Carbon monoxide
- Formula: CO
- Molecular weight: 28.0101
- IUPAC Standard InChIKey: UGFAIRIUMAVXCW-UHFFFAOYSA-N
- CAS Registry Number: 630-08-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Carbon oxide (CO); CO; Exhaust gas; Flue gas; Carbonic oxide; Carbon oxide; Carbone (oxyde de); Carbonio (ossido di); Kohlenmonoxid; Kohlenoxyd; Koolmonoxyde; NA 9202; Oxyde de carbone; UN 1016; Wegla tlenek; Carbon monooxide
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IR Spectrum
Go To: Top, Constants of diatomic molecules, References, Notes
Data compiled by: Coblentz Society, Inc.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Constants of diatomic molecules
Go To: Top, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through October, 1976
Symbol | Meaning |
---|---|
State | electronic state and / or symmetry symbol |
Te | minimum electronic energy (cm-1) |
ωe | vibrational constant – first term (cm-1) |
ωexe | vibrational constant – second term (cm-1) |
ωeye | vibrational constant – third term (cm-1) |
Be | rotational constant in equilibrium position (cm-1) |
αe | rotational constant – first term (cm-1) |
γe | rotation-vibration interaction constant (cm-1) |
De | centrifugal distortion constant (cm-1) |
βe | rotational constant – first term, centrifugal force (cm-1) |
re | internuclear distance (Å) |
Trans. | observed transition(s) corresponding to electronic state |
ν00 | position of 0-0 band (units noted in table) |
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
---|---|---|---|---|---|---|---|---|---|---|---|---|
Absorption in the 100 -20 Å region. K absorption of C and O. 1 | ||||||||||||
↳Nakamura, Morioka, et al., 1971 | ||||||||||||
Absorption cross sections from 650 - 180 Å. | ||||||||||||
↳Lee, Carlson, et al., 1973; Watson, Stewart, et al., 1975; Wight, van der Wiel, et al., 1976 | ||||||||||||
Several weak and fragmentary progressions in the region 620 - 530 Å (161000 - 186000 cm-1), probably corresponding to excitation of two electrons and tentatively assigned as first members of Rydberg series converging to higher electronic states of CO+ derived from the photoelectron spectrum [revised assignments Asbrink, Fridh, et al., 1974]. 2 | ||||||||||||
↳Codling and Potts, 1974 | ||||||||||||
Rydberg series converging to B 2Σ+ (v=0) of CO+ (also series or fragments if series with v'=1, 2)3: | ||||||||||||
(ndσ,π) 4 | Ogawa and Ogawa's series IV (joining on to R) | |||||||||||
ν = 158664 - R/(n-0.19)2; n = 3,4,...,10. | ||||||||||||
↳missing citation | ||||||||||||
(npσ,π) 5 | Tanaka's diffuse series (joining on to D2, D3) | |||||||||||
ν = 158664 - R/(n-0.55)2; n = 4,5,...,9. | ||||||||||||
↳missing citation; missing citation | ||||||||||||
Ogawa and Ogawa's series V (joining on to U) | ||||||||||||
ν = 158664 - R/(n-0.61)2; n = 5,6,7. | ||||||||||||
↳missing citation | ||||||||||||
Tanaka's sharp series (joining on to S1, S2) | ||||||||||||
ν = 158664 - R/(n-0.650-0.084/n-0.13/n2)2; n = 3,4,...,13. | ||||||||||||
↳missing citation; missing citation | ||||||||||||
(nsσ) 7 | Ogawa and Ogawa's series III (joining on to T6) | |||||||||||
(npσ) | ν = 158664 - R/(n-0.902-0.232/n)2; n = 4,5,...,18. | |||||||||||
↳missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
D3 | (153271) | (1705) | (18.5) | D3 ← X 8 | 153037 | |||||||
↳missing citation; missing citation | ||||||||||||
U | (153199) | [1676] | U ← X | 152955 | ||||||||
↳missing citation | ||||||||||||
D2 | (149294) | (1730) | (30) | D2 ← X 8 | 149070 | |||||||
↳missing citation; missing citation | ||||||||||||
S2 | (148929) | (1750) | (30) | S2 ← X | 148715 | |||||||
↳missing citation; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
T | (147065) | (1658) | (11) | 9 | T ← X | 146810 | ||||||
↳missing citation | ||||||||||||
R | (144939) | (1735) | (28) | 9 | R ← X | 144718 | ||||||
↳missing citation | ||||||||||||
S1 | (138038) | (1771) | (29) | 9 | S1 ← X | 137835 | ||||||
↳missing citation | ||||||||||||
Rydberg series10 converging to A 2Π(v=0) of CO+ [also series with v'=1...8 (Ogawa a. Ogawa) and v'=1,2,3 (Tanaka)]3 | ||||||||||||
(nsσ) | Ogawa and Ogawa's series 11 (joining on to W [n=3, see Ogawa and Ogawa, 1974] and O1, O2) | |||||||||||
ν = 133484(A 2Π1/2) - R/(n-1.077)2; n = 4,5,...,12. | ||||||||||||
↳missing citation | ||||||||||||
(npσ,π) | Tanaka's alpha series (joining on to P) | |||||||||||
ν = 133380(A 2Π3/2) - R/(n-0.67)2; n = 4,5,...,8. | ||||||||||||
↳missing citation; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
Q | 129043 | 1558 | 10.6 | 9 | Q ← X 10 R | 128738 | ||||||
↳Tanaka, 1942 | ||||||||||||
O2 (1Π) | 126729 | 1560 | 13.3 | O2 ← X R | 126424 | |||||||
↳missing citation; missing citation | ||||||||||||
P | 123656 | [1521] | P ← X R | 123335 | ||||||||
↳missing citation; missing citation | ||||||||||||
O1 (1Π) | 121137 | 1570 | 13.4 | 9 | O1 ← X R | 120837 | ||||||
↳Henning, 1932; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
N | (119882) | (1600) | N ← X 10 | (119600) | ||||||||
↳Henning, 1932 | ||||||||||||
Rydberg series10 converging to X 2Σ+(v=0) of CO+ [also series with v'=1]3: | ||||||||||||
npπ | Ogawa and Ogawa's series11 (joining on to E, L) | |||||||||||
νinf = 113029; formula not given, merging into npσ above n=8. | ||||||||||||
↳missing citation | ||||||||||||
npσ | Ogawa and Ogawa's series11 (joining on to C, K) | |||||||||||
νinf = 113029 - R/(n-0.615 - 0.263/n - 0.165/n2)2; n=3,4,...,32. | ||||||||||||
↳missing citation | ||||||||||||
nsσ | Lindholm's series (joining on to B, J, I') | |||||||||||
