hydrogen fluoride

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Reaction thermochemistry data

Go To: Top, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Fluorine anion + Hydrogen cation = hydrogen fluoride

By formula: F- + H+ = HF

Quantity Value Units Method Reference Comment
ΔrH°372. ± 1.kcal/molAVGN/AAverage of 6 out of 7 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrG°365.67 ± 0.18kcal/molH-TSBlondel, Delsart, et al., 2001gas phase; Given: 3.4011895(25) eV, or 27432.446(19) cm-1, or 78.433266(577) kcal/mol; B
ΔrG°365.53kcal/molH-TSMartin and Hepburn, 2000gas phase; Given: 371.334±0.003 kcal/mol (corr to 298K with data from Wagman, Evans, et al., 1982).H(0K)=370.422±0.003; B
ΔrG°365.67 ± 0.18kcal/molH-TSBlondel, Cacciani, et al., 1989gas phase; Reported: 3.401190±0.000004 eV. acidity includes 0.9 kcal 0 to 298 K correction.; B
ΔrG°365.5 ± 2.0kcal/molIMREBierbaum, Schmidt, et al., 1981gas phase; B
ΔrG°359.40kcal/molN/ACheck, Faust, et al., 2001gas phase; FeCl3-; ; ΔS(EA)=5.0; B

Fluorine anion + hydrogen fluoride = (Fluorine anion • hydrogen fluoride)

By formula: F- + HF = (F- • HF)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°45.8 ± 1.6kcal/molCIDCWenthold and Squires, 1995gas phase; B
ΔrH°38.6 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M
ΔrH°>34.6 ± 4.6kcal/molTherHeni and Illenberger, 1985gas phase; From CHF=CHF. Outdataed HC2. thermo used. Current value ( Berkowitz, Ellison, et al., 1994) implies Haff>57.; B
Quantity Value Units Method Reference Comment
ΔrS°21.9cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction,Thermochemical ladder(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°32.0 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
32.0289.ICRLarson and McMahon, 1983gas phase; switching reaction,Thermochemical ladder(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M

Chlorine anion + hydrogen fluoride = (Chlorine anion • hydrogen fluoride)

By formula: Cl- + HF = (Cl- • HF)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°21.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°22.5cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)SO2, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
ΔrG°15.1 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Bromine anion + hydrogen fluoride = (Bromine anion • hydrogen fluoride)

By formula: Br- + HF = (Br- • HF)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°17.0 ± 2.0kcal/molEstLarson and McMahon, 1984, 3gas phase; Extrapolated from other bihalide data; B
ΔrH°17.0kcal/molHPMSCaldwell, Masucci, et al., 1989gas phase; M

Iodide + hydrogen fluoride = (Iodide • hydrogen fluoride)

By formula: I- + HF = (I- • HF)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°15.0 ± 2.0kcal/molEstLarson and McMahon, 1984, 3gas phase; Extrapolated from other bihalide data; B
ΔrH°15.kcal/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M

Tetrafluoromethane + 2Water = Carbon dioxide + 4hydrogen fluoride

By formula: CF4 + 2H2O = CO2 + 4HF

Quantity Value Units Method Reference Comment
ΔrH°-41.5 ± 1.0kcal/molCmGood, Scott, et al., 1956gas phase; HF has 10 moles H2O, see Scott, Good, et al., 1955; ALS
ΔrH°-41.5 ± 1.0kcal/molCmScott, Good, et al., 1955gas phase; Heat of hydrolysis; ALS

Hydrogen + Propane, 2-fluoro- = Propane + hydrogen fluoride

By formula: H2 + C3H7F = C3H8 + HF

Quantity Value Units Method Reference Comment
ΔrH°-20.20 ± 0.30kcal/molChydLacher, Kianpour, et al., 1956gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -21.11 ± 0.69 kcal/mol; %hf298_gas[kcal/mol]=-66.97±0.71; Kolesov and Kozina, 1986; ALS

