Cyclohexane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-29.78kcal/molN/ASpitzer and Huffman, 1947Value computed using ΔfHliquid° value of -157.7±1.8 kj/mol from Spitzer and Huffman, 1947 and ΔvapH° value of 33.1 kj/mol from Prosen, Johnson, et al., 1946.; DRB
Δfgas-29.43 ± 0.19kcal/molCcbProsen, Johnson, et al., 1946ALS
Δfgas-29.47kcal/molN/AMoore, Renquist, et al., 1940Value computed using ΔfHliquid° value of -156.4±1.3 kj/mol from Moore, Renquist, et al., 1940 and ΔvapH° value of 33.1 kj/mol from Prosen, Johnson, et al., 1946.; DRB
Quantity Value Units Method Reference Comment
gas71.269cal/mol*KN/ABeckett C.W., 1947Close value of S(298.15 K)=298.78(0.75) J/mol*K was obtained by [43ASTSZA] from calorimetric data.; GT

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
8.14350.Dorofeeva O.V., 1986There is an appreciable difference (up to 3.0-4.5 J/mol*K) between selected values of S(T) and Cp(T) and earlier statistically calculated values [ Brickwedde F.G., 1946, Beckett C.W., 1947, Kilpatrick J.E., 1947, Lippincott E.R., 1966] at high temperatures. It is due to using the most reliable molecular constants in [ Dorofeeva O.V., 1986].; GT
10.18100.
13.10150.
16.50200.
22.75273.15
25.18 ± 0.48298.15
25.361300.
35.526400.
45.096500.
53.389600.
60.378700.
66.217800.
71.085900.
75.1481000.
78.5521100.
81.4171200.
83.8411300.
85.9081400.
87.6791500.

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
33.000370.Spitzer R., 1946Please also see Montgomery J.B., 1942.; GT
34.21 ± 0.30384.
35.000390.
36.800410.
38.67 ± 0.40428.
41.70 ± 0.40460.
45.30 ± 0.50495.
47.00 ± 0.50521.
49.30 ± 0.50544.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-37.68 ± 0.42kcal/molCcbSpitzer and Huffman, 1947ALS
Δfliquid-37.34 ± 0.19kcal/molCcbProsen, Johnson, et al., 1946ALS
Δfliquid-37.39 ± 0.32kcal/molCcbMoore, Renquist, et al., 1940Reanalyzed by Cox and Pilcher, 1970, Original value = -37.69 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Δcliquid-938. ± 5.kcal/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
liquid48.731cal/mol*KN/AAston, Szasa, et al., 1943DH
liquid48.841cal/mol*KN/ARuehrwein and Huffman, 1943DH
liquid49.21cal/mol*KN/AParks, Huffman, et al., 1930Extrapolation below 90 K, 50.54 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
37.285298.15Trejo, Costas, et al., 1991DH
37.500298.15Lainez, Rodrigo, et al., 1989DH
34.39326.5Voss and Sloan, 1989T = 326.5 to 450.0 K. Unsmoothed experimental datum.; DH
37.275298.15Saito and Tanaka, 1988DH
36.883298.15Shiohama, Ogawa, et al., 1988DH
37.077293.15Kalali, Kohler, et al., 1987T = 293.15, 313.15 K.; DH
37.538298.15Jimenez, Romani, et al., 1986DH
37.249298.15Ortega, 1986DH
37.40298.15Nkinamubanzi, Charlet, et al., 1985DH
37.275298.15Tanaka, Nakamichi, et al., 1985DH
37.000293.15Siddiqi, Svejda, et al., 1983DH
37.38298.15Grolier, Inglese, et al., 1982DH
37.28298.15Tanaka, 1982T = 293.15, 298.15, 303.15 K. Data at three temperatures.; DH
37.3205298.15Fortier, D'Arcy, et al., 1979DH
37.314298.15Vesely, Zabransky, et al., 1979DH
37.38298.15Wilhelm, Grolier, et al., 1979DH
37.369298.15Grolier, Wilhelm, et al., 1978DH
37.45298.Safir, 1978T = 298 to 313 K. Data calculated from equation Cp = 1.7493 + 0.00452 T kJ/kg*K.; DH
37.314298.15Vesely, Svoboda, et al., 1977T = 298 to 318 K.; DH
37.302298.15Fortier, Benson, et al., 1976DH
37.3016298.15Fortier and Benson, 1976DH
37.333298.15Jolicoeur, Boileau, et al., 1975DH
36.998293.15Wilhelm, Zettler, et al., 1974T = 273 to 323 K.; DH
38.15298.15Subrahmanyam and Rajagopal, 1973T = 298 to 323 K.; DH
37.09298.15Wilhelm, Schano, et al., 1969Temperature 20, 30, and 40°C.; DH
37.17298.Recko, 1968T = 24 to 40°C, equation only.; DH
36.551298.Nikolaev, Rabinovich, et al., 1966T = 10 to 50°C.; DH
37.120298.00Moelwyn-Hughes and Thorpe, 1964T = 297 to 327 K.; DH
37.09311.Swietoslawski and Zielenkiewicz, 1960Mean value 20 to 56°C.; DH
36.85300.Auerbach, Sage, et al., 1950T = 300 to 366 K. Cp given as 0.4378 Btu/lb*R at 80°F.; DH
37.249295.Aston, Szasa, et al., 1943T = 12 to 293 K.; DH
37.359298.15Ruehrwein and Huffman, 1943T = 13 to 302 K.; DH
24.00304.2Phillip, 1939DH
34.39298.9Parks, Huffman, et al., 1930T = 92 to 299 K. Value is unsmoothed experimental datum.; DH
42.09298.Dejardin, 1919T = 22 to 50°C.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Cyclohexene + Hydrogen = Cyclohexane