νinf = 113029; formula not given, n=3,4,...,10. | ||||||||||||
↳missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
I' (5sσ) | I' ← X | 106383 12 | ||||||||||
↳missing citation; Lindholm, 1969 | ||||||||||||
Z 1Σ+ | [(1.9)] | [(1.14)] | Z ↔ X 10 R | (105724) 13 (Z) | ||||||||
↳Tilford and Simmons, 1974 | ||||||||||||
H15 (1Π) | (105811) | (1097) | (47) | H ← X 10 14 R | 105266 | |||||||
↳Hopfield and Birge, 1927 | ||||||||||||
H' 1Π | [1.415] | [1.318] | H' ← X R | 104119.6 Z | ||||||||
↳Ogawa and Ogawa, 1974 | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
L 1Π 4pπ | 103251 | 2181 Z | (15) | [1.9812] | [0.000014] | [1.114] | L ← X V | 103271.5 Z | ||||
↳missing citation; Ogawa and Ogawa, 1974 | ||||||||||||
L' (1Π) | L' ← X R | 103215 HQ | ||||||||||
↳Ogawa and Ogawa, 1974 | ||||||||||||
K 1Σ+ 4pσ | [1.9189] | [0.000066] | [1.132] | K ← X R | 103054.3 Z | |||||||
↳missing citation; Ogawa and Ogawa, 1974 | ||||||||||||
W 1Π | [1.5585] | [0.000065] | [1.256] | W ↔ X R | 102807.1 Z | |||||||
↳Ogawa and Ogawa, 1974; Tilford and Simmons, 1974 | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
W' 1Π | [1.536] | [1.265] | W' ← X R | 102310.6 Z | ||||||||
↳missing citation | ||||||||||||
J 1Σ+ 4sσ | (101409) | [2235.3] Z | (15) | [1.9203] 16 | [0.0000058] 16 | [1.1315] 16 | J ← X R | (101456) (Z) | ||||
↳missing citation | ||||||||||||
G 1Π(3dπ) | [1.9625] | [0.000007] | [1.1193] | G ← X V | 101031 Z | |||||||
↳missing citation | ||||||||||||
G' 1Π | [(1.59)] | [1.24] | G' ← X R | 100651 | ||||||||
↳missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
h (3Σ+,4sσ) | h ← X R | (100392) (Z) | ||||||||||
↳Ogawa and Ogawa, 1974 | ||||||||||||
Y 1Σ+ | [(1.83)] | [1.16] | Y → X R | (99963) (Z) | ||||||||
↳Tilford and Simmons, 1974 | ||||||||||||
F 1Σ+(3dσ) | (99803) | [2034.4] Z | 17 | [1.86] | 18 | [0.00008] 18 | [1.15] | F ← X R | 99739 Z | |||
↳missing citation | ||||||||||||
V 1Π | [1.7] | [1.2] | V ↔ → X R | 98919 HQ | ||||||||
↳Ogawa and Ogawa, 1974; Tilford and Simmons, 1974 | ||||||||||||
A 1Π state at 98836 cm-1 reported by Tschulanovsky, 1939 was shown ( Tilford and Simmons, 1974) to be due to N2. | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
g 3Σ+ | g ← X R | (98129.1) (Z) | ||||||||||
↳Ogawa and Ogawa, 1974 | ||||||||||||
E 1Π 3pπ | (92903) | [2153.8] Z | (42) | 1.9771 19 | 0.0254 | [0.0000065] | 1.1152 | E → A V | 28185.18 20 Z | |||
↳missing citation; Kepa, Knot-Wisniewska, et al., 1975 | ||||||||||||
E ← X 21 V | 92930.03 Z | |||||||||||
↳missing citation; Ogawa and Ogawa, 1974 | ||||||||||||
c 3Π 3pπ | [93158.5] | [1.935] 22 | [-0.000131] 23 | [1.127] | c → a V | 43603.7 | ||||||
↳missing citation | ||||||||||||
c ← X V | 92076.9 Z | |||||||||||
↳missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
C 1Σ+ 3pσ | 91916.5 | 2175.92 Z | 14.76 24 | 1.9533 25 | 0.0196 | 0.0000062 | 1.1219 | C → A 26 27 V | 27174.4 20 Z | |||
↳Schmid and Gero, 1935 | ||||||||||||
C ↔ X 26 28 V | 91919.15 Z | |||||||||||
↳Tilford and Vanderslice, 1968; Aarts and de Heer, 1970 | ||||||||||||
j (3Σ+3pσ) | 90975 | [2166] Z | (15) | [1.8785] 29 | (0.02) | [0.0000079] | [1.1441] | j ← X R | 90988.04 Z | |||
↳Tilford and Vanderslice, 1968 | ||||||||||||
30 | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
k | [90972] 31 | k → a V | 41417 H | |||||||||
↳Kaplan, 1930 | ||||||||||||
B 1Σ+ 3sσ | 86945.2 | 2112.7 Z | 15.22 32 | 1.9612 33 | 0.0261 | 0.0000071 | 1.1197 | B → A 34 35 V | 22171.35 20 Z | |||
↳Schmid and Gero, 1935 | ||||||||||||
B → X 34 36 V | 86916.16 Z | |||||||||||
↳missing citation; Aarts and de Heer, 1970 | ||||||||||||
b 3Σ+ 3sσ | (83814) | 2199.3 Z | 1.986 37 38 | 0.042 | 1.113 | b → a 39 40 V | 35358.5 Z | |||||
↳Dieke and Mauchly, 1933; Gero, 1936; Beer, 1937 | ||||||||||||
b ← X 40 V | 83831.7 H | |||||||||||
↳Hopfield and Birge, 1927 | ||||||||||||
f (3Σ+) | This state, first suggested by Schmid and Gero, 1937 and listed by missing citation at T0 = 83744, is in all probability not a separate state but represents v = 31 and 35 of a' 3Σ+.41 | |||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
D 1Δ | 65928 | 1094 | 10.2 | 1.257 | 0.017 | 1.399 | D ← X R | 65391 42 | ||||
↳missing citation; Simmons and Tilford, 1971; Tilford and Simmons, 1972 | ||||||||||||
I 1Σ- | 65084.40 | 1092.22 | 10.704 43 | 1.2705 44 | 0.01848 45 | D2 = 9.0E-6 | 1.3911 | I ← X R | 64546.26 Z | |||
↳missing citation; Simmons and Tilford, 1971; missing citation | ||||||||||||
A 1Π | 65075.77 | 1518.24 | 19.4 46 | 1.6115 47 | 0.02325 48 | 0.00000733 49 | 1.2353 | A ↔ X 50 51 52 R | 64748.48 53 Z | |||
↳missing citation; missing citation | ||||||||||||
e 3Σ- | 64230.24 | 1117.72 | 10.686 54 | 1.2836 55 | 0.01753 56 | 0.00000677 57 | 1.384 | e → a 58 R | 15231.6 | |||
↳missing citation; Barrow, 1961 | ||||||||||||
e ← X T | 63704.85 Z | |||||||||||
↳missing citation; Simmons and Tilford, 1971; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
d 3Δi | 61120 59 | 1171.94 | 10.635 60 | 1.3108 61 | 0.01782 62 | 0.00000659 57 | 1.3696 | d → a 63 58 R | 12148.7 | |||
↳Gero and Szabo, 1939; Carroll, 1962; Slanger and Black, 1970 | ||||||||||||
d ← X R | 60621.9 60 Z | |||||||||||
↳Herzberg, Hugo, et al., 1970; missing citation | ||||||||||||
a' 3Σ+ | 55825.49 | 1228.6 | 10.468 64 | 1.3446 65 | 0.01892 66 | 0.00000641 57 | 1.3523 | a' → a 67 68 R | 6882.4 | |||
↳Asundi, 1929; Beer, 1937; Gero and Lorinezi, 1939 | ||||||||||||
a' ← X 68 R | 55355.6 Z | |||||||||||
