Oxygen anion
- Formula: O2-
- Molecular weight: 31.9993
- IUPAC Standard InChI: InChI=1S/HO2/c1-2/h1H/p-1
- IUPAC Standard InChIKey: OUUQCZGPVNCOIJ-UHFFFAOYSA-M
- CAS Registry Number: 11062-77-4
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
+
= (
•
)
By formula: O2- + O2 = (O2- • O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 48. ± 20. | kJ/mol | AVG | N/A | Average of 5 out of 7 values; Individual data points |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 102. | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
| ΔrS° | 130. | J/mol*K | PHPMS | Conway and Nesbit, 1968 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 13. ± 4.6 | kJ/mol | TDAs | Hiraoka, 1888 | gas phase; see also Sherwood, Hanold, et al., 1996. Aquino, Taylor, et al., 2001 calns indicate rectangular anion; B |
| ΔrG° | 23. ± 4.2 | kJ/mol | IMRE | Payzant J.D. and Kebarle, 1972 | gas phase; B |
| ΔrG° | 13. ± 4.2 | kJ/mol | IMRE | Pack and Phelps, 1971 | gas phase; B |
| ΔrG° | 16.7 ± 2.1 | kJ/mol | IMRE | Parkes, 1971 | gas phase; B |
| ΔrG° | 16. ± 4.2 | kJ/mol | TDAs | Conway and Nesbit, 1968 | gas phase; B |
Free energy of reaction
| ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 15. | 300. | DT | Pack and Phelps, 1971 | gas phase; M |
+
= (
•
)
By formula: O2- + CO2 = (O2- • CO2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 79.50 ± 0.84 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
| ΔrH° | 74.1 ± 7.5 | kJ/mol | IMRE | Pack and Phelps, 1966 | gas phase; Corrected with more recent EA(O2) = 0.45 eV; B,M |
| ΔrH° | 106. ± 19. | kJ/mol | PDis | Vestal and Mauclaire, 1977 | gas phase; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 101. | J/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
| ΔrS° | 88. | J/mol*K | DT | Pack and Phelps, 1966 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 49.0 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
| ΔrG° | 51.0 ± 5.0 | kJ/mol | IMRE | Pack and Phelps, 1966 | gas phase; Corrected with more recent EA(O2) = 0.45 eV; B |
| ΔrG° | 41.8 | kJ/mol | FA | Adams and Bohme, 1970 | gas phase; switching reaction(O2-)O2; Conway and Nesbit, 1968; M |
Free energy of reaction
| ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 54.0 | 296. | FA | Fehsenfeld and Ferguson, 1974 | gas phase; switching reaction(O2-)H2O; Arshadi and Kebarle, 1970; M |
( •
) +
= (
• 2
)
By formula: (O2- • H2O) + H2O = (O2- • 2H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 72.0 ± 4.2 | kJ/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 105. | J/mol*K | PHPMS | Arshadi and Kebarle, 1970 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 40.6 | kJ/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase; B |
| ΔrG° | 36. ± 4.2 | kJ/mol | IMRE | Payzant J.D. and Kebarle, 1972 | gas phase; B |
| ΔrG° | 41. ± 4.2 | kJ/mol | IMRE | Pack and Phelps, 1971 | gas phase; B |
Free energy of reaction
| ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 35. | 300. | PHPMS | Payzant J.D. and Kebarle, 1972 | gas phase; M |
( • 2
) +
= (
• 3
)
By formula: (O2- • 2H2O) + H2O = (O2- • 3H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 64.4 ± 4.2 | kJ/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 118. | J/mol*K | PHPMS | Arshadi and Kebarle, 1970 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 29.3 | kJ/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase; B |
| ΔrG° | 26. ± 8.4 | kJ/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
Free energy of reaction
| ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 22. | 296. | FA | Fehsenfeld and Ferguson, 1974 | gas phase; M |
| 30. | 300. | PHPMS | Payzant J.D. and Kebarle, 1972 | gas phase; M |
+
= (
•
)
By formula: O2- + H2O = (O2- • H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 93.3 ± 6.3 | kJ/mol | N/A | Luong, Clements, et al., 2001 | gas phase; Vertical Detachment Energy: 2.03±0.05 eV.; B |
| ΔrH° | 77.0 ± 8.4 | kJ/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 84.1 | J/mol*K | PHPMS | Arshadi and Kebarle, 1970 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 52.3 ± 8.4 | kJ/mol | TDAs | Arshadi and Kebarle, 1970 | gas phase; B |
