Tetrafluoromethane

• Formula: CF₄
• Molecular weight: 88.0043
• IUPAC Standard InChI: InChI=1S/CF4/c2-1(3,4)5 Copy

  
• IUPAC Standard InChIKey: TXEYQDLBPFQVAA-UHFFFAOYSA-N Copy
• CAS Registry Number: 75-73-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Carbon tetrafluoride; Methane, tetrafluoro-; Arcton 0; Carbon fluoride (CF4); Freon 14; FC 14; Perfluoromethane; CF4; Halon 14; Carbon fluoride; F 14; Halocarbon 14; R 14; UN 1982; Refrigerant 14; CFC 14; R 14 (Refrigerant); Refrigerant R 14; Methane, tetrafluo-
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• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • Henry's Law data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Phase change data
  • Gas phase ion energetics data
  • Ion clustering data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
  • Fluid Properties
• Data at other public NIST sites:
  • Electron-Impact Ionization Cross Sections (on physics web site)
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
MS - José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

( • 4) +  = ( • 5)

By formula: (F^- • 4CF₄) + CF₄ = (F^- • 5CF₄)

(CF₃^- • 3) +  = (CF₃^- • 4)

By formula: (CF₃^- • 3CF₄) + CF₄ = (CF₃^- • 4CF₄)

 + 2 =  + 4

By formula: CF₄ + 2H₂O = CO₂ + 4HF

( • 2) +  = ( • 3)

By formula: (CF₃⁺ • 2CF₄) + CF₄ = (CF₃⁺ • 3CF₄)

( • 3) +  = ( • 4)

By formula: (CF₃⁺ • 3CF₄) + CF₄ = (CF₃⁺ • 4CF₄)

( • ) +  = ( • 2)

By formula: (CF₃⁺ • CF₄) + CF₄ = (CF₃⁺ • 2CF₄)

(CHF₄⁺ • 2) +  = (CHF₄⁺ • 3)

By formula: (CHF₄⁺ • 2CF₄) + CF₄ = (CHF₄⁺ • 3CF₄)

(CHF₄⁺ • ) +  = (CHF₄⁺ • 2)

By formula: (CHF₄⁺ • CF₄) + CF₄ = (CHF₄⁺ • 2CF₄)

( • 2) +  = ( • 3)

By formula: (F^- • 2CF₄) + CF₄ = (F^- • 3CF₄)

( • 3) +  = ( • 4)

By formula: (F^- • 3CF₄) + CF₄ = (F^- • 4CF₄)

(CF₃^- • 2) +  = (CF₃^- • 3)

By formula: (CF₃^- • 2CF₄) + CF₄ = (CF₃^- • 3CF₄)

( • ) +  = ( • 2)

By formula: (F^- • CF₄) + CF₄ = (F^- • 2CF₄)

(CF₃^- • ) +  = (CF₃^- • 2)

By formula: (CF₃^- • CF₄) + CF₄ = (CF₃^- • 2CF₄)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CF₄ = (C₄H₉⁺ • CF₄)

 +  = ( • )

By formula: CF₃⁺ + CF₄ = (CF₃⁺ • CF₄)

CHF₄⁺ +  = (CHF₄⁺ • )

By formula: CHF₄⁺ + CF₄ = (CHF₄⁺ • CF₄)

 +  = ( • )

By formula: F^- + CF₄ = (F^- • CF₄)

CF₃^- +  = (CF₃^- • )

By formula: CF₃^- + CF₄ = (CF₃^- • CF₄)

2 =  + 

By formula: 2CF₂O = CO₂ + CF₄

2 = 4 + 5 + 3

By formula: 2C₂F₁₁N₅ = 4CF₄ + 5N₂ + 3F₂

CF₅N =  + 0.5 + 0.5

By formula: CF₅N = CF₄ + 0.5N₂ + 0.5F₂

 + 0.5 + 0.5 = CF₅N

By formula: CF₄ + 0.5N₂ + 0.5F₂ = CF₅N

2 = 2 + 3 + 3

By formula: 2CF₇N₃ = 2CF₄ + 3N₂ + 3F₂

2 = 2 + 3 + 

By formula: 2CF₅N₃ = 2CF₄ + 3N₂ + F₂

=  + 2 + 2

By formula: CF₈N₄ = CF₄ + 2N₂ + 2F₂

=  +  + 

By formula: CF₆N₂ = CF₄ + N₂ + F₂

C₅O₅W (g) +  (g) = C₆F₄O₅W (g)

By formula: C₅O₅W (g) + CF₄ (g) = C₆F₄O₅W (g)

3 + 5 = 6 + 4

By formula: 3C₂F₃N + 5F₃N = 6CF₄ + 4N₂

4 +  =  + 4

By formula: 4Na + CF₄ = C + 4FNa

 + 4 =  + 4

By formula: CF₄ + 4HF = CH₄ + 4F₂

3 + 2 = 6 + 

By formula: 3C₂F₆ + 2F₃N = 6CF₄ + N₂

(CHF₄⁺ • 3) +  = (CHF₄⁺ • 4)

By formula: (CHF₄⁺ • 3CF₄) + CF₄ = (CHF₄⁺ • 4CF₄)

 + 2 = 2

By formula: C₂F₄ + 2F₂ = 2CF₄

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

k_H(T) = k°_H exp(d(ln(k_H))/d(1/T) ((1/T) - 1/(298.15 K)))
k°_H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(k_H))/d(1/T) = Temperature dependence constant (K)

