Hydroperoxy radical
- Formula: HO2
- Molecular weight: 33.0067
- IUPAC Standard InChIKey: OUUQCZGPVNCOIJ-UHFFFAOYSA-N
- CAS Registry Number: 3170-83-0
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, Henry's Law data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1476.9 ± 3.0 | kJ/mol | D-EA | Travers, Cowles, et al., 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1450.5 ± 3.4 | kJ/mol | H-TS | Travers, Cowles, et al., 1989 | gas phase |
Henry's Law data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Rolf Sander
Henry's Law constant (water solution)
kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)
k°H (mol/(kg*bar)) | d(ln(kH))/d(1/T) (K) | Method | Reference | Comment |
---|---|---|---|---|
5700. | R | N/A | ||
4000. | 5900. | T | N/A | |
9000. | T | N/A | ||
6600. | E | N/A | ||
9000. | T | N/A | ||
1200. | T | N/A | missing citation gives an upper limit of kH = 6.8E3 M/atm. In the abstract a range of 1E3 M/atm < kH < 3E3 M/atm is given. The mean value of this range (2E3 M/atm) has been used by missing citation, missing citation, and missing citation. | |
4600. | 4800. | T | N/A | Calculated from correlation between the polarizabilities and solubilities of stable gases. The temperature dependence is an estimate of the upper limit. |
References
Go To: Top, Reaction thermochemistry data, Henry's Law data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Travers, Cowles, et al., 1989
Travers, M.J.; Cowles, D.C.; Ellison, G.B.,
Reinvestigation of the Electron Affinities of O2 and NO,
Chem. Phys. Lett., 1989, 164, 5, 449, https://doi.org/10.1016/0009-2614(89)85237-6
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Henry's Law data, References
- Symbols used in this document:
d(ln(kH))/d(1/T) Temperature dependence parameter for Henry's Law constant k°H Henry's Law constant at 298.15K ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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