phosphorus
- Formula: P
- Molecular weight: 30.973762
- IUPAC Standard InChIKey: OAICVXFJPJFONN-UHFFFAOYSA-N
- CAS Registry Number: 7723-14-0
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: red phosphorus; Phosphorus atom
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- NIST Atomic Spectra Database - Lines Holdings (on physics web site)
- NIST Atomic Spectra Database - Levels Holdings (on physics web site)
- NIST Atomic Spectra Database - Ground states and ionization energies (on physics web site)
- Gas Phase Kinetics Database
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: (HP- • 4294967295P) + P = HP-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 325. ± 35. | kJ/mol | N/A | Ervin and Lineberger, 2005 | gas phase |
ΔrH° | 325. ± 34. | kJ/mol | Ther | Zittel and Lineberger, 1976 | gas phase |
(CAS Reg. No. 329230-30-0 • 4294967295) + = CAS Reg. No. 329230-30-0
By formula: (CAS Reg. No. 329230-30-0 • 4294967295P) + P = CAS Reg. No. 329230-30-0
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 354. ± 21. | kJ/mol | N/A | Jones, Ganteför, et al., 1995 | gas phase; Vertical Detachment Energy: 1.68±0.05 eV |
By formula: (OP- • 4294967295P) + P = OP-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 558.0 ± 3.5 | kJ/mol | N/A | Zittel and Lineberger, 1976 | gas phase |
(CAS Reg. No. 55030-79-0 • 4294967295) + = CAS Reg. No. 55030-79-0
By formula: (CAS Reg. No. 55030-79-0 • 4294967295P) + P = CAS Reg. No. 55030-79-0
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 229.3 ± 3.3 | kJ/mol | N/A | Snodgrass, Coe, et al., 1985 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ervin and Lineberger, 2005
Ervin, K.M.; Lineberger, W.C.,
Photoelectron spectroscopy of phosphorus hydride anions,
J. Chem. Phys., 2005, 122, 19, 194303, https://doi.org/10.1063/1.1881153
. [all data]
Zittel and Lineberger, 1976
Zittel, P.F.; Lineberger, W.C.,
Laser photoelectron spectrometry of PO-, PH-, and PH2-,
J. Chem. Phys., 1976, 65, 1236. [all data]
Jones, Ganteför, et al., 1995
Jones, R.O.; Ganteför, G.; Hunsicker, S.; Pieperhoff, P.,
Structure and Spectroscopy of Phosphorous Cluster anions: Theory (simulated annealing) and Experiment (Photoelectron Detachment),
J. Chem. Phys., 1995, 103, 22, 9549, https://doi.org/10.1063/1.469969
. [all data]
Snodgrass, Coe, et al., 1985
Snodgrass, J.T.; Coe, J.V.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H.,
Negative ion photoelectron spectroscopy of P2-,
Chem. Phys. Lett., 1985, 122, 352. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.