↳missing citation; Simmons and Tilford, 1971; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
a 3Πr | 48686.7 69 | 1743.41 | 14.36 70 | 1.69124 71 | 0.01904 72 | 0.00000636 73 | 1.20574 | a ↔ X 74 75 R | 48473.22 70 | |||
↳missing citation; Field, Tilford, et al., 1972; missing citation | ||||||||||||
X 1Σ+ | 0 | 2169.81358 | 13.28831 76 | 1.93128087 77 | 0.01750441 78 | 6.12147E-06 79 | 1.128323 80 81 | |||||
3-0 | ||||||||||||
↳Bouanich, Levy, et al., 1967; Bouanich, Levy, et al., 1968; Bouanich and Brodbeck, 1974 | ||||||||||||
2-082 | ||||||||||||
↳Mantz and Maillard, 1974 | ||||||||||||
1-083 | ||||||||||||
↳Rank, Skorinko, et al., 1960; Rao, Humphreys, et al., 1966 | ||||||||||||
Rotation sp.: | ||||||||||||
Far IR sp. 84 | ||||||||||||
↳Loewenstein, 1960 | ||||||||||||
Microwave sp. | ||||||||||||
↳Rosenblum, Nethercot, et al., 1958; Helminger, De Lucia, et al., 1970; Lovas and Krupenie, 1974 | ||||||||||||
Molecular beam el. reson.85 | ||||||||||||
↳Muenter, 1975 | ||||||||||||
Mol. beam magn. reson.86 | ||||||||||||
↳Ozier, Yi, et al., 1967; Ozier, Crapo, et al., 1968 |
Notes
1 | Preceding the two K limits (see 88) are strong Rydberg series of absorption bands. The longest-wavelength absorptions correspond to excitation to the 2π orbital yielding a weak 3Π ← X 1Σ+ and a strong 1Π ← X 1Σ+ peak at 283 and 285 eV for the transitions from lsC and at 529 and 532 eV for the transitions from 1s0 Nakamura, Morioka, et al., 1971. The transitions to the 1Π states have also been observed in electron impact experiments at 287.7 and 534.4 eV van der Wiel, El-Sherbini, et al., 1970. |
2 | Dissociation produced by absorption in these bands and subsequent atomic fluorescence Lee, Carlson, et al., 1975; predissociation into C+ + O- Locht and Durer, 1975. |
3 | Calcu1ated Franck-Condon factors for ionization: X 2Σ+ ← X 1Σ+, A 2Π ← 1Σ+, and B 2Σ+ ← X 1Σ+, see Krupenie and Benesch, 1968 and Nicholls, 1968. Observed Franck-Condon factors from photoelectron spectrum Turner and May, 1966, Comes and Speier, 1971, Gardner and Samson, 1974; absolute ionization cross-sections Judge and Lee, 1972, Samson and Gardner, 1976. |
4 | Tanaka's diffuse series (joining on to D2, D3) |
5 | Ogawa and Ogawa's series III (joining on to T6) |
6 | The progression P5 of Tanaka, 1942 [called T in MOLSPEC 1 and missing citation] must be reclassified as representing the members n=6, 7, and 9 of series III; see the spectrograms of Tanaka, 1942 and Ogawa and Ogawa, 1972. |
7 | ν = 158664 - R/(n-0.902-0.232/n)2; n = 4,5,...,18. |
8 | Diffuse looking bands. |
9 | Preionization observed in electro-ionization of CO Carbonneau and Marmet, 1973. |
10 | Absorption and photoionization coefficients from 1000 to 600 Å Cook, Metzger, et al., 1965. |
11 | These series and progressions from the high resolution work of Ogawa and Ogawa, 1972 agree only partially with the early work Tanaka, 1942, Takamine, Tanaka, et al., 1943 at lower resolution. |
12 | This strong absorption band is clearly present but not assigned on the spectrogram of Ogawa and Ogawa, 1972. |
13 | An absorption band at this wavenumber is visible but not identified on the published spectrogram of Ogawa and Ogawa, 1972. |
14 | This is the strongest system of Hopfield and Birge, 1927. It is clearly present on the reproduction of Ogawa and Ogawa, 1972, but these authors consider the first band at 950 Å as due to v'=1 of K(4pσ)←X. Do not assign the second (strongest) band at 941 Å and consider the third band at 933 Å as n=5, v'=0 of the Rydberg series which starts with C(3pσ) and E(3pπ). |
15 | Previously called G [see missing citation]. The present G 1Π is from Ogawa and Ogawa, 1974. |
16 | v=0 diffuse by predissociation, v=1 sharp. The rotational constants are for v=1 Ogawa and Ogawa, 1974. |
17 | Jevons, 1932 gives ωe = 2112 Jevons, 1932, ωexe = 198 Jevons, 1932, presumably from private communication by Hopfield-Birge. |
18 | B1 = 1.837, D1 = 3E-6. |
19 | Clear case of accidental predissociation for J=31 (e level) at 94872 cm-1 above v=0, J=0 of X 1Σ+ Simmons and Tilford, 1974. |
20 | The ν00 values for B→A, C→A, E→A are not deperturbed and, therefore, do not add up with the deperturbed ν00 for A-X (see also 53) to the ν00 values listed for B-X, C-X, and E-X. |
21 | Oscillator strength f00 = 0.094 Lassettre and Skerbele, 1971. |
22 | Λ-type doubling, Δν = 0.011N(N+1). Triplet splitting unobservably small as for most Rydberg states. |
23 | H0 = -1.9E-7. The rotational constants represent average values for the two Λ-doubling components. |
24 | Only v=0 and 1 observed in absorption, only v=0 in emission. ωe, ωexe derived with the aid of isotope (12,13CO) data, see Tilford and Vanderslice, 1968. |
25 | μel = 4.5 D Fisher and Dalby, 1976, from Stark effect observations on the Herzberg bands Fisher and Dalby, 1976. |
26 | Lifetime τ(v=0) = 1.5 ns Hesser, 1968, Dotchin and Chupp, 1973; electronic branching ratios Dotchin and Chupp, 1973. |
27 | Kepa, 1969 and Asundi, Dhumwad, et al., 1970 have studied the bands of the isotopic molecules 13C16O and 12C18O. |
28 | Osci1lator strength f00 = 0.163 Lassettre and Skerbele, 1971. |
29 | Rotational lines are diffuse because of predissociation. |
30 | In the electron energy loss spectrum Swanson, Celotta, et al., 1975 find a peak at 90858 cm-1 which, according to them, cannot be identified with the j 3Σ+ state. |
31 | single 0-v" progression. |
32 | Only two vibrational levels observed, ΔG(1/2) = 2082.26. ωe, ωexe derived with the aid of isotope data Tilford and Vanderslice, 1968. |
