 | Uncertainty assigned by TRC = 0.06 K; TRC |
Tfus | 231.25 | K | N/A | Timmermans, 1952 | Uncertainty assigned by TRC = 0.5 K; TRC |
Tfus | 231.3 | K | N/A | Timmermans, 1935 | Uncertainty assigned by TRC = 1. K; TRC |
Tfus | 231.25 | K | N/A | Timmermans, 1934 | Uncertainty assigned by TRC = 0.4 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 230.92 | K | N/A | Scott, McCullough, et al., 1956, 2 | Uncertainty assigned by TRC = 0.08 K; by extrapolation of 1/f to 0.0; TRC |
Ttriple | 230.94 | K | N/A | Scott, McCullough, et al., 1956, 2 | Uncertainty assigned by TRC = 0.05 K; TRC |
Ttriple | 231.1 | K | N/A | Stull, 1937, 2 | Uncertainty assigned by TRC = 0.2 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 560.1 | K | N/A | Majer and Svoboda, 1985 | |
Tc | 560.1 | K | N/A | Ambrose, Cox, et al., 1960 | Uncertainty assigned by TRC = 0.2 K; Visual, PRT, IPTS-48; TRC |
Tc | 560.070 | K | N/A | Douslin, Moore, et al., 1958 | Uncertainty assigned by TRC = 0.07 K; TRC |
Tc | 559.7 | K | N/A | Young, 1889 | Uncertainty assigned by TRC = 0.6 K; by visual observation of meniscus; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 44.910 | atm | N/A | Douslin, Moore, et al., 1958 | Uncertainty assigned by TRC = 0.0499 atm; TRC |
Pc | 44.6211 | atm | N/A | Young, 1889 | Uncertainty assigned by TRC = 0.3947 atm; vapor pressure at critical temperature; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.269 | l/mol | N/A | Douslin, Moore, et al., 1958 | Uncertainty assigned by TRC = 0.008 l/mol; TRC |
Vc | 0.462 | l/mol | N/A | Young, 1889 | Uncertainty assigned by TRC = 0.004 l/mol; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 8.289 | kcal/mol | N/A | Majer and Svoboda, 1985 | |
ΔvapH° | 8.25 | kcal/mol | N/A | Boublik, Fried, et al., 1984 | Based on data from 255. to 360. K. See also Basarová and Svoboda, 1991.; AC |
ΔvapH° | 8.253 | kcal/mol | V | Findlay, 1969 | ALS |
ΔvapH° | 8.27 | kcal/mol | V | Scott, McCullough, et al., 1956, 3 | ALS |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
7.455 | 357.9 | N/A | Majer and Svoboda, 1985 | |
7.62 | 373. | A | Stephenson and Malanowski, 1987 | Based on data from 358. to 530. K.; AC |
7.60 | 388. | A | Stephenson and Malanowski, 1987 | Based on data from 373. to 419. K.; AC |
7.41 | 429. | A | Stephenson and Malanowski, 1987 | Based on data from 414. to 501. K.; AC |
7.39 | 512. | A | Stephenson and Malanowski, 1987 | Based on data from 497. to 561. K.; AC |
8.03 | 327. | EB | Stephenson and Malanowski, 1987 | Based on data from 312. to 394. K. See also Scott, McCullough, et al., 1956.; AC |
8.01 ± 0.02 | 318. | C | Scott, McCullough, et al., 1956 | AC |
7.74 ± 0.02 | 337. | C | Scott, McCullough, et al., 1956 | AC |
7.46 ± 0.02 | 358. | C | Scott, McCullough, et al., 1956 | AC |
7.10 ± 0.02 | 382. | C | Scott, McCullough, et al., 1956 | AC |
Enthalpy of vaporization
ΔvapH =
A exp(-βTr) (1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kcal/mol)
Tr = reduced temperature (T / Tc)
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Temperature (K) | A (kcal/mol) | β | Tc (K) | Reference | Comment |
---|---|---|---|---|---|
318. to 382. | 11.9 | 0.2823 | 560.1 | Majer and Svoboda, 1985 |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
255.30 to 357.00 | 4.35654 | 1409.848 | -34.792 | Young, 1889, 2 | Coefficents calculated by NIST from author's data. |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
2.7020 | 230.94 | Scott, McCullough, et al., 1956 | DH |
2.703 | 230.9 | Domalski and Hearing, 1996 | AC |
2.4849 | 231.10 | Stull, 1937 | DH |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
11.70 | 230.94 | Scott, McCullough, et al., 1956 | DH |
10.75 | 231.10 | Stull, 1937 | DH |
