Molybdenum, tetrakis[μ-(acetato-O:O')]di-, (Mo-Mo)


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub165.0 ± 8.4kJ/molN/APilcher and Skinner, 1983See also Cavell, Garner, et al., 1979.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
129. ± 1.491.CSlyusareva, Kondrat'ev, et al., 2008 
171. ± 7.410.ME,TECarson, 1984Based on data from 400. to 420. K.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Cavell, Garner, et al., 1979
Cavell, Kingsley J.; Garner, C. David; Pilcher, Geoffrey; Parkes, Stephen, Standard enthalpies of formation of the tetra-«65533»-acetato-derivatives of dimolybdenum(II), chromium(II)?molybdenum(II), dichromium(II), and dichromium(II) dihydrate, and di-«65533»-acetato-bis(pentane-2,4-dionato)dimolybdenum(II), and their metal?metal bond enthalpy contributions, J. Chem. Soc., Dalton Trans., 1979, 11, 1714, https://doi.org/10.1039/dt9790001714 . [all data]

Slyusareva, Kondrat'ev, et al., 2008
Slyusareva, I.V.; Kondrat'ev, Yu.V.; Kozin, A.O.; Belorukova, L.P., Vestn. St. Petersburg. Universit. Ser. 4 Fiz. Khim., 2008, 3, 64. [all data]

Carson, 1984
Carson, A.S., The molar enthalpy of dehydration of Cr2(O2CCH3)4·2H2O(cr) and the molar enthalpies of sublimation of Cr2(O2CCH3)4(cr), Mo2(O2CCH3)4(cr), and Mo2(O2CCF3)4(cr), The Journal of Chemical Thermodynamics, 1984, 16, 5, 427-429, https://doi.org/10.1016/0021-9614(84)90198-8 . [all data]


Notes

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