33 | A partial breaking off of the rotational structure in the Å bands occurs above J=37 in v'=0 and above J=17 in v'=1 leading to a dissociation limit at 89595 ± 30 cm-1 Douglas and Moller, 1955. RKR potential missing citation. μel = 1.60 D Fisher and Dalby, 1976 from Stark effect measurements on the Å bands Fisher and Dalby, 1976. |
34 | Lifetime τ(v=0) = 21.8 ns Imhof, Read, et al., 1972, good agreement with Hesser, 1968, Rogers and Anderson, 1970, Dotchin and Chupp, 1973. τ(v=1) = 15.5 ns Imhof, Read, et al., 1972; Rogers and Anderson, 1970 give 23.8 ns. Electronic branching ratios Dotchin and Chupp, 1973. |
35 | Franck-Condon factors missing citation. Kepa and Rytel, 1970 have studied the rotational structure in the Å bands of the isotopic molecules 12C18O, 13C16O, 13C18O and the perturbations in these isotopes as well as in 12C16O; see also Douglas and Moller, 1955, Janjic, Pesic, et al., 1969. |
36 | Oscillator strength f00 = 0.0153 Lassettre and Skerbele, 1971. Discussion of the r-dependence of the transition moment Imhof, Read, et al., 1972. |
37 | This state is strongly perturbed by the higher vibrational levels of the a' 3Σ+ state (near its dissociation limit). Dieke and Mauchly, 1933 derived B0 = 1.89 from lines with N values between 7 and 15. Gero, 1935 from deperturbed term values derived B0 = 2.058 ; Schmid and Gero, 1935, 2 gave α = 0.033 Schmid and Gero, 1935, 2. The listed values of Be and αe are from a revised deperturbation by Stepanov, 1940 who also gives the deperturbed constants ΔG(1/2) = 2188 Stepanov, 1940 and τ0 = 83816 Stepanov, 1940. |
38 | Only two vibrational levels, v=0 and 1, have been observed. Breaking off on account of predissociation in v=0 above N=55, in v=1 above N=42 Gero, 1935, Gero, 1936. The absence of v=2 is puzzling since it is expected to lie below the dissociation limit Barrow, Gratzer, et al., 1956. |
39 | Lifetimes τ(v=0) =53.6 ns Rogers and Anderson, 1970, 2, Smith, Imhof, et al., 1973, τ(v=1) = 69.1 ns Rogers and Anderson, 1970, 2, Smith, Imhof, et al., 1973. |
40 | Franck-Condon factors missing citation. |
41 | This interpretation was first suggested by Gero, 1938. It is in agreement with the data of Tilford and Simmons, 1972 on the a'-X system. The occurrence of these particular vibrational levels of a' 3Σ+ in the emission spectrum is due to strong interaction with b 3Σ+. Indeed, the levels mentioned were observed as "extra" bands accompanying the b 3Σ+ → a 3Π (third positive) bands. |
42 | Extrapo1ated, only v'=1, 6, 21 observed. |
43 | ωexe= +0.0554(v+1/2)3- ...; for higher order coefficients see Tilford and Simmons, 1972. |
44 | RKR potential Tilford and Simmons, 1972. |
45 | αv= +0.000291(v+1/2)2 - + ...; for higher order coefficients see Tilford and Simmons, 1972. Revised coefficients from deperturbed Bv values in Field, 1971. |
46 | missing note |
47 | Numerous perturbations produced by e 3Σ-, d 3Δ, a' 3Σ+, D 1Δ, I 1Σ-, discussed by many investigators and summarized in Simmons, Bass, et al., 1969. Deperturbed Tv and Bv values are given by Field, Wicke, et al., 1972, see also Field, 1971. RKR potential Tilford and Simmons, 1972; the potential function has a maximum, the last observed level lies above the dissociation limit. |
48 | αv= +0.00159(v+1/2)2 - + ...; higher order coefficients in Tilford and Simmons, 1972, revised coefficients from deperturbed B values in Field, 1971. |
49 | Calculated value, βe = +0.10E-6; see Field, Wicke, et al., 1972. |
50 | Lifetimes Hesser, 1968, Imhof and Read, 1971, Burnham, Isler, et al., 1972 : τ=10.7 ns; v=0, τ=10.4 ns; v=1, τ=9.4 ns; v=2, τ=9.0 ns; v=3, τ=9.7 ns; v=4, τ=9.8 ns; v=5, τ=10.5 ns;v=6. Values that are about 50% larger were given by Chervenak and Anderson, 1971. |
51 | Oscillator strength fel = 0.195 Lassettre and Skerbele, 1971, f00 = 0.020 Lassettre and Skerbele, 1971. f values from lifetime measurements Hesser, 1968 are approximately a factor of 2 smaller. See also Mumma, Stone, et al., 1971 [r-dependence of electronic transition moment, fel ~ 0.15 Mumma, Stone, et al., 1971] and Pilling, Bass, et al., 1971, Vargin, Pasynkova, et al., 1973. Franck-Condon factors Halmann and Laulicht, 1966, missing citation, Shimauchi, 1976. |
52 | See Shvangiradze, Oganezov, et al., 1960, Rytel and Siwiec, 1973 for spectroscopic data on 13CO and C18O. |
53 | This is a nominal, rotationally deperturbed value. The lowest observed levels (v=0, J=1) lie at 64747.90(-) and at 64748.09(+) which would correspond to a J=0 level at 64744.8 cm-1. |
54 | ωexe= +0.1174(v+1/2)3- + ... Tilford and Simmons, 1972; from Tilford and Simmons, 1972, see also Field, 1971. |
55 | Spin-splitting constant λ0= +0.51; for its dependence on v see Field, 1971, Field and Lefebvre-Brion, 1974. RKR potential Tilford and Simmons, 1972. |
56 | αv= +7.1E-6(v+1/2)2 + - ...; the coefficients are from Tilford and Simmons, 1972, but considerably different values for the higher order terms were obtained by Field, 1971 from deperturbed rotational constants. |
57 | Calculated value, see Field, 1971. |
58 | Intensity distribution, relative electronic transition moments: e→a Slanger and Black, 1976, d→a Slanger and Black, 1972. Franck-Condon factors; d→a missing citation. Rotational intensity distribution in the "triplet" bands Kovacs and Toros, 1965. |
59 | Av = -16.005 - 0.113(v+1/2) - 0.00357(v+1/2)2 Field, 1971. |
60 | ωexe= +0.0785(v+1/2)3-0.001634(v+1/2)4 Tilford and Simmons, 1972. The constants refer to the 3Δ2 component Tilford and Simmons, 1972; see also Field, 1971. |