Reaction thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C6H4F- + =
By formula: C6H4F- + H+ = C6H5F
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 386.8 ± 2.1 | kcal/mol | G+TS | Buker, Nibbering, et al., 1997 | gas phase; B |
ΔrH° | 387.3 ± 2.1 | kcal/mol | G+TS | Andrade and Riveros, 1996 | gas phase; B |
ΔrH° | 387.2 ± 2.5 | kcal/mol | TDEq | Meot-ner and Kafafi, 1988 | gas phase; anchored to 88MEO scale, not the "87 acidity scale". The Kiefer, Zhang, et al., 1997 BDE is for ortho.; B |
ΔrH° | 387.2 ± 2.5 | kcal/mol | Bran | Wenthold and Squires, 1995 | gas phase; By HO- cleavage of substituted silanes; B |
ΔrH° | 387.2 ± 5.4 | kcal/mol | G+TS | Briscese and Riveros, 1975 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 378.6 ± 2.0 | kcal/mol | IMRE | Buker, Nibbering, et al., 1997 | gas phase; B |
ΔrG° | 379.1 ± 2.0 | kcal/mol | IMRE | Andrade and Riveros, 1996 | gas phase; B |
ΔrG° | 378.9 ± 2.0 | kcal/mol | TDEq | Meot-ner and Kafafi, 1988 | gas phase; anchored to 88MEO scale, not the "87 acidity scale". The Kiefer, Zhang, et al., 1997 BDE is for ortho.; B |
ΔrG° | 379.0 ± 2.6 | kcal/mol | H-TS | Wenthold and Squires, 1995 | gas phase; By HO- cleavage of substituted silanes; B |
ΔrG° | 379.0 ± 5.3 | kcal/mol | IMRB | Briscese and Riveros, 1975 | gas phase; B |
By formula: Br- + C6H5F = (Br- • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.6 ± 1.6 | kcal/mol | IMRE | Paul and Kebarle, 1991 | gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20. | cal/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 2.1 ± 1.0 | kcal/mol | IMRE | Paul and Kebarle, 1991 | gas phase; ΔGaff measured at 303 K, corrected to 423 K, ΔSaff taken as that of PhNO2..Br-; B |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
2.1 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: C6H5F+ + C6H5F = (C6H5F+ • C6H5F)
Bond type: Charge transfer bond (positive ion)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.1 | kcal/mol | PI | Ruhl, Bisling, et al., 1986 | gas phase; from vIP of perpendicular dimer; M |
ΔrH° | 14.1 | kcal/mol | PHPMS | Meot-Ner (Mautner), Hamlet, et al., 1978 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 27. | cal/mol*K | N/A | Meot-Ner (Mautner), Hamlet, et al., 1978 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
5.3 | 356. | PHPMS | Meot-Ner (Mautner), Hamlet, et al., 1978 | gas phase; Entropy change calculated or estimated; M |
By formula: C6H6+ + C6H5F = (C6H6+ • C6H5F)
Bond type: Charge transfer bond (positive ion)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.6 | kcal/mol | PI | Ruhl, Bisling, et al., 1986 | gas phase; from vIP of perpendicular dimer; M |
ΔrH° | 17.0 | kcal/mol | PHPMS | Meot-Ner (Mautner), Hamlet, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 30. | cal/mol*K | PHPMS | Meot-Ner (Mautner), Hamlet, et al., 1978 | gas phase; M |
C6H4F- + =
By formula: C6H4F- + H+ = C6H5F
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 399.60 ± 0.90 | kcal/mol | Bran | Wenthold and Squires, 1995 | gas phase; By HO- cleavage of substituted silanes; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 391.8 ± 1.0 | kcal/mol | H-TS | Wenthold and Squires, 1995 | gas phase; By HO- cleavage of substituted silanes; B |
C6H4F- + =
By formula: C6H4F- + H+ = C6H5F
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 395.2 ± 2.0 | kcal/mol | Bran | Wenthold and Squires, 1995 | gas phase; By HO- cleavage of substituted silanes; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 387.0 ± 2.1 | kcal/mol | H-TS | Wenthold and Squires, 1995 | gas phase; By HO- cleavage of substituted silanes; B |
By formula: C6H7N+ + C6H5F = (C6H7N+ • C6H5F)