By formula: C6H10 + H2 = C6H12

Quantity Value Units Method Reference Comment
Δr-28. ± 1.kcal/molAVGN/AAverage of 8 values; Individual data points

NH4+ + Cyclohexane = (NH4+ • Cyclohexane)

By formula: H4N+ + C6H12 = (H4N+ • C6H12)

Quantity Value Units Method Reference Comment
Δr9.kcal/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, DG<, ΔrH<; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KN/ADeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, DG<, ΔrH<; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
2.8317.PHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, DG<, ΔrH<; M

C6H6+ + Cyclohexane = (C6H6+ • Cyclohexane)

By formula: C6H6+ + C6H12 = (C6H6+ • C6H12)

Quantity Value Units Method Reference Comment
Δr11.2kcal/molPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr27.cal/mol*KN/AMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.2295.PHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; Entropy change calculated or estimated; M

C6H11- + Hydrogen cation = Cyclohexane

By formula: C6H11- + H+ = C6H12

Quantity Value Units Method Reference Comment
Δr418.3 ± 2.0kcal/molBranPeerboom, Rademaker, et al., 1992gas phase; B
Δr406.82 ± 0.90kcal/molG+TSBohme, Lee-Ruff, et al., 1972gas phase; B
Quantity Value Units Method Reference Comment
Δr409.5 ± 2.2kcal/molH-TSPeerboom, Rademaker, et al., 1992gas phase; B
Δr>398.00kcal/molIMRBBohme, Lee-Ruff, et al., 1972gas phase; B

2Hydrogen + 1,3-Cyclohexadiene = Cyclohexane

By formula: 2H2 + C6H8 = C6H12

Quantity Value Units Method Reference Comment
Δr-53.64 ± 0.29kcal/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid; ALS
Δr-54.88 ± 0.10kcal/molChydKistiakowsky, Ruhoff, et al., 1936gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -55.4 ± 0.1 kcal/mol; At 355 °K; ALS

2Hydrogen + 1,4-Cyclohexadiene = Cyclohexane

By formula: 2H2 + C6H8 = C6H12

Quantity Value Units Method Reference Comment
Δr-55.6kcal/molChydRoth, Adamczak, et al., 1991liquid phase; ALS
Δr-53.90 ± 0.33kcal/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid; ALS

C3H9Si+ + Cyclohexane = (C3H9Si+ • Cyclohexane)

By formula: C3H9Si+ + C6H12 = (C3H9Si+ • C6H12)

Quantity Value Units Method Reference Comment
Δr37.9kcal/molPHPMSLi and Stone, 1989gas phase; condensation; M
Quantity Value Units Method Reference Comment
Δr48.1cal/mol*KPHPMSLi and Stone, 1989gas phase; condensation; M

3Hydrogen + Benzene = Cyclohexane

By formula: 3H2 + C6H6 = C6H12

Quantity Value Units Method Reference Comment
Δr-49.06 ± 0.15kcal/molChydKistiakowsky, Ruhoff, et al., 1936gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -49.80 ± 0.15 kcal/mol; At 355 °K; ALS

Hydrogen iodide + Cyclohexane, iodo- = Cyclohexane + Iodine

By formula: HI + C6H11I = C6H12 + I2

Quantity Value Units Method Reference Comment
Δr-7.8 ± 2.0kcal/molCmBrennan and Ubbelohde, 1956gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -6.8 ± 1.0 kcal/mol; ALS

