Fe(CO)5..HO anion
- Formula: C5HFeO6-
- Molecular weight: 212.903
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -269.38 | kcal/mol | Ther | Sunderlin and Squires, 1993 | HO- transfer equilibrium to SO2. Structure thought ot be (CO)4Fe-CO2H |
| ΔfH°gas | <-257.00 | kcal/mol | IMRB | Lane, Lee, et al., 1984 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sunderlin and Squires, 1993
Sunderlin, L.S.; Squires, R.R.,
Energetics and Mechanism of the Thermal Decarboxylation of (CO)4FeCOOH- in the Gas Phase,
J. Am. Chem. Soc., 1993, 115, 1, 337, https://doi.org/10.1021/ja00054a048
. [all data]
Lane, Lee, et al., 1984
Lane, K.R.; Lee, R.E.; Sallans, L.; Squires, R.R.,
Formation and reactivity of Fe(CO)4COOH- in the gas phase. Implication for the Fe(CO)5 catalyzed water gas shift reaction,
J. Am. Chem. Soc., 1984, 106, 5767. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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