Hydrogen + n-Propyl fluoride = Propane + hydrogen fluoride

By formula: H2 + C3H7F = C3H8 + HF

Quantity Value Units Method Reference Comment
ΔrH°-22.00 ± 0.50kcal/molChydLacher, Kianpour, et al., 1956gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -22.9 ± 1.6 kcal/mol; %hf298_gas[kcal/mol]=-66.71±0.62; Kolesov and Kozina, 1986; ALS

2-Fluoro-N-(2-fluoro-2,2-dinitroethyl)-N,2,2-trinitroethylamine + 6Oxygen + Ethanedioic acid, diethyl ester = 10Carbon dioxide + 2hydrogen fluoride + 3Nitrogen + 6Water

By formula: C4H4F2N6O10 + 6O2 + C6H10O4 = 10CO2 + 2HF + 3N2 + 6H2O

Quantity Value Units Method Reference Comment
ΔrH°-1189.33 ± 0.56kcal/molCcrBaroody and Carpenter, 1973solid phase; Corrected for CODATA value of ΔfH; HF.100H2O; ALS

C4F9O- + hydrogen fluoride = (C4F9O- • hydrogen fluoride)

By formula: C4F9O- + HF = (C4F9O- • HF)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°17.kcal/molICRLarson and McMahon, 1983gas phase; M

C3HF6O- + hydrogen fluoride = (C3HF6O- • hydrogen fluoride)

By formula: C3HF6O- + HF = (C3HF6O- • HF)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°25.kcal/molICRLarson and McMahon, 1983gas phase; M

C4H3F6O- + hydrogen fluoride = (C4H3F6O- • hydrogen fluoride)

By formula: C4H3F6O- + HF = (C4H3F6O- • HF)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°26.kcal/molICRLarson and McMahon, 1983gas phase; M

Carbonic difluoride + Water = Carbon dioxide + 2hydrogen fluoride

By formula: CF2O + H2O = CO2 + 2HF

Quantity Value Units Method Reference Comment
ΔrH°-26.73 ± 0.25kcal/molCcrWartenberg, 1949gas phase; solvent: Gas phase;; Corrected for CODATA value of ΔfH; ALS

Ethane, 2-chloro-1,1,1,2-tetrafluoro- + hydrogen fluoride = Ethane, pentafluoro- + Hydrogen chloride

By formula: C2HClF4 + HF = C2HF5 + HCl

Quantity Value Units Method Reference Comment
ΔrH°-2.5 ± 1.5kcal/molKinCoulson, 1993gas phase; solvent: On solid catalyst; ALS

Ethane, 2-chloro-1,1,1,2-tetrafluoro- + Hydrogen chloride = Ethane, 2,2-dichloro-1,1,1-trifluoro- + hydrogen fluoride

By formula: C2HClF4 + HCl = C2HCl2F3 + HF

Quantity Value Units Method Reference Comment
ΔrH°-0.4 ± 1.4kcal/molKinCoulson, 1993gas phase; solvent: On solid catalyst; ALS

(H2F+ • hydrogen fluoride) + hydrogen fluoride = (H2F+ • 2hydrogen fluoride)

By formula: (H2F+ • HF) + HF = (H2F+ • 2HF)

Quantity Value Units Method Reference Comment
ΔrH°14.8 ± 4.2kcal/molPITiedemann, Anderson, et al., 1979gas phase; M

Ethene, tetrafluoro- + 2Hydrogen = 2carbon + 4hydrogen fluoride

By formula: C2F4 + 2H2 = 2C + 4HF

Quantity Value Units Method Reference Comment
ΔrH°-147.8 ± 1.1kcal/molChydNeugebauer and Margrave, 1956gas phase; ALS

Hydrogen fluoride, positive ion + hydrogen fluoride = (Hydrogen fluoride, positive ion • hydrogen fluoride)

By formula: HF+ + HF = (HF+ • HF)

Quantity Value Units Method Reference Comment
ΔrH°33.kcal/molPITiedemann, Anderson, et al., 1979gas phase; ΔrH>; M