61 | RKR potential Tilford and Simmons, 1972. |
62 | αv= +0.000113(v+1/2)2 Tilford and Simmons, 1972. The constants refer to the 3Δ2 component Tilford and Simmons, 1972. From properly averaged term values of v=3,4,7,9 Carroll, 1962 gives Be = 1.3099 Carroll, 1962, αe = 0.01677 Carroll, 1962 in good agreement with the first two of the expansion coefficients determined by Field, 1971. |
63 | Lifetime strongly dependent on J and Ω because of perturbations by A 1Π Slanger and Black, 1973. |
64 | ωexe= +0.0091(v+1/2)3 + 0.00259(v+1/2)4- + ... Tilford and Simmons, 1972. Revised coefficients from deperturbed Tv values in Field, 1971. |
65 | Spin-splitting constants λ0 = -1.23, γ0 ~ -0.007; dependence on v Field, 1971, Field and Lefebvre-Brion, 1974. See also Sink, Lefebvre-Brion, et al., 1975. Dipole moment μel = 1.06 D (-CO+), from the radiofrequency spectrum of a3Π; see Wicke, Field, et al., 1972, Wicke, Klemperer, et al., 1975. RKR potential Tilford and Simmons, 1972. |
66 | αv= +0.000345(v+1/2)2 - + ... Tilford and Simmons, 1972; revised coefficients from deperturbed Bv values in Field, 1971. |
67 | Lifetime τ= 3.7 to 2.9 μs; v=5 to 8 Hartfuss and Schmillen, 1968. |
68 | Franck-Condon factors Halmann and Laulicht, 1966, missing citation. |
69 | Av =+ 41.53 - 0.14(v+1/2) - 0.009(v+1/2)2; AJ(v=0) = -0.000206. |
70 | ωexe= -0.045(v+1/2)3 + 0.0025(v+1/2)4; all vibrational and rotational constants for this state are from deperturbed levels Field, Tilford, et al., 1972, Field, Wicke, et al., 1972. |
71 | Very precise values for the Λ-type doubling in 3Π1 and 3Π2, v=0-7, J=1-8, have been obtained Stern, Gammon, et al., 1970, Gammon, Stern, et al., 1971, Wicke, Field, et al., 1972, Wicke, Klemperer, et al., 1975 from the study of the radiofrequency spectrum in a molecular beam electric resonance apparatus. While these doublings are small and increase rapidly with J the Λ-doubling for 3Π0 [from combination defects Dieke and Mauchly, 1933, Freund and Klemperer, 1965] is fairly large at low J (~1.7 cm-1) and decreases with J. Hyperfine structure in 13C16O Gammon, Stern, et al., 1971, 2. Dipole moment (+CO-) from molecular beam electric resonance spectrum μel(v=0) = 1.374 D Wicke, Field, et al., 1972; dipole moment function and radiative lifetimes for vibrational transitions in a 3Π Wicke and Klemperer, 1975, Wicke and Klemperer, 1975, 2. |
72 | αv= -0.000041(v+1/2)2; see β. |
73 | Calculated value, βe = +0.04E-6 Field, Tilford, et al., 1972, Field, Wicke, et al., 1972. |
74 | Lifetime from time of flight studies τ= ~9.5 ms Johnson, 1972; from afterglow decay τ= 7.5 ms Lawrence, 1971, Wauchop and Broida, 1972; theoretical values James, 1971. |
75 | missing note |
76 | ωexe= +0.010511(v+1/2)3 + 5.74E-5(v+1/2)4 + 9.83E-7(v+1/2)5 - 3.166E-8(v+1/2)6; v≤37 Mantz and Maillard, 1975. |
77 | RKR potential functions Mantz, Watson, et al., 1971, Dickinson, 1972, Fleming and Rao, 1972. |
78 | αv= +5.487E-7(v+1/2)2 + 2.54E-8(v+1/2)3 Mantz and Maillard, 1975. |
79 | Dv= -1.153E-9(v+1/2) + 1.805E-10(v+1/2)2 Mantz and Maillard, 1975; Hv = [5.83 - 0.1738(v+1/2)]E-12 Mantz and Maillard, 1975. |
80 | From the effective Be value; the "true" Be = 1.93160 Bunker, 1970 found by Bunker, 1970 after introducing adiabatic and non-adiabatic corrections (and using older data) leads to re = 1.12823 Å 469. See also Bunker, 1972, Watson, 1973. |
81 | Rot.-vibr. sp. 96, 97: |
82 | Δv=2 sequence up to 33-31 in chemiluninescence Schwartz and Thrush, 1969 and flames Mantz and Maillard, 1974. |
83 | Δv=1 sequence up to 37-36 in the CO laser Mantz, Nichols, et al., 1970, Yardley, 1970, Kildal, Eng, et al., 1974; 1-0 band in resonance fluorescence Millikan, 1963, McCaa and Williams, 1964. |
84 | Line widths and intensities Dowling, 1969, Sanderson, Scott, et al., 1971. High pressure gas and liquid far IR absorption spectra in Ar Buontempo, Cunsolo, et al., 1973; the quadrupole moment derived from this and other experimental and theoretical work [see Billingsley and Krauss, 1974] is Qm= -2.0E-26 esu cm2. |
85 | μel(v=0, J=0) = 0.10980 D (-CO+); with the dipole moment function of Toth, Hunt, et al., 1969 (see 97) this gives 0.1222 D at re Muenter, 1975. |
86 | gJ = -0.26890 μN Ozier, Yi, et al., 1967 for 12C16O Ozier, Yi, et al., 1967; gJ = -0.25691 μN Ozier, Crapo, et al., 1968 for 13C16O Ozier, Crapo, et al., 1968. |
87 | From the predissociation in the B 1Σ+ state (see 33). The uncertainty of ±0.017 eV corresponds to the uncertainty as to which combination of 3P component states arises at the dissociation limit. |
88 | From Rydberg series Ogawa and Ogawa, 1972. For the second and third I.P. (1π and 4σ orbitals) see the higher Rydberg limits in the Table. The fourth, fifth, and sixth I.P. (3σ, 2σ, 1σ) have been determined from X-ray photoelectron spectroscopy to be 38.9, 296.24 (K limit of C), and 542.57 eV. (K limit of O), respectively Siegbahn, Nordling, et al., 1969, Thomas, 1970, Smith and Thomas, 1976. See also 3. |
89 | Absorption and photoionization coefficients from 1000 to 600 Å Cook, Metzger, et al., 1965. |
90 | Calcu1ated Franck-Condon factors for ionization: X 2Σ+ ← X 1Σ+, A 2Π ← 1Σ+, and B 2Σ+ ← X 1Σ+, see Krupenie and Benesch, 1968 and Nicholls, 1968. Observed Franck-Condon factors from photoelectron spectrum Turner and May, 1966, Comes and Speier, 1971, Gardner and Samson, 1974; absolute ionization cross-sections Judge and Lee, 1972, Samson and Gardner, 1976. |
91 | cf. Ogawa and Ogawa's Rydberg series converging to A 2Π1/2. |
