2-Aminobiphenyl

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid93.8 ± 1.1kJ/molCcrSteele, Chirico, et al., 1991Hfusion=16.8 kJ/mol; ALS
Quantity Value Units Method Reference Comment
Δcsolid-6387.97 ± 0.88kJ/molCcrSteele, Chirico, et al., 1991Hfusion=16.8 kJ/mol; ALS
Δcsolid-6406.16kJ/molCcbBrull, 1935ALS
Quantity Value Units Method Reference Comment
solid,1 bar233.48J/mol*KN/ASteele, Chirico, et al., 1991, 2crystaline, I phase; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
221.86298.15Steele, Chirico, et al., 1991, 2crystaline, I phase; T = 5 to 800 K. Cp(liq, 298.15 K) = 298.17 J/mol*K.; DH

Phase change data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil572.2KN/AWeast and Grasselli, 1989BS
Tboil572.KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Tfus322. to 323.KN/ABuckingham and Donaghy, 1982BS
Tfus322.65KN/ACumper, Ginman, et al., 1962Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Ttriple322.28KN/ASteele, Chirico, et al., 1991, 3Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Δsub90.6kJ/molN/ASteele, Chirico, et al., 1991DRB

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
443.20.020Weast and Grasselli, 1989BS
443.0.020Buckingham and Donaghy, 1982BS
418. to 421.0.007Buckingham and Donaghy, 1982BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
68.6400.EB,IPSteele, Chirico, et al., 1991, 2Based on data from 340. to 623. K.; AC
65.1440.EB,IPSteele, Chirico, et al., 1991, 2Based on data from 340. to 623. K.; AC
61.8480.EB,IPSteele, Chirico, et al., 1991, 2Based on data from 340. to 623. K.; AC
58.5520.EB,IPSteele, Chirico, et al., 1991, 2Based on data from 340. to 623. K.; AC
55.2560.EB,IPSteele, Chirico, et al., 1991, 2Based on data from 340. to 623. K.; AC
51.7600.EB,IPSteele, Chirico, et al., 1991, 2Based on data from 340. to 623. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
13.99322.3Domalski and Hearing, 1996AC

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.00258.00crystaline, IIcrystaline, ISteele, Chirico, et al., 1991, 2DH
13.98742322.28crystaline, IliquidSteele, Chirico, et al., 1991, 2DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
43.40322.28crystaline, IliquidSteele, Chirico, et al., 1991, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Chirico, et al., 1991
Steele, W.V.; Chirico, R.D.; Nguyen, A.; Hossenlopp, I.A.; Smith, N.K., DIPPR PROJECT 871: Determination of ideal-gas enthalpies of formation for key compounds: The 1989 project results, J. Chem. Thermodyn., 1991, 101-134. [all data]

Brull, 1935
Brull, L., Sui calori di combustione di alcuni derivati del bifenil, Gazz. Chim. Ital., 1935, 65, 19-28. [all data]

Steele, Chirico, et al., 1991, 2
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A., The thermodynamic properties of 2-aminobiphenyl, J. Chem. Thermodynam., 1991, 23, 957-977. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Cumper, Ginman, et al., 1962
Cumper, C.W.N.; Ginman, R.F.A.; Vogel, A.I., Physical properties and chemical constitution. The electric dipole moments of phenyl derivatives of some n-heterocyclic molecules, J. Chem. Soc., 1962, 1962, 4518. [all data]

Steele, Chirico, et al., 1991, 3
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A., The thermodynamic properties of 2-aminobiphenyl, J. Chem. Thermodyn., 1991, 23, 957-77. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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