| ΔrG° | 49.0 ± 8.4 | kJ/mol | IMRE | Parkes, 1971 | gas phase; B |
( • 7
•
) +
= (
• 8
•
)
By formula: (O2- • 7N2 • O2) + N2 = (O2- • 8N2 • O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 7. ± 1. | kJ/mol | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
| ΔrH° | 6.40 | kJ/mol | PHPMS | Hiraoka, 1988, 2 | gas phase; Entropy change calculated or estimated; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 74.9 | J/mol*K | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
| ΔrS° | 75.3 | J/mol*K | N/A | Hiraoka, 1988, 2 | gas phase; Entropy change calculated or estimated; M |
( • 2
) +
= (
• 3
)
By formula: (O2- • 2N2O) + N2O = (O2- • 3N2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 26.8 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | -3. ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
( • 3
) +
= (
• 4
)
By formula: (O2- • 3N2O) + N2O = (O2- • 4N2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.8 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | -6.3 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
( • 4
) +
= (
• 5
)
By formula: (O2- • 4N2O) + N2O = (O2- • 5N2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.2 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | -7.9 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
( • 5
) +
= (
• 6
)
By formula: (O2- • 5N2O) + N2O = (O2- • 6N2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 20.9 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | -9.2 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
( •
) +
= (
• 2
)
By formula: (O2- • N2O) + N2O = (O2- • 2N2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 36.4 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 110. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 3. ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
( • 2
) +
= (
• 3
)
By formula: (O2- • 2CH4O) + CH4O = (O2- • 3CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 56.5 ± 2.9 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 117. | J/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 21.8 ± 1.3 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
( • 2
) +
= (
• 3
)
By formula: (O2- • 2C2H3N) + C2H3N = (O2- • 3C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 49.8 ± 2.5 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 103. | J/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 18.8 ± 0.84 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
+
= (
•
)
By formula: O2- + N2O = (O2- • N2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | <56.90 | kJ/mol | IMRB | Adams and Bohme, 1970 | gas phase; N2O..O2- + O2 -> O4- + N2O; B |
| ΔrH° | 37. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 110. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
( • 3
) +
= (
• 4
)
By formula: (O2- • 3C2H3N) + C2H3N = (O2- • 4C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 39.7 ± 2.1 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 93.7 | J/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 11.7 ± 0.42 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
( •
) +
= (
• 2
)
By formula: (O2- • CH4O) + CH4O = (O2- • 2CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 64.9 ± 3.3 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 104. | J/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 33.9 ± 1.7 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
( •
) +
= (
• 2
)
By formula: (O2- • C2H3N) + C2H3N = (O2- • 2C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 59.4 ± 2.9 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 92.0 | J/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 32.2 ± 1.7 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
( • 2
) +
= (
• 3
)
By formula: (O2- • 2CO2) + CO2 = (O2- • 3CO2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 26. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 96.2 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | -3. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
( • 3
) +
= (
• 4
)