92 | The b→a bands with v'=1 were previously called "5B" bands Asundi, 1929. |
93 | Lifetime of this state (and/or D 1Δ) 97 ± 15 μs Wells, Borst, et al., 1973. |
94 | ωexe= +0.766(v+1/2)3 - + ...; higher order coefficients in Tilford and Simmons, 1972. Because of numerous perturbations (see 95) these constants do not accurately represent the observed (v≤23) vibrational levels. Revised coefficients from deperturbed Tv values [see Field, Wicke, et al., 1972] in Field, 1971. |
95 | Franck-Condon factors Halmann and Laulicht, 1966, missing citation. |
96 | For data on 13C16O, 12C18O, 13C18O see Johns, McKellar, et al., 1974, Chen, Rao, et al., 1976. |
97 | Intensities in 1-0, 2-0, 3-0 rotation-vibration bands and dipole moment function Young and Eachus, 1966, Toth, Hunt, et al., 1969, Moskalenko and Mirumyants, 1971, Roux, Effantin, et al., 1972, Billingsley and Krauss, 1974, 2, Bouanich and Brodbeck, 1974, 2, Varanasi and Sarangi, 1975 Tipping, 1976; for Δv=1 transitions with v=4-10 Weisbach and Chackerian, 1973. Pressure shift and pressure broadening Hunt, Toth, et al., 1968, Hoover and Williams, 1969, Bouanich, Larvor, et al., 1969, Bouanich and Brodbeck, 1974, Varanasi, 1975, Moskalenko, 1975. |
References
Go To: Top, IR Spectrum, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
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Swanson, Celotta, et al., 1975
Swanson, N.; Celotta, R.J.; Kuyatt, C.E.; Cooper, J.W.,
Resonant structure in electron impact excitation of CO near threshold,
J. Chem. Phys., 1975, 62, 4880. [all data]
Douglas and Moller, 1955
Douglas, A.E.; Moller, C.K.,
Predissociations of the C12O and C13O molecules,
Can. J. Phys., 1955, 33, 125. [all data]
Imhof, Read, et al., 1972
Imhof, R.E.; Read, F.H.; Beckett, S.T.,
Determination of the transition moment of the B1Σ+-x1Σ+ transition in CO,
J. Phys. B:, 1972, 5, 896. [all data]
Rogers and Anderson, 1970
Rogers, J.; Anderson, R.,
Radiative lifetime of the B1Σ+ state of CO,
J. Opt. Soc. Am., 1970, 60, 278. [all data]
Kepa and Rytel, 1970
Kepa, R.; Rytel, M.,
On the angstrom bands of 12C16O,
Acta Phys. Pol., 1970, 37, 585. [all data]
Janjic, Pesic, et al., 1969
Janjic, F.D.; Pesic, D.S.; Jankovic, D.S.,
The angstrom band system of the 12C18O molecule,
Bull. Soc. Chim. Beograd., 1969, 34, 301. [all data]
Gero, 1935
Gero, L.,
Storung und pradissoziation im b3Σ-term des CO-bandenspektrums,
Z. Phys., 1935, 95, 747. [all data]
Schmid and Gero, 1935, 2
Schmid, R.; Gero, L.,
Zur struktur der 5 B-banden des CO-spektrums,
Z. Phys., 1935, 96, 198. [all data]
Stepanov, 1940
Stepanov, B.I.,
On the calculation of constants of the level b3Σ in molecule CO,
J. Phys. (USSR), 1940, 2, 197. [all data]
Barrow, Gratzer, et al., 1956
Barrow, R.F.; Gratzer, W.B.; Malherbe, J.F.,
Intensities of bands in the system b3Σ+-a3Π of carbon monoxide,
Proc. Phys. Soc. London Sect. A, 1956, 69, 574. [all data]
Rogers and Anderson, 1970, 2
Rogers, J.; Anderson, R.,
Radiative lifetime of the b3Σ+ state of CO,
J. Quant. Spectrosc. Radiat. Transfer, 1970, 10, 515. [all data]
Smith, Imhof, et al., 1973
Smith, A.J.; Imhof, R.E.; Read, F.H.,
Measured lifetimes of the two vibrational levels of the b3Σ+ state of CO,
J. Phys. B:, 1973, 6, 1333. [all data]
Gero, 1938
Gero, L.,
Rotationsanalyse von a'3Σ+ → a3Π-banden des CO,
Z. Phys., 1938, 109, 216. [all data]
Field, 1971
Field, R.W.,
Thesis, Harvard University, Massachusetts, 1971, 0. [all data]
Simmons, Bass, et al., 1969
Simmons, J.D.; Bass, A.M.; Tilford, S.G.,
The fourth positive system of carbon monoxide observed in absorption at high resolution in the vacuum ultraviolet region,
Astrophys. J., 1969, 155, 345. [all data]
Field, Wicke, et al., 1972
Field, R.W.; Wicke, B.G.; Simmons, J.D.; Tilford, S.G.,
Analysis of perturbations in the a3Π and A1Π states of CO,
J. Mol. Spectrosc., 1972, 44, 383. [all data]
Imhof and Read, 1971
Imhof, R.E.; Read, F.H.,
Measured lifetimes of the first seven vibrational levels of the A1Π state of CO,
Chem. Phys. Lett., 1971, 11, 326. [all data]
Burnham, Isler, et al., 1972
Burnham, R.L.; Isler, R.C.; Wells, W.C.,
Zero-field level-crossing spectroscopy of the A1Π state of carbon monoxide,
Phys. Rev. A: Gen. Phys., 1972, 6, 1327. [all data]
Chervenak and Anderson, 1971
Chervenak, J.G.; Anderson, R.A.,
Radiative lifetime of the A1Π state of CO,
J. Opt. Soc. Am., 1971, 61, 952. [all data]
Mumma, Stone, et al., 1971
Mumma, M.J.; Stone, E.J.; Zipf, E.C.,
Excitation of the CO fourth positive band system by electron impact on carbon monoxide and carbon dioxide,
J. Chem. Phys., 1971, 54, 2627. [all data]
Pilling, Bass, et al., 1971
Pilling, M.J.; Bass, A.M.; Braun, W.,
A curve of growth determination of the f-values for the fourth positive system of CO and the Lyman-Birge-Hopfield system of N2,
J. Quant. Spectrosc. Radiat. Transfer, 1971, 11, 1593. [all data]
Vargin, Pasynkova, et al., 1973
Vargin, A.N.; Pasynkova, L.M.; Trekhov, E.S.,
Measurement of |Re|2 for the 4+ system of CO,
J. Appl. Spectrosc. Engl. Transl., 1973, 13, 1340, In original 662. [all data]
Halmann and Laulicht, 1966
Halmann, M.; Laulicht, I.,
Isotope effects on vibrational transition probabilities. IV. Electronic transitions of isotopic C2, CO, CN, H2, and CH molecules,
Astrophys. J. Suppl. Ser., 1966, 12, 307. [all data]
Shimauchi, 1976
Shimauchi, M.,
Franck-Condon factors and r-centroids for the A1Π-X1Σ systems of CO and NO+,
Sci. Light (Tokyo), 1976, 25, 1. [all data]
Shvangiradze, Oganezov, et al., 1960
