Ozone

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Oxygen cation + Ozone = (Oxygen cation • Ozone)

By formula: O2+ + O3 = (O2+ • O3)

Quantity Value Units Method Reference Comment
Δr14.5kcal/molFADotan, Davidson, et al., 1978gas phase; switching reaction(O2+)O2, Entropy change calculated or estimated; Conway and Janik, 1970
Quantity Value Units Method Reference Comment
Δr20.5cal/mol*KN/ADotan, Davidson, et al., 1978gas phase; switching reaction(O2+)O2, Entropy change calculated or estimated; Conway and Janik, 1970
Quantity Value Units Method Reference Comment
Δr8.4kcal/molFADotan, Davidson, et al., 1978gas phase; switching reaction(O2+)O2, Entropy change calculated or estimated; Conway and Janik, 1970

Nitric oxide anion + Ozone = (Nitric oxide anion • Ozone)

By formula: NO- + O3 = (NO- • O3)

Quantity Value Units Method Reference Comment
Δr13.8kcal/molFAFehsenfeld, 1974gas phase; switching reaction(NO+)CO2, ΔrH<

Sodium ion (1+) + Ozone = (Sodium ion (1+) • Ozone)

By formula: Na+ + O3 = (Na+ • O3)

Quantity Value Units Method Reference Comment
Δr12.5kcal/molFARowe, Viggiano, et al., 1982gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dotan, Davidson, et al., 1978
Dotan, I.; Davidson, J.A.; Fehsenfeld, F.C.; Albritton, D.L., Reactions of O2+.O2 with CO2, O3 and CH4 and O2+.O3 with H2O and CH4 and their Role in Stratospheric Ion Chemistry, J. Geophys. Res., 1978, 83, C8, 4036, https://doi.org/10.1029/JC083iC08p04036 . [all data]

Conway and Janik, 1970
Conway, D.C.; Janik, G.S., Determination of the Bond Energies for the Series O2 - O2+ through O2 - O10+, J. Chem. Phys., 1970, 53, 5, 1859, https://doi.org/10.1063/1.1674262 . [all data]

Fehsenfeld, 1974
Fehsenfeld, F.C., Clustering of O3 to O2+ and NO+, J. Chem. Phys., 1974, 61, 4, 1588, https://doi.org/10.1063/1.1682129 . [all data]

Rowe, Viggiano, et al., 1982
Rowe, B.R.; Viggiano, A.A.; Fehsenfeld, F.C.; Fahey, D.W.; Ferguson, E.E., Reactions between Neutrals Clustered on Ions, J. Chem. Phys., 1982, 76, 1, 742, https://doi.org/10.1063/1.442684 . [all data]


Notes

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