By formula: (O2- • 3CO2) + CO2 = (O2- • 4CO2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 20. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 78.2 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | -3. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
( • 4
) +
= (
• 5
)
By formula: (O2- • 4CO2) + CO2 = (O2- • 5CO2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 77.0 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | -4.6 ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
( • 5
) +
= (
• 6
)
By formula: (O2- • 5CO2) + CO2 = (O2- • 6CO2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 18. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 79.5 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | -6.3 ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
( • 6
) +
= (
• 7
)
By formula: (O2- • 6CO2) + CO2 = (O2- • 7CO2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 17. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 80.8 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | -7.5 ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
( •
) +
= (
• 2
)
By formula: (O2- • CO2) + CO2 = (O2- • 2CO2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 27.6 ± 0.84 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 76.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1992 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 4.6 ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; B |
+
= (
•
)
By formula: O2- + CH4O = (O2- • CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 79.91 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 91.6 | J/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 52.30 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
+
= (
•
)
By formula: O2- + C2H3N = (O2- • C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 68.62 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 72.8 | J/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 46.86 | kJ/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
( • 6
) +
= (
• 7
)
By formula: (O2- • 6O2) + O2 = (O2- • 7O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 5.86 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; Entropy change calculated or estimated; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 67. | J/mol*K | N/A | Hiraoka, 1988 | gas phase; Entropy change calculated or estimated; M |
+
= (
•
)
By formula: O2- + N2 = (O2- • N2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 25. ± 4.2 | kJ/mol | N/A | Posey and Johnson, 1988 | gas phase; B |
| ΔrH° | <56.90 | kJ/mol | IMRB | Adams and Bohme, 1970 | gas phase; N2..O2- + O2 -> O4-; B |
+
= (
•
)
By formula: O2- + CO = (O2- • CO)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | <56.90 | kJ/mol | IMRB | Adams and Bohme, 1970 | gas phase; CO..O2- + O2 -> O4- + CO. G3MP2B3 calculations indicate a HOF(A-) ca. -38 kcal/mol; B |
( • 2
•
) +
= (
• 3
•
)
By formula: (O2- • 2N2 • O2) + N2 = (O2- • 3N2 • O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.3 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 76.6 | J/mol*K | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
( • 3
•
) +
= (
• 4
•
)
By formula: (O2- • 3N2 • O2) + N2 = (O2- • 4N2 • O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.0 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 78.2 | J/mol*K | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
( • 4
•
) +
= (
• 5
•
)
By formula: (O2- • 4N2 • O2) + N2 = (O2- • 5N2 • O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 8.1 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 81.6 | J/mol*K | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
( • 5
•
) +
= (
• 6
•
)
By formula: (O2- • 5N2 • O2) + N2 = (O2- • 6N2 • O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 7.6 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 81.6 | J/mol*K | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
( • 6
•
) +
= (
• 7
•
)
By formula: (O2- • 6N2 • O2) + N2 = (O2- • 7N2 • O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 7.1 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 78.7 | J/mol*K | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
( •
•
) +
= (
• 2
•
)