Shvangiradze, R.R.; Oganezov, K.A.; Chikhladze, B.Ya.,
Isotopic band shifts in the electronic-vibrational spectra of some diatomic molecules,
Opt. Spectrosc. Engl. Transl., 1960, 8, 239. [all data]
Rytel and Siwiec, 1973
Rytel, M.; Siwiec, T.,
Perturbations in the spectra of CO isotopic molecules. I. Partial analysis of e3Σ- - A1Π perturbations,
Acta Phys. Pol., 1973, 44, 67. [all data]
Field and Lefebvre-Brion, 1974
Field, R.W.; Lefebvre-Brion, H.,
On the effective spin-spin constants of some states of diatomic molecules. Application to the CO molecule,
Acta Phys. Acad. Sci. Hung., 1974, 35, 51. [all data]
Slanger and Black, 1976
Slanger, T.G.; Black, G.,
Relative electronic transition moments for the e3Σ--a3Π Herman system of CO,
J. Chem. Phys., 1976, 64, 219. [all data]
Slanger and Black, 1972
Slanger, T.G.; Black, G.,
Relative electronic transition moments for the triplet system (d3Δ → a3Π) of CO,
J. Phys. B:, 1972, 5, 1988. [all data]
Kovacs and Toros, 1965
Kovacs, I.; Toros, R.,
The intensity distribution of the triplet bands of the CO molecule,
Acta Phys. Hung., 1965, 18, 101. [all data]
Slanger and Black, 1973
Slanger, T.G.; Black, G.,
Relaxation processes in excited CO states. I. Spin multiplet relaxation and radiative lifetimes of CO(d3Δ)v=5,
J. Chem. Phys., 1973, 58, 194. [all data]
Sink, Lefebvre-Brion, et al., 1975
Sink, M.L.; Lefebvre-Brion, H.; Hall, J.A.,
Ab initio calculations of the effective spin-spin constants of the 3Σ excited states of the N2 and CO molecules,
J. Chem. Phys., 1975, 62, 1802. [all data]
Wicke, Field, et al., 1972
Wicke, B.G.; Field, R.W.; Klemperer, W.,
Fine structure, dipole moment, and perturbation analysis of a3Π CO,
J. Chem. Phys., 1972, 56, 5758. [all data]
Wicke, Klemperer, et al., 1975
Wicke, B.G.; Klemperer, W.; Field, R.,
Lambda doublings and electric dipole moments of v = 6 and 7 a3Π carbon monoxide,
J. Chem. Phys., 1975, 62, 3544. [all data]
Hartfuss and Schmillen, 1968
Hartfuss, H.J.; Schmillen, A.,
Uber das Abklingen der ersten positiven Gruppe des N2 und der Asundi-Banden des CO,
Z. Naturforsch. A, 1968, 23, 722. [all data]
Stern, Gammon, et al., 1970
Stern, R.C.; Gammon, R.H.; Lesk, M.E.; Freund, R.S.; Klemperer, W.A.,
Fine structure and dipole moment of metastable a3Π carbon monoxide,
J. Chem. Phys., 1970, 52, 3467. [all data]
Gammon, Stern, et al., 1971
Gammon, R.H.; Stern, R.C.; Klemperer, W.,
Molecular-beam electric-resonance spectroscopy of the a3Π (v = 4)-a'3Σ+ (v' = O) perturbation in CO,
J. Chem. Phys., 1971, 54, 2151. [all data]
Freund and Klemperer, 1965
Freund, R.S.; Klemperer, W.,
Radio-frequency spectrum of the a3Π state of carbon monoxide,
J. Chem. Phys., 1965, 43, 2422. [all data]
Gammon, Stern, et al., 1971, 2
Gammon, R.H.; Stern, R.C.; Lesk, M.E.; Wicke, B.G.; Klemperer, W.,
Metastable a 3Π 13CO: molecular-beam electric-resonance measurements of the fine structure, hyperfine structure, and dipole moment,
J. Chem. Phys., 1971, 54, 2136. [all data]
Wicke and Klemperer, 1975
Wicke, B.G.; Klemperer, W.,
On the experimentally determined dipole moment function of CO a3Π,
Mol. Phys., 1975, 30, 1021. [all data]
Wicke and Klemperer, 1975, 2
Wicke, B.G.; Klemperer, W.,
Experimental dipole moment function and calculated radiative lifetimes for vibrational transitions in carbon monoxide a3Π,
J. Chem. Phys., 1975, 63, 3756. [all data]
Johnson, 1972
Johnson, C.E.,
Lifetime of CO(a3Π) following electron impact dissociation of CO2,
J. Chem. Phys., 1972, 57, 576. [all data]
Lawrence, 1971
Lawrence, G.M.,
Quenching and radiation rates of CO (a3Π),
Chem. Phys. Lett., 1971, 9, 575. [all data]
Wauchop and Broida, 1972
Wauchop, T.S.; Broida, H.P.,
Lifetime and quenching of CO(a3Π) produced by recombination of CO2 ions in a helium afterglow,
J. Chem. Phys., 1972, 56, 330. [all data]
James, 1971
James, T.C.,
Transition moments, Franck-Condon factors, and lifetimes of forbidden transitions. Calculation of the intensity of the Cameron system of CO,
J. Chem. Phys., 1971, 55, 4118. [all data]
Mantz and Maillard, 1975
Mantz, A.W.; Maillard, J.P.,
Ground state molecular constants of 12C16O,
J. Mol. Spectrosc., 1975, 57, 155. [all data]
Mantz, Watson, et al., 1971
Mantz, A.W.; Watson, J.K.G.; Rao, K.N.; Albritton, D.L.; Schmeltekopf, A.L.; Zare, R.N.,
Rydberg-Klein-Rees potential for the X1Σ+ state of the CO molecule,
J. Mol. Spectrosc., 1971, 39, 180. [all data]
Dickinson, 1972
Dickinson, A.S.,
A new method for evaluating Rydberg-Klein-Rees intergrals,
J. Mol. Spectrosc., 1972, 44, 183. [all data]
Fleming and Rao, 1972
Fleming, H.E.; Rao, K.N.,
A simple numerical evaluation of the Rydberg-Klein-Rees integrals: application to X1Σ+ state of 12C16O,
J. Mol. Spectrosc., 1972, 44, 189. [all data]
Bunker, 1970
Bunker, P.R.,
The effect of the breakdown of the Born-Oppenheimer approximation on the determination of Be and ωe for a diatomic molecule,
J. Mol. Spectrosc., 1970, 35, 306-313. [all data]
Bunker, 1972
Bunker, P.R.,
On the breakdown of the Born-Oppenheimer approximation for a diatomic molecule,
J. Mol. Spectrosc., 1972, 5, 478. [all data]
Watson, 1973
Watson, J.K.G.,
The isotope dependence of the equilibrium rotational constants in 1Σ states of diatomic molecules,
J. Mol. Spectrosc., 1973, 45, 99. [all data]
Schwartz and Thrush, 1969
Schwartz, S.E.; Thrush, B.A.,
Energies of vibrational levels 22 to 33 of carbon monoxide X1Σg+,
J. Mol. Spectrosc., 1969, 32, 343. [all data]
Mantz, Nichols, et al., 1970
Mantz, A.W.; Nichols, E.R.; Alpert, B.D.; Rao, K.N.,