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   T_d     Symmetry Number σ = 12

Source: Shimanouchi, 1972

Notes

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Price and Sapiano, 1979
Price, S.J.W.; Sapiano, H.J., Determination of ΔH°_f298(C₆F₁₀,g) and ΔH°_f298(C₆F₁₂,g) from studies of the combustion of decafluorocyclohexene and dodecafluorocylohexene in oxygen and calculation of the resonance energy of hexafluorobenzene, Can. J. Chem., 1979, 58, 685-688. [all data]

Krech, Price, et al., 1973
Krech, M.J.; Price, S.J.W.; Yared, W.F., Determination of the heat of formation of octafluorotoluene and calculation of D[C₆F₅-F] - D[C₆F₅-CF₃], Can. J. Chem., 1973, 51, 3662-3664. [all data]

Smith and Pace, 1969
Smith, J.H.; Pace, E.L., The thermodynamic properties of carbon tetrafluoride from 12°K to its boiling point. The significance of the parameter {nu}, J. Phys. Chem., 1969, 73, 4232-4236. [all data]

Hiraoka, Nasu, et al., 1995
Hiraoka, K.; Nasu, M.; Fujimaki, S.; Ignacio, E.W.; Yamabe, S., Weak Ion-Molecule Complexes of F-(CF4)n and CF3-(CF4)n, Chem Phys. Let., 1995, 245, 1, 14, https://doi.org/10.1016/0009-2614(95)00980-I . [all data]

Good, Scott, et al., 1956
Good, W.D.; Scott, D.W.; Waddington, G., Combustion calorimetry of organic fluorine compounds by a rotating-bomb method, J. Phys. Chem., 1956, 60, 1080-1089. [all data]

Scott, Good, et al., 1955
Scott, D.W.; Good, W.D.; Waddington, G., Heat of formation of tetrafluoromethane from combustion calorimetry of polytetrafluoroethylene, J. Am. Chem. Soc., 1955, 77, 245-246. [all data]

Hiraoka, Nasu, et al., 1996
Hiraoka, K.; Nasu, M.; Fujimaki, S.; Ignacio, E.W.; Yamabe, S., Gas-Phase Stability and Structure of the Cluster Ions CF3+(CO)n, CF3+(N2)n, CF3+((CF4)n, and CF4H+(CF4)n, J. Phys. Chem., 1996, 100, 13, 5245, https://doi.org/10.1021/jp9530010 . [all data]

Sharma, Meza de Hojer, et al., 1985
Sharma, D.M.S.; Meza de Hojer, S.; Kebarle, P., Stabilities of halonium ions from a study of gas-phase equilibria R+ + XR' = (RXR')+, J. Am. Chem. Soc., 1985, 107, 13, 3757, https://doi.org/10.1021/ja00299a002 . [all data]

Amphlett, Dacey, et al., 1971
Amphlett, J.C.; Dacey, J.R.; Pritchard, G.O., An investigation of the reaction 2COF₂ = CO₂ + CF₄ and the heat of formation of carbonyl fluoride, J. Phys. Chem., 1971, 75, 3024-3026. [all data]

Sinke, Thompson, et al., 1967
Sinke, G.C.; Thompson, C.J.; Jostad, R.E.; Walker, L.C.; Swanson, A.C.; Stull, D.R., Enthalpies of formation and bond energies of some fluoramines, J. Chem. Phys., 1967, 47, 1852-1854. [all data]

Walker, 1972
Walker, L.C., The enthalpy of decomposition of CF₃NF₂(g) to CF₄(g), N₂(g), and F₂(g), J. Chem. Thermodyn., 1972, 4, 219-223. [all data]

Brown, Ishikawa, et al., 1990
Brown, C.E.; Ishikawa, Y.; Hackett, P.A.; Rayner, D.M., J. Am. Chem. Soc., 1990, 112, 2530. [all data]

Walker, Sinke, et al., 1970
Walker, L.C.; Sinke, G.C.; Perettie, D.J.; Janz, G.J., Enthalpy of formation of trifluoroacetonitrile, J. Am. Chem. Soc., 1970, 92, 4525-4526. [all data]

Vorob'ev and Skuratov, 1960
Vorob'ev, A.F.; Skuratov, S.M., Standard enthalpies of formation of CF₄, Zh. Neorg. Khim., 1960, 5, 1398-1401. [all data]

Jessup, McCoskey, et al., 1955
Jessup, R.S.; McCoskey, R.E.; Nelson, R.A., The heat of formation of tetrafluoromethane, J. Am. Chem. Soc., 1955, 77, 244-245. [all data]

Sinke, 1966
Sinke, G.C., The heat of reaction of nitrogen trifluoride and hexafluoroethane, J. Phys. Chem., 1966, 70, 1326-1327. [all data]

Domalski and Armstrong, 1967
Domalski, E.S.; Armstrong, G.T., The heats of combustion of polytetrafluoroethylene (teflon) and graphite in elemental fluorine, J. Res. NBS, 1967, 71, 105-118. [all data]

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume I, National Bureau of Standards, 1972, 1-160. [all data]

Notes

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• Symbols used in this document:
  

  Cp,liquid	Constant pressure heat capacity of liquid
  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  S°liquid	Entropy of liquid at standard conditions
  d(ln(kH))/d(1/T)	Temperature dependence parameter for Henry's Law constant
  k°H	Henry's Law constant at 298.15K
  ΔcH°liquid	Enthalpy of combustion of liquid at standard conditions
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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