Tetrafluoromethane + 4hydrogen fluoride = Methane + 4fluorine

By formula: CF4 + 4HF = CH4 + 4F2

Quantity Value Units Method Reference Comment
ΔrH°-459.3 ± 3.0kcal/molCmJessup, McCoskey, et al., 1955gas phase; ALS

H2F+ + hydrogen fluoride = (H2F+ • hydrogen fluoride)

By formula: H2F+ + HF = (H2F+ • HF)

Quantity Value Units Method Reference Comment
ΔrH°25.1 ± 2.5kcal/molPITiedemann, Anderson, et al., 1979gas phase; M

Ethene, fluoro- + hydrogen fluoride = Ethane, 1,1-difluoro-

By formula: C2H3F + HF = C2H4F2

Quantity Value Units Method Reference Comment
ΔrH°-12.kcal/molEqkMoore, 1971gas phase; ALS

Constants of diatomic molecules

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through January, 1977

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for H19F
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
Rydberg 1Rydberg levels converging to the ground state of HF+ have been observed in the electronic energy loss spectrum.
D 1Σ+ 1           D ← X 
↳di Londardo and Douglas, 1973
C 1Π (105820) [2636]   [16.0]     [1.049] C ← X R 105090.8
↳di Lonardo and Douglas, 1972; di Londardo and Douglas, 1973
b 3Π 2           b ← X 
↳di Lonardo and Douglas, 1972
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
B 1Σ+ 84776.65 1159.18 Z 18.005 3 0.184 4.0291 4 0.0177 5  1.932E-4 6  2.09086 B ↔ X 7 R 83304.96 Z
↳Johns and Barrow, 1959; missing citation
AContinuous absorption starting at 60600 cm-1. 8
↳Safari, 1954
X 1Σ+ 0 4138.32 9 Z 89.88 10  20.9557 9 11 12 0.798 13  21.51E-4 14  0.916808 15  
↳Mann, Thrush, et al., 1961; Herget, Deeds, et al., 1962; Fishburne and Rao, 1966; Webb and Rao, 1968
Rotation sp. 16 17
↳Rothschild, 1964; Revich and Stankevich, 1966; Mason and Nielsen, 1967
Mol. Beam el. Reson. 18
↳Weiss, 1963; Muenter and Klemperer, 1970; Muenter, 1972; de Leeuw and Dymanus, 1973
Mol. Beam magn. Reson. 19
↳Baker, Nelson, et al., 1961