By formula: (O2- • N2 • O2) + N2 = (O2- • 2N2 • O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 11.7 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 74.9 | J/mol*K | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
( • 4294967295
) +
=
By formula: (O2- • 4294967295O) + O = O2-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 400.7 | kJ/mol | N/A | Ervin, Anusiewicz, et al., 2003 | gas phase; B |
| ΔrH° | 401. ± 4.2 | kJ/mol | Ther | Travers, Cowles, et al., 1989 | gas phase; B |
+
=
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1476.9 ± 3.0 | kJ/mol | D-EA | Travers, Cowles, et al., 1989 | gas phase; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1450.5 ± 3.4 | kJ/mol | H-TS | Travers, Cowles, et al., 1989 | gas phase; B |
( •
) +
= (
•
•
)
By formula: (O2- • O2) + N2 = (O2- • N2 • O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 12.0 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 69.0 | J/mol*K | PHPMS | Hiraoka, 1988, 2 | gas phase; M |
( • 3
) +
= (
• 4
)
By formula: (O2- • 3H2O) + H2O = (O2- • 4H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrG° | 18. ± 8.4 | kJ/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
| ΔrG° | 14. | kJ/mol | PHPMS | Arshadi and Kebarle, 1970 | gas phase; M |
( • 2
) +
= (
• 3
)
By formula: (O2- • 2O2) + O2 = (O2- • 3O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.0 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 89.1 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
( • 3
) +
= (
• 4
)
By formula: (O2- • 3O2) + O2 = (O2- • 4O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 7. ± 1. | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 64.4 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
( • 4
) +
= (
• 5
)
By formula: (O2- • 4O2) + O2 = (O2- • 5O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 6.4 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 64.4 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
( • 5
) +
= (
• 6
)
By formula: (O2- • 5O2) + O2 = (O2- • 6O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 6. ± 1. | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 67.8 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
( •
) +
= (
• 2
)
By formula: (O2- • O2) + O2 = (O2- • 2O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.5 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 87.4 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
( •
) +
= (
•
•
)
By formula: (O2- • H2O) + CO2 = (O2- • CO2 • H2O)
Free energy of reaction
| ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 34. | 296. | FA | Fehsenfeld and Ferguson, 1974 | gas phase; switching reaction(O2-)2H2O; Arshadi and Kebarle, 1970; M |
+
= C5H5NO2-
By formula: O2- + C5H5N = C5H5NO2-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 90.8 ± 9.6 | kJ/mol | N/A | Le Barbu, Schiedt, et al., 2002 | gas phase; Affinity is difference in EAs of lesser solvated species; B |
+
= C6H6O2-
By formula: O2- + C6H6 = C6H6O2-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 59.0 ± 9.6 | kJ/mol | N/A | Le Barbu, Schiedt, et al., 2002 | gas phase; Affinity is difference in EAs of lesser solvated species; B |
+
= C10H8O2-
By formula: O2- + C10H8 = C10H8O2-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 92.5 ± 9.6 | kJ/mol | N/A | Le Barbu, Schiedt, et al., 2002 | gas phase; Affinity is difference in EAs of lesser solvated species; B |
+
= (
•
)
By formula: O2- + Ar = (O2- • Ar)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 6.95 | kJ/mol | N/A | Bowen and Eaton, 1988 | gas phase; Bound by 70 meV relative to EA(O2-.); B |
( • 4
) +
= (
• 5
)
By formula: (O2- • 4H2O) + H2O = (O2- • 5H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrG° | 14. ± 8.4 | kJ/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B |
Constants of diatomic molecules
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through March, 1977
| Symbol | Meaning |
|---|---|
| State | electronic state and / or symmetry symbol |
| Te | minimum electronic energy (cm-1) |
| ωe | vibrational constant – first term (cm-1) |
| ωexe | vibrational constant – second term (cm-1) |
| ωeye | vibrational constant – third term (cm-1) |
| Be | rotational constant in equilibrium position (cm-1) |