Lithium ion (1+) + Cyclohexane = (Lithium ion (1+) • Cyclohexane)

By formula: Li+ + C6H12 = (Li+ • C6H12)

Quantity Value Units Method Reference Comment
Δr24.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Cyclopentane, methyl- = Cyclohexane

By formula: C6H12 = C6H12

Quantity Value Units Method Reference Comment
Δr-3.510kcal/molEqkGlasebrook and Lovell, 1939liquid phase; Heat of isomerization; ALS

2Hydrogen + Bicyclo[2.2.0]hex-1(4)-ene = Cyclohexane

By formula: 2H2 + C6H8 = C6H12

Quantity Value Units Method Reference Comment
Δr-102.0 ± 1.9kcal/molChydRoth, Adamczak, et al., 1991liquid phase; ALS

Cyclohexanol = Cyclohexane + Hydrogen

By formula: C6H12O = C6H12 + H2

Quantity Value Units Method Reference Comment
Δr15.2 ± 0.55kcal/molEqkFedoseenko, Yursha, et al., 1983gas phase; At 502 K; ALS

Cyclohexane, chloro- + Hydrogen chloride = Cyclohexane + Chlorine

By formula: C6H11Cl + HCl = C6H12 + Cl2

Quantity Value Units Method Reference Comment
Δr-34.20kcal/molCmKirkbride, 1956liquid phase; ALS

Cyclohexane = Cyclopentane, methyl-

By formula: C6H12 = C6H12

Quantity Value Units Method Reference Comment
Δr4.32 ± 0.28kcal/molEqkKabo and Andreevskii, 1973liquid phase; ALS

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference Comment
0.0051 QN/A missing citation give several references for the Henry's law constants but don't assign them to specific species.
0.00553200.XN/A 
0.0062710.XN/A 
0.0056 LN/A 
0.0051 VN/A 

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   D3d     Symmetry Number σ = 6


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1g 1 CH2 a-str 2930  E  ia 2938 VS p liq. FR(2ν3)
a1g 1 CH2 a-str 2930  E  ia 2923 VS p liq. FR(2ν3)
a1g 2 CH2 s-str 2852  C  ia 2852 VS p liq.
a1g 3 CH2 scis 1465  C  ia 1465 M p liq.
a1g 4 CH2 rock 1157  C  ia 1157 S p liq.
a1g 5 CC str 802  C  ia 802 VS p liq.
a1g 6 CCC deform + CC torsion 383  C  ia 383 M p liq.
a1u 7 CH2 twist 1383  C 1383 gas  ia Observed in the crystalline state at about ν90 K
a1u 8 CH2 wag 1157  C 1157 gas  ia Observed in the crystalline state at about ν90 K
a1u 9 CC str + CC torsion 1057  C 1057 gas  ia Observed in the crystalline state at about ν90 K
a2g 10 CH2 wag 1437  C 1437 gas  ia Observed in the crystalline state at about ν90 K
a2g 11 CH2 twist 1090  C 1090 gas  ia Observed in the crystalline state at about ν90 K
a2u 12 CH2 a-str 2915  E 2915 M gas  ia
a2u 13 CH2 s-str 2860  E  ia SF21826)
a2u 14 CH2 scis 1437  C 1437 M gas  ia
a2u 15 CH2 rock 1030  D 1040 M gas  ia FR2332)
a2u 15 CH2 rock 1030  D 1016 M gas  ia FR2332)
a2u 16 CCC deform 523  A 523 W gas  ia
eg 17 CH2 a-str 2930  E  ia SF11225)
eg 18 CH2 s-str 2897  E  ia 2897 M vb
eg 19 CH2 scis 1443  C  ia 1443 S dp
eg 20 CH2 wag 1347  C  ia 1347 S dp
eg 21 CH2 twist 1266  C  ia 1266 VS dp
eg 22 CC str 1027  C  ia 1027 VS dp
eg 23 CH2 rock 785  C 785 gas 785 VW dp liq. Observed in the crystalline state at about ν90 K
eg 24 CCC deform + CC torsion 426  C  ia 426 S dp liq.
eu 25 CH2 a-str 2933  A 2933 VS gas  ia
eu 26 CH2 s-str 2863  A 2863 VS gas  ia
eu 27 CH2 scis 1457  A 1457 VS gas  ia
eu 28 CH2 wag 1355  B 1355 W gas  ia
eu 29 CH2 twist 1261  A 1261 S gas  ia
eu 30 CH2 rock 907  B 907 S gas  ia
eu 31 CC str 863  A 863 S gas  ia
eu 32 CCC deform + CC torsion 248  C 248 VW liq.  ia

