Trimethylamine, compd. with borane (1:1)

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Condensed phase thermochemistry data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
solid,1 bar40.531cal/mol*KN/AFinke, Todd, et al., 1970crystaline, III phase

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
41.530298.15Finke, Todd, et al., 1970crystaline, III phase; T = 12 to 390 K.

Reaction thermochemistry data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H11BN- + Hydrogen cation = Trimethylamine, compd. with borane (1:1)

By formula: C3H11BN- + H+ = C3H12BN

Quantity Value Units Method Reference Comment
Δr393.1 ± 2.1kcal/molG+TSRen, Workman, et al., 1998gas phase; Acid heat est. from B-N bond strength of "35-40 kcal/mol" in Ren, Workman, et al., 1998
Quantity Value Units Method Reference Comment
Δr384.0 ± 2.0kcal/molIMRBRen, Workman, et al., 1998gas phase; Acid heat est. from B-N bond strength of "35-40 kcal/mol" in Ren, Workman, et al., 1998

References

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Finke, Todd, et al., 1970
Finke, H.L.; Todd, S.S.; Messerly, J.F., Trimethylamineborane and triethylamineborane: low-temperature thermodynamic properties, J. Chem. Thermodynam., 1970, 2, 129-138. [all data]

Ren, Workman, et al., 1998
Ren, J.H.; Workman, D.B.; Squires, R.R., Gas-phase negative ion chemistry of Lewis acid-base complexes, J. Am. Chem. Soc., 1998, 120, 40, 10511-10522, https://doi.org/10.1021/ja9804518 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References