Notes

1Two strong bands between 104000 and 116000 cm-1, not yet analysed.
2Absorption bands above 100000 cm-1, not yet analysed.
3The vibrational and rotational constants, were obtained from a fit to the seven lowest vibrational levels di Londardo and Douglas, 1973. See 7.
4RKR potential curves Fallon, Vanderslice, et al., 1960, di Londardo and Douglas, 1973.
5-0.000950(v+1/2)2 + 0.000060l(v+1/2)3; see 3.
6+0.182E-4(v+1/2) + 0.00551E-4(v+1/2)2; see 3.
7Very extensive band system (also called V-X) extending in absorption from 96000 to 117000, in emission from 36000 to 70000 cm-1. Strong perturbations above v'=27, but bands have been identified to v'=73. The B (or V) state was also observed in the electron energy loss spectrum Salama and Hasted, 1976.
8HF is quite transparent to 1650 Safari, 1954. Theoretical potential curves for three repulsive states (3Π, 1Π, 3Σ+) arising from ground state atomic products were given by Dunning, 1976.
9Introduction of the Dunham correction Webb and Rao, 1968 gives ωe = 4138.767 Webb and Rao, 1968 and Be = 20.9561.
10+0.90(v+1/2)3 - 0.0ll0(v+1/2)4 - 0.00067(v+1/2)5, v≤9 Webb and Rao, 1968. A different formula for higher vibrational levels (v≤19) was derived by Johns and Barrow, 1959. All levels up to the last (v=19) are tabulated in di Londardo and Douglas, 1973).
11For v=14,...19 the rotational levels break off at decreasing J on account of predissociation by rotation. A few broadened lines near these limits have been observed di Londardo and Douglas, 1973. From the limiting curve the dissociation energy 47333 ± 60 cm-1 has been determined di Londardo and Douglas, 1973.
12RKR potential curves Fallon, Vanderslice, et al., 1960, di Londardo and Douglas, 1973, Dunham potential coefficients Webb and Rao, 1968, Ogilvie and Koo, 1976. Ab initio calculations of molecular constants Bondybey, Pearson, et al., 1972, Krauss and Neumann, 1974, Meyer and Rosmus, 1975, Dunning, 1976.
13+0.0127(v+1/2)2 - 0.00044(v+1/2)3 , from Webb and Rao, 1968.
14-0.68E-4(v+1/2)+0.029E-4(v+1/2)2, He = 1.59E-7; from Webb and Rao, 1968; see also Mann, Thrush, et al., 1961.
15Rot.-vibr. Sp. 22 23 17
16Laser emission in the pure rotation spectrum Deutsch, 1967.
17Rotation and rotation-vibration spectra in rare-gas matrices Mason, von Holle, et al., 1971.
18μel(v=0,J=1) = 1.82618 D Muenter and Klemperer, 1970, Muenter, 1972; gJ = 0.7410, quadrupole moment Θm= 2.36E-26 esu cm2 de Leeuw and Dymanus, 1973; also nuclear spin - rotation and other hyperfine structure constants.
19Nuclear reorientation spectrum.
20From the limiting curve of dissociation for the ground state di Londardo and Douglas, 1973; see 11.
21From photoelectron spectra Walker, Dehmer, et al., 1973, Guyon, Spohr, et al., 1976. Earlier photoionization studies yielded 16.007 eV Berkowitz, Chupka, et al., 1971, a value strongly affected by the presence of autoionizing Rydberg levels in the threshold region Guyon, Spohr, et al., 1976. The second ionization potential (removal of a 3σ electron) from the photoelectron spectrum Berkowitz, 1971, Guyon, Spohr, et al., 1976 is 19.118 eV in agreement with the value derived from the spectrum of HF+. The third and fourth ionization potentials (removal of a 2σ and 1σ electron, respectively) are 39.61 Banna and Shirley, 1975, Shaw and Thomas, 1975 and 694.25 eV Shaw and Thomas, 1975; these are vertical potentials from X-ray photoelectron spectra.
221-0, 2-0 bands studied in absorption under high resolution by Herget, Deeds, et al., 1962, Webb and Rao, 1968, 3-0, 4-0, 5-0 in the photographic infrared by Naude and Verleger, 1950, Fishburne and Rao, 1966. In emission, rotation-vibration bands have been studied by Mann, Thrush, et al., 1961 and Sileo and Cool, 1976, the latter extending the chemical laser emission, first observed in the 2-1 band by Kompa and Pimentel, 1967, to v=9 and Δv=6. Electric discharge induced laser emission in the 3-2, 2-1, 1-0 bands, see Deutsch, 1967, 2, Coldhar, Osgood, et al., 1971.
23Line strengths, collision-broadened widths, dipole moment function Meredith, 1972, Spellicy, Meredith, et al., 1972, Lie, 1974, Rimpel, 1974, Sileo and Cool, 1976, Yardley and Balint-Kurti, 1976. The radiative lifetime of v=1 [P(4) line] is 6.16 ms Hinchen, 1974. Sileo and Cool, 1976 give a vibrational dipole moment matrix for v ≤ 9 based on intensity measurements in chemical laser emission.

