Silane, chlorotrimethyl-
- Formula: C3H9ClSi
- Molecular weight: 108.642
- IUPAC Standard InChIKey: IJOOHPMOJXWVHK-UHFFFAOYSA-N
- CAS Registry Number: 75-77-4
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Chlorotrimethylsilane; Trimethylchlorosilane; Trimethylsilyl chloride; (CH3)3SiCl; Monochlorotrimethylsilicon; Silane, trimethylchloro-; Silicane, chlorotrimethyl-; TL 1163; UN 1298; Silylium, trimethyl-, chloride; Monochlorotrimethylsilane; NSC 15750; Trimethylsilane chloride; KA 31; TSL 8031
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°liquid | 275.1 | J/mol*K | N/A | Samorukov, Kostryukov, et al., 1971 |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
187.5 | 298.15 | Samorukov, Kostryukov, et al., 1971 | T = 12.38 to 303.05 K. Cp(liq) = 18.19046 + 0.077664T + 309052T-2 cal/mol*K. Value is calculated from equation. Deposited in VINITI, No 2501-71, 18 January 1971. |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
+ = C3H9Cl2Si-
By formula: Cl- + C3H9ClSi = C3H9Cl2Si-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.8 ± 5.9 | kJ/mol | CIDT | Hao, Kaspar, et al., 2005 | gas phase |
References
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Samorukov, Kostryukov, et al., 1971
Samorukov, O.P.; Kostryukov, V.N.; Samorukova, N.Kh.,
Thermodynamics of chlorosilanes with organic substituents. Low-temperature heat capacity, temperatures, and heats of phase transformation and thermodynamics functions of the condensed phase of chlorotrimethylsilane,
Russ. J. Phys. Chem., 1971, 45, 562-563. [all data]
Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S.,
Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-),
J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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