| αe | rotational constant – first term (cm-1) |
| γe | rotation-vibration interaction constant (cm-1) |
| De | centrifugal distortion constant (cm-1) |
| βe | rotational constant – first term, centrifugal force (cm-1) |
| re | internuclear distance (Å) |
| Trans. | observed transition(s) corresponding to electronic state |
| ν00 | position of 0-0 band (units noted in table) |
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| b | 118540 | 1290 1 | 14.27 eV 2 | |||||||||
| ↳Sanche and Schulz, 1972; Schulz, 1973 | ||||||||||||
| a (4Πu) | 97800 | 1044 | 10 3 | 11.68 eV 4 | ||||||||
| ↳Sanche and Schulz, 1972; Schulz, 1973 | ||||||||||||
| Additional resonances in the electron transmission current at 8-11 eV. 2 | ||||||||||||
| ↳Sanche and Schulz, 1972; Schulz, 1973 | ||||||||||||
| Several bound excited states predicted by theoretical calculations Krauss, Neumann, et al., 1973. | ||||||||||||
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
| A (2Πu) | (25300) | (574.5) 5 | (7.1) 5 | A ↔ X 6 | (25000) 7 | |||||||
| ↳Rolfe, 1964; Ikezawa and Rolfe, 1973 | ||||||||||||
| Photodetachment cross sections 6700 - 4600 Å (14900 - 21800 cm-1). | ||||||||||||
| ↳Cosby, Ling, et al., 1976 | ||||||||||||
| X 2Πgi | 0 8 | 1090 9 | 8.1 9 | 1.35 10 11 | ||||||||
| ↳Creighton and Lippincott, 1964; Holzer, Murphy, et al., 1968 | ||||||||||||
| EPR sp. 12 | ||||||||||||
| ↳Kanzig and Cohen, 1959; Zeller and Kanzig, 1967 | ||||||||||||
Notes
| 1 | Short progression of resonances in electron transmission. 15 |
| 2 | Energy relative to X 3Σg-(v=0) of neutral O2. |
| 3 | Long progression of resonances in electron transmission. 16 |
| 4 | Extrapo1ated energy of v=0 relative to X 3Σg-(v=0) of neutral O2. |
| 5 | Absorption in KBr, vibrational numbering uncertain Ikezawa and Rolfe, 1973. |
| 6 | Observed in alkali halide crystals at 4.2 and 2 K. |
| 7 | Estimated v00 for the free O2- ion, by extrapolation from data for various host crystals Holzer, Murphy, et al., 1968. |
| 8 | A = -160 cm-1 103. |
| 9 | From electron scattering cross sections for gaseous O2 Boness and Schulz, 1970, Linder and Schmidt, 1971; similar measurements by Gray, Haselton, et al., 1972 suggest ωe = 1140 Gray, Haselton, et al., 1972, ωexe = 12 Gray, Haselton, et al., 1972. A direct measurement of ΔG"(1/2) in the photodetachment spectrum Celotta, Bennett, et al., 1972 gives ΔG"(1/2) ~ 1090 cm-1 Celotta, Bennett, et al., 1972, in agreement with extrapolations from Raman frequencies in alkali halide crystals Holzer, Murphy, et al., 1968. Anharmonicities derived from low-temperature fluorescence spectra (see 6) are approximately 8.7 Ikezawa and Rolfe, 1973. |
| 10 | From a Franck-Condon factor analysis of the photodetachment spectrum Celotta, Bennett, et al., 1972 and a similar evaluation by Parlant and Fiquet-Fayard, 1976 of the electron scattering data of Linder and Schmidt, 1971. |
| 11 | Raman sp. 17 |
| 12 | In alkali halide crystals. |
| 13 | From D00(O2) and the electron affinities of O(1.462 eV) and O2. |
| 14 | From the O2- photodetachment spectrum Celotta, Bennett, et al., 1972; see also Pack and Phelps, 1966, 2. From endothermic negative-ion charge-transfer reactions Tiernan, Hughes, et al., 1971 obtain I.P. ≥ 0.45 ± 0.1 eV. The theoretical value is 0.42eV Zemke, Das, et al., 1972. |
| 15 | "Band b". Suggested "grandparent" state b 4Σg- of O2+. |
| 16 | "Band a". The negative ion state results from the addition of two Rydberg electrons in the 3sσg orbital to the O2+ core in the a 4Πu state ("grandparent"). |
| 17 | In alkali ha1ide crystals and in solid KO2 and NaO2. |
References
Go To: Top, Reaction thermochemistry data, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka, 1988
Hiraoka, K.,
A Determination of the Stabilities of O2+(O2)n and O2-(O2)n with n = 1 - 8 from Measurements of the Gas-Phase Ion Equilibria,
J. Chem. Phys., 1988, 89, 5, 3190, https://doi.org/10.1063/1.454976
. [all data]
Conway and Nesbit, 1968
Conway, D.C.; Nesbit, L.E.,
Stability of O4-,
J. Chem. Phys., 1968, 48, 1, 509, https://doi.org/10.1063/1.1667956
. [all data]
Hiraoka, 1888
Hiraoka, K.,