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
MMedium
WWeak
VWVery weak
iaInactive
vbVery broad
pPolarized
dpDepolarized
FRFermi resonance with an overtone or a combination tone indicated in the parentheses.
SFCalculation shows that the frequency approximately equals that of the vibration indicated in the parentheses.
A0~1 cm-1 uncertainty
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty
D6~15 cm-1 uncertainty
E15~30 cm-1 uncertainty

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Spitzer and Huffman, 1947
Spitzer, R.; Huffman, H.M., The heats of combustion of cyclopentane, cyclohexane, cycloheptane and cyclooctane, J. Am. Chem. Soc., 1947, 69, 211-213. [all data]

Prosen, Johnson, et al., 1946
Prosen, E.J.; Johnson, W.H.; Rossini, F.D., Heats of formation and combustion of the normal alkylcyclopentanes and cyclohexanes and the increment per CH2 group for several homologous series of hydrocarbons, J. Res. NBS, 1946, 37, 51-56. [all data]

Moore, Renquist, et al., 1940
Moore, G.E.; Renquist, M.L.; Parks, G.S., Thermal data on organic compounds. XX. Modern combustion data for two methylnonanes, methyl ethyl ketone, thiophene and six cycloparaffins, J. Am. Chem. Soc., 1940, 62, 1505-1507. [all data]

Beckett C.W., 1947
Beckett C.W., The thermodynamic properties and molecular structure of cyclohexane, methylcyclohexane, ethylcyclohexane, and seven dimethylcyclohexanes, J. Am. Chem. Soc., 1947, 69, 2488-2495. [all data]

Dorofeeva O.V., 1986
Dorofeeva O.V., Thermodynamic properties of twenty-one monocyclic hydrocarbons, J. Phys. Chem. Ref. Data, 1986, 15, 437-464. [all data]

Brickwedde F.G., 1946
Brickwedde F.G., Equilibrium constants of some reactions involved in the production of 1,3-butadiene, J. Res. Nat. Bur. Stand., 1946, 37, 263-279. [all data]

Kilpatrick J.E., 1947
Kilpatrick J.E., Heats, equilibrium constants, and free energies of formation of the alkylcyclopentanes and alkylcyclohexanes, J. Res. Nat. Bur. Stand., 1947, 39, 523-543. [all data]

Lippincott E.R., 1966
Lippincott E.R., Enthalpy, free energy, entropy, and heat capacity of cyclohexane and acetaldehyde, Bull. Soc. Chim. Belges., 1966, 75, 655-667. [all data]

Spitzer R., 1946
Spitzer R., The heat capacity of gaseous cyclopentane, cyclohexane and methylcyclohexane, J. Am. Chem. Soc., 1946, 68, 2537-2538. [all data]

Montgomery J.B., 1942
Montgomery J.B., The heat capacity of organic vapors. IV. Benzene, fluorobenzene, toluene, cyclohexane, methylcyclohexane and cyclohexene, J. Am. Chem. Soc., 1942, 64, 2375-2377. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Aston, Szasa, et al., 1943
Aston, J.G.; Szasa, G.J.; Fink, H.L., The heat capacity and entropy, heats of transition, fusion and vaporization and the vapor pressures of cyclohexane. The vibrational frequencies of alicyclic ring systems, J. Am. Chem. Soc., 1943, 65, 1135-1139. [all data]

Ruehrwein and Huffman, 1943
Ruehrwein, R.A.; Huffman, H.M., Thermal data. XVII. The heat capacity, entropy and free energy of formation of cyclohexane. A new method of heat transfer in low temperature calorimetry, J. Am. Chem. Soc., 1943, 65, 1620-1625. [all data]

Parks, Huffman, et al., 1930
Parks, G.S.; Huffman, H.M.; Thomas, S.B., Thermal data on organic compounds. VI. The heat capacities, entropies and free energies of some saturated, non-benzenoid hydrocarbons, J. Am. Chem. Soc., 1930, 52, 1032-1041. [all data]

Trejo, Costas, et al., 1991
Trejo, L.M.; Costas, M.; Patterson, D., Excess heat capacity of organic mixtures, Internat. DATA Series, Selected Data Mixt., 1991, Ser. [all data]

Lainez, Rodrigo, et al., 1989
Lainez, A.; Rodrigo, M.M.; Wilhelm, E.; Grolier, J.-P.E., Excess volumes and excess heaat capacitiies of some mixtures with trans,trans,cis-1,5,9-cyclododecatriene at 298.15K, J. Chem. Eng. Data, 1989, 34, 332-335. [all data]