Bond type: Charge transfer bond (positive ion)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.7 | kcal/mol | PHPMS | Meot-Ner (Mautner) and El-Shall, 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 26.5 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and El-Shall, 1986 | gas phase; M |
By formula: NO- + C6H5F = (NO- • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 37.8 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: Cl- + C6H5F = (Cl- • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 5.90 | kcal/mol | TDEq | French, Ikuta, et al., 1982 | gas phase; B |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
5.9 | 300. | PHPMS | French, Ikuta, et al., 1982 | gas phase; M |
By formula: C7H8+ + C6H5F = (C7H8+ • C6H5F)
Bond type: Charge transfer bond (positive ion)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.9 | kcal/mol | PI | Ruhl, Bisling, et al., 1986 | gas phase; from vIP of perpendicular dimer; M |
By formula: H4N+ + C6H5F = (H4N+ • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.4 | kcal/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.0 | cal/mol*K | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; M |
By formula: (V- • C6H5F) + C6H6 = (V- • C6H6 • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3. ± 15. | kcal/mol | N/A | Judai, Hirano, et al., 1997 | gas phase; B |
By formula: V- + C6H5F = (V- • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.4 ± 3.8 | kcal/mol | N/A | Judai, Hirano, et al., 1997 | gas phase; B |
By formula: (Li+ • C6H5F) + C6H5F = (Li+ • 2C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22.7 ± 0.7 | kcal/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: (Na+ • C6H5F) + C6H5F = (Na+ • 2C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.7 ± 0.9 | kcal/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: (Cs+ • C6H5F) + C6H5F = (Cs+ • 2C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.7 ± 1.1 | kcal/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: (Rb+ • C6H5F) + C6H5F = (Rb+ • 2C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.3 ± 1.2 | kcal/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: (K+ • C6H5F) + C6H5F = (K+ • 2C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.0 ± 0.7 | kcal/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: Li+ + C6H5F = (Li+ • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 35.1 ± 5.0 | kcal/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: Na+ + C6H5F = (Na+ • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 16.7 ± 0.8 | kcal/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: Cs+ + C6H5F = (Cs+ • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.0 ± 1.2 | kcal/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: Rb+ + C6H5F = (Rb+ • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.8 ± 1.3 | kcal/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: K+ + C6H5F = (K+ • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13.2 ± 0.7 | kcal/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: Cr+ + C6H5F = (Cr+ • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39.2 | kcal/mol | RAK | Ryzhov, 1999 | RCD |
Henry's Law data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Rolf Sander
Henry's Law constant (water solution)
kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)
k°H (mol/(kg*bar)) | d(ln(kH))/d(1/T) (K) | Method | Reference | Comment |
---|---|---|---|---|
0.12 | Q | N/A | Several references are given in the list of Henry's law constants but not assigned to specific species. | |
0.16 | Q | N/A | missing citation give several references for the Henry's law constants but don't assign them to specific species. | |
0.16 | L | N/A | ||
0.16 | 4100. | M | N/A |
IR Spectrum
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compiled by: Coblentz Society, Inc.