References

Go To: Top, Reaction thermochemistry data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blondel, Delsart, et al., 2001
Blondel, C.; Delsart, C.; Goldfarb, F., Electron spectrometry at the mu eV level and the electron affinities of Si and F, J. Phys. B: Atom. Mol. Opt. Phys., 2001, 34, 9, L281-L288, https://doi.org/10.1088/0953-4075/34/9/101 . [all data]

Martin and Hepburn, 2000
Martin, J.D.D.; Hepburn, J.W., Faraday Disc. Chem. Soc., 2000, 115, 416. [all data]

Wagman, Evans, et al., 1982
Wagman, D.D.; Evans, W.H.; Parker, V.B.; Schumm, R.H.; Halow, I.; Bailey, S.M.; Churney, K.L.; Nuttall, R.L., The NBS Tables of Chemical Thermodynamic Properties (NBS Tech Note 270), J. Phys. Chem. Ref. Data, Supl. 1, 1982, 11. [all data]

Blondel, Cacciani, et al., 1989
Blondel, C.; Cacciani, P.; Delsart, C.; Trainham, R., High Resolution Determination of the Electron Affinity of Fluorine and Bromine using Crossed Ion and Laser Beams, Phys. Rev. A, 1989, 40, 7, 3698, https://doi.org/10.1103/PhysRevA.40.3698 . [all data]

Bierbaum, Schmidt, et al., 1981
Bierbaum, V.M.; Schmidt, R.J.; DePuy, C.H.; Mead, R.H.; Schulz, P.A.; Lineberger, W.C., Reactions of carbanions with triplet and singlet molecular oxygen, J. Am. Chem. Soc., 1981, 103, 6262. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Wenthold and Squires, 1995
Wenthold, P.G.; Squires, R.R., Bond dissociation energies of F2(-) and HF2(-). A gas-phase experimental and G2 theoretical study, J. Phys. Chem., 1995, 99, 7, 2002, https://doi.org/10.1021/j100007a034 . [all data]

Larson and McMahon, 1983
Larson, J.W.; McMahon, T.B., Strong hydrogen bonding in gas-phase anions. An ion cyclotron resonance determination of fluoride binding energetics to bronsted acids from gas-phase fluoride exchange equilibria measurements, J. Am. Chem. Soc., 1983, 105, 2944. [all data]

Heni and Illenberger, 1985
Heni, M.; Illenberger, E., The stability of the bifluoride ion (HF2-) in the gas phase, J. Chem. Phys., 1985, 83, 6056. [all data]

Berkowitz, Ellison, et al., 1994
Berkowitz, J.; Ellison, G.B.; Gutman, D., Three methods to measure RH bond energies, J. Phys. Chem., 1994, 98, 2744. [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B., Hydrogen bonding in gas phase anions. An experimental investigation of the interaction between chloride ion and bronsted acids from ICR chloride exchange equilibria, J. Am. Chem. Soc., 1984, 106, 517. [all data]

Larson and McMahon, 1984, 2
Larson, J.W.; McMahon, T.B., Gas phase negative ion chemistry of alkylchloroformates, Can. J. Chem., 1984, 62, 675. [all data]

Larson and McMahon, 1984, 3
Larson, J.W.; McMahon, T.B., Gas phase bihalide and pseudohalide ions. An ICR determination of hydrogen bond energies in XHY- species (X,Y = F, Cl, Br, CN), Inorg. Chem., 1984, 23, 2029. [all data]

Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G., Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions, Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103 . [all data]

Good, Scott, et al., 1956
Good, W.D.; Scott, D.W.; Waddington, G., Combustion calorimetry of organic fluorine compounds by a rotating-bomb method, J. Phys. Chem., 1956, 60, 1080-1089. [all data]

Scott, Good, et al., 1955
Scott, D.W.; Good, W.D.; Waddington, G., Heat of formation of tetrafluoromethane from combustion calorimetry of polytetrafluoroethylene, J. Am. Chem. Soc., 1955, 77, 245-246. [all data]

