Strontium monofluoride

• Formula: FSr
• Molecular weight: 106.62
• IUPAC Standard InChI: InChI=1S/FH.Sr/h1H;/q;+1/p-1 Copy

  
• IUPAC Standard InChIKey: GXLMLAGMLTWIOF-UHFFFAOYSA-M Copy
• CAS Registry Number: 13569-27-2
• Chemical structure:
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• Information on this page:
  • Gas phase thermochemistry data
  • Constants of diatomic molecules
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
• Data at other public NIST sites:
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through October, 1977

Notes

References

Go To: Top, Gas phase thermochemistry data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Fowler, 1941
Fowler, C.A., Jr., New absorption spectra of the alkaline earth fluorides, Phys. Rev., 1941, 59, 645. [all data]

Barrow and Beale, 1967
Barrow, R.F.; Beale, J.R., The internuclear distance in gaseous SrF, Chem. Commun., 1967, 606. [all data]

Novikov and Gurvich, 1967
Novikov, M.M.; Gurvich, L.V., Electronic emission spectrum of SrF, Opt. Spectrosc. Engl. Transl., 1967, 22, 395, In original 720. [all data]

Johnson, 1929
Johnson, R.C., The band spectra of the alkaline earth halides. I. CaF, SrF, Proc. R. Soc. London A, 1929, 122, 161. [all data]

Ahrens, 1948
Ahrens, L.H., Molecular spectroscopic evidence of the existence of strontium isotopes Sr⁸⁸, Sr⁸⁷, and Sr⁸⁶, Phys. Rev., 1948, 74, 74. [all data]

Steimle, Domaille, et al., 1977
Steimle, T.C.; Domaille, P.J.; Harris, D.O., Rotational analysis of the B²Σ⁺-X²Σ⁺ system of SrF using a cw tunable dye laser, J. Mol. Spectrosc., 1977, 68, 134. [all data]

Domaille, Steimle, et al., 1977
Domaille, P.J.; Steimle, T.C.; Harris, D.O., The rotational spectrum of the X²Σ⁺ state of the SrF radical using laser microwave optical double resonance, J. Mol. Spectrosc., 1977, 68, 146. [all data]

Knight, Easley, et al., 1971
Knight, L.B., Jr.; Easley, W.C.; Weltner, W., Jr., Hyperfine interaction and chemical bonding in MgF, CaF, SrF, and BaF molecules, J. Chem. Phys., 1971, 54, 322. [all data]

Dagdigian, Cruse, et al., 1974
Dagdigian, P.J.; Cruse, H.W.; Zare, R.N., Radiative lifetimes of the alkaline earth monohalides, J. Chem. Phys., 1974, 60, 2330. [all data]

Hildenbrand, 1968
Hildenbrand, D.L., Mass-spectrometric studies of bonding in the group IIA fluorides, J. Chem. Phys., 1968, 48, 3657. [all data]

Blue, Green, et al., 1963
Blue, G.D.; Green, J.W.; Ehlert, T.C.; Margrave, J.L., Dissociation energies of the alkaline earth monofluorides, Nature (London), 1963, 199, 804. [all data]

Ehlert, Blue, et al., 1964
Ehlert, T.C.; Blue, G.D.; Green, J.W.; Margrave, J.L., Mass spectrometric studies at high temperatures. IV. Dissociation energies of the alkaline earth monofluorides, J. Chem. Phys., 1964, 41, 2250. [all data]

Ryabova and Gurvich, 1964
Ryabova, V.G.; Gurvich, L.V., Determination of dissociation energies of metal halides from equilibria in flames. 2. Dissociation energies of CaF, CaF₂, SrF, and SrF₂, High Temp. Engl. Transl., 1964, 2, 749, In original 834. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Constants of diatomic molecules, References

• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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