Voss and Sloan, 1989
Voss, S.F.; Sloan, E.D., Thermal conductivity and heat capacity of synthetic fuel components, Int. J. Thermophys., 1989, 10(5), 1029-1040. [all data]

Saito and Tanaka, 1988
Saito, A.; Tanaka, R., Excess volumes and heat capacities of binary mixtures formed from cyclohexane, hexane and heptane at 298.15 K, J. Chem. Thermodynam., 1988, 20, 859-865. [all data]

Shiohama, Ogawa, et al., 1988
Shiohama, Y.; Ogawa, H.; Murakami, S.; Fujihara, I., Excess thermodynamic properties of (cis-decalin or trans-decalin + cyclohexane or methylcyclohexane or cyclooctane) at 298.15 K, J. Chem. Thermodynam., 1988, 20, 1307-1314. [all data]

Kalali, Kohler, et al., 1987
Kalali, H.; Kohler, F.; Svejda, P., Excess properties of the mixture bis(2-dichlorethyl)ether (chlorex) + 2,2,4-trimethylpentane (isooctane), Monatsh. Chem., 1987, 118, 1-18. [all data]

Jimenez, Romani, et al., 1986
Jimenez, E.; Romani, L.; Paz Andrade, M.I.; Roux-Desgranges, G.; Grolier, J.-P.E., Molar excess heat capacities and volumes for mixtures of alkanoates with cyclohexane at 25°C, J. Solution Chem., 1986, 15(11), 879-890. [all data]

Ortega, 1986
Ortega, J., Excess molar heat capacities of the binary mixtures of cyclohexane with isomers of hexanol at 298.15 K, Rev. Latinoam. Ing. Quim. Quim. Apl., 1986, 16, 307-315. [all data]

Nkinamubanzi, Charlet, et al., 1985
Nkinamubanzi, P.; Charlet, G.; Delmas, G., Excess enthalpies, excess heat capacities and excess volumes of tetraalkoxysilanes with cyclohexane and carbon tetrachloride, Fluid Phase Equilibria, 1985, 20, 57-73. [all data]

Tanaka, Nakamichi, et al., 1985
Tanaka, R.; Nakamichi, T.; Murakami, S., Molar excess heat capacities and volumes for mixtures of benzomitrile with cyclohexane between 10 and 45°C, J. Solution Chem., 1985, 14(11), 795-803. [all data]

Siddiqi, Svejda, et al., 1983
Siddiqi, M.A.; Svejda, P.; Kohler, F., A generalized van der Waals equation of state II. Excess heat capacities of mixtures containing cycloalkanes (C5,C6), methylcycloalkanes (C5,C6) and n-decane, Ber. Bunsenges. Phys. Chem., 1983, 87, 1176-1181. [all data]

Grolier, Inglese, et al., 1982
Grolier, J.-P.E.; Inglese, A.; Wilhelm, E., Excess volumes and excess heat capacities of tetrachloroethene + cyclohexane, + methylcyclohexane, + benzene, and + toluene at 298.15 K, J. Chem. Thermodynam., 1982, 14, 523-529. [all data]

Tanaka, 1982
Tanaka, R., Determination of excess heat capacities of (benzene + tetrachloromethane and + cyclohexane) between 293.15 and 303.15 K by use of a Picker flow calorimeter, J. Chem. Thermodynam., 1982, 14, 259-268. [all data]

Fortier, D'Arcy, et al., 1979
Fortier, J.-L.; D'Arcy, P.J.; Benson, G.C., Heat capacities of binary cycloalkane mixtures at 298.15 K, Thermochim. Acta, 1979, 28, 37-43. [all data]

Vesely, Zabransky, et al., 1979
Vesely, F.; Zabransky, M.; Svoboda, V.; Pick, J., The use of mixing calorimeter for measuring heat capacities of liquids, Coll. Czech. Chem. Commun., 1979, 44, 3529-3532. [all data]

Wilhelm, Grolier, et al., 1979
Wilhelm, E.; Grolier, G.-P.E.; Karbalai Ghassemi, M.H., Molar heat capacity of binary liquid mixtures: 1,2-dichloroethane + cyclohexane and 1,2-dichloroethane + methylcyclohexane, Thermochim. Acta, 1979, 28, 59-69. [all data]

Grolier, Wilhelm, et al., 1978
Grolier, J.-P.E.; Wilhelm, E.; Hamedi, M.H., Molar heat capacities and isothermal compressibility of binary liquid mixtures: carbon tetrachloride + benzene, carbon tetrachloride + cyclohexane and benzene + cyclohexane, Ber. Bunsenges. Phys. Chem., 1978, 82, 1282-1290. [all data]

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Notes

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