Lacher, Kianpour, et al., 1956
Lacher, J.R.; Kianpour, A.; Park, J.D., Reaction heats of organic halogen compounds. VI. The catalytic hydrogenation of some alkyl fluorides, J. Phys. Chem., 1956, 60, 1454-1455. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Kolesov and Kozina, 1986
Kolesov, V.P.; Kozina, M.P., Thermochemistry of organic and organohalogen compounds, Russ. Chem. Rev., 1986, 55, 912. [all data]

Baroody and Carpenter, 1973
Baroody, E.E.; Carpenter, G.A., Enthalpies of formation of some fluorodinitroethyl derivatives and 2,2',4,4',6,6'-hexanitroazobenzene, J. Chem. Eng. Data, 1973, 18, 28-36. [all data]

Wartenberg, 1949
Wartenberg, H.V., Die bildungswarme einiger fluorid, Z. Anorg. Chem., 1949, 258, 354-360. [all data]

Coulson, 1993
Coulson, D.R., Kinetics of the fluorination/chlorination of 1-chloro-1,2,2,2-tetrafluoroethane, J. Catal., 1993, 142, 289-302. [all data]

Tiedemann, Anderson, et al., 1979
Tiedemann, P.W.; Anderson, S.L.; Ceyer, S.T.; Hirooka, T.; Ng, C.Y.; Mahan, B.H.; Lee, Y.T., Proton affinities of hydrogen halides determined by the molecular beam photoionization method, J. Chem. Phys., 1979, 71, 605. [all data]

Neugebauer and Margrave, 1956
Neugebauer, C.A.; Margrave, J.L., The heats of formation of tetrafluoroethylene, tetrafluoromethane and 1,1-difluoroethylene, J. Phys. Chem., 1956, 60, 1318-1321. [all data]

Jessup, McCoskey, et al., 1955
Jessup, R.S.; McCoskey, R.E.; Nelson, R.A., The heat of formation of tetrafluoromethane, J. Am. Chem. Soc., 1955, 77, 244-245. [all data]

Moore, 1971
Moore, L.O., Kinetics and thermodynamic data for the hydrogen fluoride addition to vinyl fluoride, Can. J. Chem., 1971, 49, 2471-2475. [all data]

di Londardo and Douglas, 1973
di Londardo, G.; Douglas, A.E., The electronic spectrum of HF. I. The B1Σ+-X1Σ+ 1 band system, Can. J. Phys., 1973, 51, 434. [all data]

di Lonardo and Douglas, 1972
di Lonardo, G.; Douglas, A.E., Electronic spectra of HF and F2, J. Chem. Phys., 1972, 56, 5185. [all data]

Johns and Barrow, 1959
Johns, J.W.C.; Barrow, R.F., The ultra-violet spectra of HF and DF, Proc. R. Soc. London A, 1959, 251, 504. [all data]

Safari, 1954
Safari, E., Contribution a l'etude spectrale de l'acide fluorhydrique, Ann. Phys. (Paris), 1954, 9, 203. [all data]

Mann, Thrush, et al., 1961
Mann, D.E.; Thrush, B.A.; Lide, D.R., Jr.; Ball, J.J.; Acquista, N., Spectroscopy of fluorine flames. I. Hydrogen-fluorine flame and the vibration-rotation emission spectrum of HF, J. Chem. Phys., 1961, 34, 420. [all data]

Herget, Deeds, et al., 1962
Herget, W.F.; Deeds, W.E.; Gailar, N.M.; Lovell, R.J.; Nielsen, A.H., Infrared spectrum of hydrogen fluoride: line positions and line shapes. Part II. Treatment of data and results, J. Opt. Soc. Am., 1962, 52, 1113. [all data]

Fishburne and Rao, 1966
Fishburne, E.S.; Rao, K.N., Vibration rotation bands of HF, J. Mol. Spectrosc., 1966, 19, 290. [all data]

Webb and Rao, 1968
Webb, D.U.; Rao, K.N., Vibration rotation bands of heated hydrogen halides, J. Mol. Spectrosc., 1968, 28, 121. [all data]

Rothschild, 1964
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Notes

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