CO laser spectra studied with a 10-meter vacuum infrared grating spectrograph,
J. Mol. Spectrosc., 1970, 35, 325. [all data]
Yardley, 1970
Yardley, J.T.,
Laser action in highly-excited vibrational levels of CO,
J. Mol. Spectrosc., 1970, 35, 314. [all data]
Kildal, Eng, et al., 1974
Kildal, H.; Eng, R.S.; Ross, A.H.M.,
Heterodyne measurements of 12C16O laser frequencies and improved Dunham coefficients,
J. Mol. Spectrosc., 1974, 53, 479. [all data]
Millikan, 1963
Millikan, R.C.,
Vibrational fluorescence of carbon monoxide,
J. Chem. Phys., 1963, 38, 2855. [all data]
McCaa and Williams, 1964
McCaa, D.J.; Williams, D.,
Infrared fluorescence of carbon monoxide,
J. Opt. Soc. Am., 1964, 54, 326. [all data]
Dowling, 1969
Dowling, J.M.,
Line widths in the pure rotational spectrum of carbon monoxide,
J. Quant. Spectrosc. Radiat. Transfer, 1969, 9, 1613. [all data]
Sanderson, Scott, et al., 1971
Sanderson, R.B.; Scott, H.E.; White, J.T.,
Strengths and widths of the pure rotational lines of CO,
J. Mol. Spectrosc., 1971, 38, 252. [all data]
Buontempo, Cunsolo, et al., 1973
Buontempo, U.; Cunsolo, S.; Jacucci, G.,
Electric quadrupole moment of CO and molecular torque in liquid Ar and N2 from ir spectra,
J. Chem. Phys., 1973, 59, 3750. [all data]
Billingsley and Krauss, 1974
Billingsley, F.P., II; Krauss, M.,
Quadrupole moment of CO, N2, and NO+,
J. Chem. Phys., 1974, 60, 2767. [all data]
Toth, Hunt, et al., 1969
Toth, R.A.; Hunt, R.H.; Plyler, E.K.,
Line intensities in the 3-0 of the CO and dipole moment matrix elements for the CO molecule,
J. Mol. Spectrosc., 1969, 32, 85. [all data]
Siegbahn, Nordling, et al., 1969
Siegbahn, K.; Nordling, C.; Johansson, G.; Hedman, J.; Heden, P.F.; Hamrin, k.; Gelius, U.; Bergmark, T.; Werme, L.O.; Manne, R.; Baer,
ESCA Applied to Free Molecules, North-Holland Publishing Company, Amsterdam, 1969, 0. [all data]
Thomas, 1970
Thomas, T.D.,
X-ray photoelectron spectroscopy of carbon monoxide,
J. Chem. Phys., 1970, 53, 1744. [all data]
Smith and Thomas, 1976
Smith, S.R.; Thomas, T.D.,
Core ionization potentials in carbon monoxide,
J. Electron Spectrosc. Relat. Phenom., 1976, 8, 45. [all data]
Wells, Borst, et al., 1973
Wells, W.C.; Borst, W.L.; Zipf, E.C.,
Excitation of higher-lying metastable states in carbon monoxide by electron impact: cross-section and lifetime measurements,
Phys. Rev. A: Gen. Phys., 1973, 8, 2463. [all data]
Johns, McKellar, et al., 1974
Johns, J.W.C.; McKellar, A.R.W.; Weitz, D.,
Wavelength measurements of 13C16O laser transitions,
J. Mol. Spectrosc., 1974, 51, 539. [all data]
Chen, Rao, et al., 1976
Chen, D.-W.; Rao, K.N.; McDowell, R.S.,
Fundamental and overtone bands of isotopic species of carbon monoxide,
J. Mol. Spectrosc., 1976, 61, 71. [all data]
Young and Eachus, 1966
Young, L.A.; Eachus, W.J.,
Dipole moment function and vibration-rotation matrix elements for CO,
J. Chem. Phys., 1966, 44, 4195. [all data]
Moskalenko and Mirumyants, 1971
Moskalenko, N.I.; Mirumyants, S.O.,
Measurement of the integral intensities of infrared absorption bands of H2O, CO2, N2O, CO, CH4, and NO vapor in the temperature range 220-400°K,
Sov. Phys. J. Engl. Transl., 1971, 6, 721, In original 7. [all data]
Roux, Effantin, et al., 1972
Roux, F.; Effantin, C.; D'Incan, J.,
Forces d'oscillateur absolues de rotation dans les transitions 2-0, 3-1, 4-2, 5-3, du spectre de vibration-rotation de la molecule CO, deduites de mesures d'intensites en emission,
J. Quant. Spectrosc. Radiat. Transfer, 1972, 12, 97-106. [all data]
Billingsley and Krauss, 1974, 2
Billingsley, F.P., II; Krauss, M.,
Multiconfiguration self-consistent-field calculation of the dipole moment function of CO(X1Σ+),
J. Chem. Phys., 1974, 60, 4130. [all data]
Bouanich and Brodbeck, 1974, 2
Bouanich, J.-P.; Brodbeck, C.,
Moments de transition vibrationnelle des molecules diatomiques. Intensite des raies rovibrationnelles des bandes 0 → 2 et 0 → 3 et fonction dipolaire de CO,
J. Quant. Spectrosc. Radiat. Transfer, 1974, 14, 1199. [all data]
Varanasi and Sarangi, 1975
Varanasi, P.; Sarangi, S.,
Measurements of intensities and nitrogen-broadened linewidths in the CO fundamental at low temperatures,
J. Quant. Spectrosc. Radiat. Transfer, 1975, 15, 473. [all data]
Tipping, 1976
Tipping, R.H.,
Vibration-rotation intensities for "hot" bands,
J. Mol. Spectrosc., 1976, 61, 272-281. [all data]
Weisbach and Chackerian, 1973
Weisbach, M.F.; Chackerian, C., Jr.,
Linewidths and transition probabilities for the carbon monoxide laser lines,
J. Chem. Phys., 1973, 59, 4272. [all data]
Hunt, Toth, et al., 1968
Hunt, R.H.; Toth, R.A.; Plyler, E.K.,
High-resolution determination of the widths of self-broadened lines of carbon monoxide,
J. Chem. Phys., 1968, 49, 3909. [all data]
Hoover and Williams, 1969
Hoover, G.M.; Williams, D.,
Infrared absorptance of carbon monoxide at low temperatures,
J. Opt. Soc. Am., 1969, 59, 28. [all data]
Bouanich, Larvor, et al., 1969
Bouanich, P.; Larvor, M.; Haeusler, C.,
Etude des raies de vibration-rotation de la bande v0→3 de l'oxyde de carbone CO comprime,
C.R. Acad. Sci. Paris, Ser. B, 1969, 269, 1238. [all data]
Varanasi, 1975
Varanasi, P.,
Measurement of line widths of CO of planetary interest at low temperatures,
J. Quant. Spectrosc. Radiat. Transfer, 1975, 15, 191. [all data]
Moskalenko, 1975
Moskalenko, N.I.,
Measurement of intensities and halfwidths of spectral absorption lines of the fundamental 0-1 band of CO,
Opt. Spectrosc. Engl. Transl., 1975, 38, 382, In original 676. [all data]
Notes
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