A Determination of the Stability of O2+(O2)n and O2-(O2)n with n=1-8 from Measurements of the Gas Phase Ion Equilibria,
J. Chem. Phys., 1888, 89, 5, 3190, https://doi.org/10.1063/1.454976
. [all data]
Sherwood, Hanold, et al., 1996
Sherwood, C.R.; Hanold, K.A.; Garner, M.C.; Strong, K.M.; Continetti, R.E.,
Translational Spectroscopy Studies of the Photodissociation Dynamics of O4-,
J. Chem. Phys., 1996, 105, 24, 10803, https://doi.org/10.1063/1.472888
. [all data]
Aquino, Taylor, et al., 2001
Aquino, A.J.A.; Taylor, P.R.; Walch, S.P.,
Structure, properties, and photodissociation of O-4(-),
J. Chem. Phys., 2001, 114, 7, 3010-3017, https://doi.org/10.1063/1.1288379
. [all data]
Payzant J.D. and Kebarle, 1972
Payzant J.D.; Kebarle, P.,
Kinetics and Reactions Leading to O2-(H2O)n in Moist Oxygen,
J. Chem. Phys., 1972, 56, 7, 3482, https://doi.org/10.1063/1.1677723
. [all data]
Pack and Phelps, 1971
Pack, J.L.; Phelps, A.V.,
Hydration of Oxygen Negative Ions,
Bull. Am. Phys. Soc., 1971, 16, 214. [all data]
Parkes, 1971
Parkes, D.A.,
Electron Attachment and Negative Ion-Molecule Reactions in Pure O2,
Trans. Farad. Soc., 1971, 97, 711, https://doi.org/10.1039/tf9716700711
. [all data]
Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S.,
Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n,
J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560
. [all data]
Pack and Phelps, 1966
Pack, J.L.; Phelps, A.V.,
Electron Attachment and Detachment . II. Mixtures of O2 and CO2 and of O2 and H2O,
J. Chem. Phys., 1966, 45, 11, 4316, https://doi.org/10.1063/1.1727491
. [all data]
Vestal and Mauclaire, 1977
Vestal, M.L.; Mauclaire, G.H.,
Photodissociaton of negative ions formed in CO2 and CO2/O2 Mixtures,
J. Chem. Phys., 1977, 67, 3758. [all data]
Adams and Bohme, 1970
Adams, N.G.; Bohme, D.,
Flowing Afterglow Studies of Formation and Reactions of Cluster Ions of O2+, O2-, and O-,
J. Chem. Phys., 1970, 52, 6, 3133, https://doi.org/10.1063/1.1673449
. [all data]
Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E.,
Laboratory studies of negative ion reactions with atmospheric trace constituents,
J. Chem. Phys., 1974, 61, 3181. [all data]
Arshadi and Kebarle, 1970
Arshadi, M.; Kebarle, P.,
Hydration of OH- and O2- in the Gas Phase. Comparative Solvation of OH- by Water and the Hydrogen Halides. Effect of Acidity,
J. Phys. Chem., 1970, 74, 7, 1483, https://doi.org/10.1021/j100702a015
. [all data]
Kebarle, Arshadi, et al., 1968
Kebarle, P.; Arshadi, M.; Scarborough, J.,
Hydration of Negative Ions in the Gas Phase,
J. Chem. Phys., 1968, 49, 2, 817, https://doi.org/10.1063/1.1670145
. [all data]
Luong, Clements, et al., 2001
Luong, A.K.; Clements, T.G.; Resat, M.S.; Continetti, R.E.,
Energetics and dissociative photodetachment dynamics of superoxide-water clusters: O-2(-)(H2O)(n), n=1-6,
J. Chem. Phys., 2001, 114, 8, 3449-3455, https://doi.org/10.1063/1.1342221
. [all data]
Hiraoka, 1988, 2
Hiraoka, K.,
Determination of the Stabilities of O3-(N2)n, O3-(O2)n, and O4-(N2)n from Measurements of the Gas Phase Equilibria,
Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4
. [all data]
Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S.,
Gas-phase clustering reactions of O2(-), NO-, and O- with N2O: Isomeric structures for (NO-N2O)(-),
J. Phys. Chem., 1994, 98, 34, 8295, https://doi.org/10.1021/j100085a006
. [all data]
Yamdagni, Payzant, et al., 1973
Yamdagni, R.; Payzant, J.D.; Kebarle, P.,
Solvation of Cl- and O2- with H2O, CH3OH, and CH3CN in the gas phase,
Can. J. Chem., 1973, 51, 2507. [all data]
Posey and Johnson, 1988
Posey, L.A.; Johnson, M.A.,
Pulsed Photoelectron Spectroscopy of Negative Cluster Ions: Isolation of Three Distinguishable Forms of N2O2-,
J. Chem. Phys., 1988, 88, 9, 5385, https://doi.org/10.1063/1.454576
. [all data]
Ervin, Anusiewicz, et al., 2003
Ervin, K.M.; Anusiewicz, W.; Skurski, P.; Simons, J.; Lineberger, W.C.,
The only stable state of O-2(-) is the X (2)Pi(g) ground state and it (still!) has an adiabatic electron detachment energy of,
J. Phys. Chem. A, 2003, 107, 41, 8521-8529, https://doi.org/10.1021/jp0357323
. [all data]
Travers, Cowles, et al., 1989