- GAS (50 mmHg, N2 ADDED, TOTAL PRESSURE 600 mmHg); DOW KBr FOREPRISM-GRATING; DIGITIZED BY COBLENTZ SOCIETY (BATCH II) FROM HARD COPY; 2 cm-1 resolution
- SOLUTION (10% CCl4 FOR 3800-1300, 10% CS2 FOR 1300-450 CM-1); DOW KBr FOREPRISM-GRATING; DIGITIZED BY COBLENTZ SOCIETY (BATCH I) FROM HARD COPY; 2 cm-1 resolution
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Mass spectrum (electron ionization)
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW- 529 |
NIST MS number | 229256 |
UV/Visible spectrum
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spectrum
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Additional Data
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Download spectrum in JCAMP-DX format.
Source | Bowden and Braude, 1952 |
---|---|
Owner | INEP CP RAS, NIST OSRD Collection (C) 2007 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
Origin | INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS |
Source reference | RAS UV No. 11510 |
Instrument | Hilger, Beckman spectrophotometer |
Melting point | - 42.2 |
Boiling point | 84.7 |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Good, Scott, et al., 1956
Good, W.D.; Scott, D.W.; Waddington, G.,
Combustion calorimetry of organic fluorine compounds by a rotating-bomb method,
J. Phys. Chem., 1956, 60, 1080-1089. [all data]
Swarts, 1919
Swarts, F.,
Etudes thermochimiques sur les combinaisons organiques fluorees,
J. Chim. Phys., 1919, 17, 3-70. [all data]
Scott, McCullough, et al., 1956
Scott, D.W.; McCullough, J.P.; Good, W.D.; Messerly, J.F.; Pennington, R.E.; Kincheloe, T.C.; Hossenlopp, I.A.; Douslin, D.R.; Waddington, G.,
Fluorobenzene: Thermodynamic properties in the solid, liquid and vapor states, a revised vibrational assignment,
J. Am. Chem. Soc., 1956, 78, 5457-5463. [all data]
Stull, 1937
Stull, D.R.,
A semi-micro calorimeter for measuring heat capacities at low temperatures,
J. Am. Chem. Soc., 1937, 59, 2726-2733. [all data]
Roux, Grolier, et al., 1984
Roux, A.H.; Grolier, J.-P.E.; Inglese, A.; Wilhelm, E.,
Excess molar enthalpies, excess molar heat capacities and excess molar volumes of (fluorobenzene + an n-alkane),
Ber. Bunsenges. Phys. Chem., 1984, 88, 986-992. [all data]
Goates, Ott, et al., 1976
Goates, J.R.; Ott, J.B.; Moellmer, J.F.,
Solid + Liquid Phase Equilibria and Solid-compound Formation in Halobenzenes + Aromatic Hydrocarbons,
J. Chem. Thermodyn., 1976, 8, 217. [all data]
Timmermans, 1952
Timmermans, J.,
Freezing points of organic compounds. VVI New determinations.,
Bull. Soc. Chim. Belg., 1952, 61, 393. [all data]
Timmermans, 1935
Timmermans, J.,
Researches in Stoichiometry. I. The Heat of Fusion of Organic Compounds.,
Bull. Soc. Chim. Belg., 1935, 44, 17-40. [all data]
Timmermans, 1934
Timmermans, J.,
Theory of Concentrated Solutions XII.,
Bull. Soc. Chim. Belg., 1934, 43, 626. [all data]
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Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Pc Critical pressure S°liquid Entropy of liquid at standard conditions T Temperature Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature Vc Critical volume d(ln(kH))/d(1/T) Temperature dependence parameter for Henry's Law constant k°H Henry's Law constant at 298.15K ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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