Niobium dimer


Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through March, 1975

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for 93Nb2
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
A (280) 1          A ← X 1 (18704)
Green and Gruen, 1972
X 0           

Notes

1Absorption in Ar matrix at 14 K.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Green and Gruen, 1972
Green, D.W.; Gruen, D.M., Absorption spectra of Nb atoms isolated in rare-gas matrices, J. Chem. Phys., 1972, 57, 4462. [all data]


Notes

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