Travers, M.J.; Cowles, D.C.; Ellison, G.B.,
Reinvestigation of the Electron Affinities of O2 and NO,
Chem. Phys. Lett., 1989, 164, 5, 449, https://doi.org/10.1016/0009-2614(89)85237-6
. [all data]
Le Barbu, Schiedt, et al., 2002
Le Barbu, K.; Schiedt, J.; Weinkauf, R.; Schlag, E.W.; Nilles, J.M.; Xu, S.J.; Thomas, O.C.; Bowen, K.H.,
Microsolvation of small anions by aromatic molecules: An exploratory study,
J. Chem. Phys., 2002, 116, 22, 9663-9671, https://doi.org/10.1063/1.1475750
. [all data]
Bowen and Eaton, 1988
Bowen, K.H.; Eaton, J.G.,
Photodetachment Spectroscopy of Negative Cluster Ions,
in The Structure of Small Molecules and Ions, Ed. R. Naaman, Z. Vager, Plenum NY, 1988, 1988, p.147-169. [all data]
Sanche and Schulz, 1972
Sanche, L.; Schulz, G.J.,
Electron transmission spectroscopy: core-excited resonances in diatomic molecules,
Phys. Rev. A: Gen. Phys., 1972, 6, 69. [all data]
Schulz, 1973
Schulz, G.J.,
Resonances in electron impact on diatomic molecules,
Rev. Mod. Phys., 1973, 45, 423. [all data]
Krauss, Neumann, et al., 1973
Krauss, M.; Neumann, D.; Wahl, A.C.; Das, G.; Zemke, W.,
Excited electronic states of O2,
Phys. Rev. A: Gen. Phys., 1973, 7, 69. [all data]
Rolfe, 1964
Rolfe, J.,
Low-temperature emission spectrum of O2- in alkali halides,
J. Chem. Phys., 1964, 40, 1664. [all data]
Ikezawa and Rolfe, 1973
Ikezawa, M.; Rolfe, J.,
Zero-phonon transitions in O2-, S2-, and Se2-, and SeS- molecules dissolved in alkali halide crystals,
J. Chem. Phys., 1973, 58, 2024. [all data]
Cosby, Ling, et al., 1976
Cosby, P.C.; Ling, J.H.; Peterson, J.R.; Moseley, J.T.,
Photodissociation and photodetachment of molecular negative ions. III. Ions formed in CO2.O2.H2O mixtures,
J. Chem. Phys., 1976, 65, 5267. [all data]
Creighton and Lippincott, 1964
Creighton, J.A.; Lippincott, E.R.,
Vibrational frequency and dissociation energy of the superoxide ion,
J. Chem. Phys., 1964, 40, 1779. [all data]
Holzer, Murphy, et al., 1968
Holzer, W.; Murphy, W.F.; Bernstein, H.J.; Rolfe, J.,
Raman spectrum of O2- ion in alkali halide crystals,
J. Mol. Spectrosc., 1968, 26, 543. [all data]
Kanzig and Cohen, 1959
Kanzig, W.; Cohen, M.H.,
Paramagnetic resonance of oxygen in alkali halides,
Phys. Rev. Lett., 1959, 3, 509. [all data]
Zeller and Kanzig, 1967
Zeller, H.R.; Kanzig, W.,
Die elekrtonische Struktur des O2--Zentrums in den Alkalihalogeniden. I. Die paramagnetischen und optischen Spektren und ihre Interpretation,
Helv. Phys. Acta, 1967, 40, 845. [all data]
Boness and Schulz, 1970
Boness, M.J.W.; Schulz, G.J.,
Structure of O2,
Phys. Rev. A: Gen. Phys., 1970, 2, 2182. [all data]
Linder and Schmidt, 1971
Linder, F.; Schmidt, H.,
Experimental study of low energy e - O2 collision processes,
Z. Naturforsch. A, 1971, 26, 1617. [all data]
Gray, Haselton, et al., 1972
Gray, R.L.; Haselton, H.H.; Krause, D., Jr.; Soltysik, E.A.,
Vibrational structure in electron scattering by O2,
Chem. Phys. Lett., 1972, 13, 51. [all data]
Celotta, Bennett, et al., 1972
Celotta, R.J.; Bennett, R.A.; Hall, J.L.; Siegel, M.W.; Levine, J.,
Molecular photodetachment spectrometry. II. The electron affinity of O2 and the structure of O2-,
Phys. Rev. A:, 1972, 6, 631. [all data]
Parlant and Fiquet-Fayard, 1976
Parlant, G.; Fiquet-Fayard, F.,
The O2- 2Πg resonance: theoretical analysis of electron scattering data,
J. Phys. B:, 1976, 9, 1617. [all data]
Pack and Phelps, 1966, 2
Pack, J.L.; Phelps, A.V.,
Electron Attachment and Detachment. I. Pure O2 at Low Energy,
J. Chem. Phys., 1966, 44, 5, 1870, https://doi.org/10.1063/1.1726956
. [all data]
Tiernan, Hughes, et al., 1971
Tiernan, T.O.; Hughes, B.M.; Lifschitz, C.,
Electron affinities from endothermic negative ion charge transfer reactions. II. O2,
J. Chem. Phys., 1971, 55, 5692. [all data]
Zemke, Das, et al., 1972
Zemke, W.T.; Das, G.; Wahl, A.C.,
Theoretical determination of the electron affinity of O2 molecule from the binding energy of O2-,
Chem. Phys. Lett., 1972, 14, 310. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Constants of diatomic molecules, References
- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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