Bismuthine, triphenyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas580. ± 19.kJ/molReviewMartinho Simões 
Δfgas601. ± 10.kJ/molReviewMartinho SimõesSelected data
Δfgas569. ± 12.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid469. ± 17.kJ/molReviewMartinho SimõesMS
Δfsolid489.6 ± 5.6kJ/molReviewMartinho SimõesSelected data; MS
Δfsolid457.8 ± 7.9kJ/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Δcsolid-10003.5 ± 5.0kJ/molCC-RBSteele, 1979MS
Δcsolid-9971.7 ± 7.5kJ/molCC-RBBirr, 1961MS
Δcsolid-9983. ± 17.kJ/molCC-SBBirr, 1960Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
330.2298.15Steele, 1979, 2DH
328.4298.5Smith and Andrews, 1931T = 102 to 323 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Tfus351.5KN/AForward, Bowden, et al., 1949Uncertainty assigned by TRC = 0.5 K; TRC
Tfus350.15KN/ASmith and Andrews, 1931, 2Uncertainty assigned by TRC = 1. K; with Hg thermometer; TRC
Tfus346.65KN/ASmith and Andrews, 1931, 2Uncertainty assigned by TRC = 1. K; with thermocouple; TRC
Quantity Value Units Method Reference Comment
Δsub110.9 ± 8.4kJ/molN/APilcher and Skinner, 1983See also Steele, 1979, 2.; AC
Δsub110.9 ± 8.4kJ/molCC-SBSkinner H.A., 1964MS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Steele, 1979
Steele, W.V., J. Chem. Thermodyn., 1979, 11, 187. [all data]

Birr, 1961
Birr, K.-H., Z. Anorg. Allg. Chem., 1961, 311, 92. [all data]

Birr, 1960
Birr, K.-H., Z. Anorg. Allg. Chem., 1960, 306, 21. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Steele, 1979, 2
Steele, W.V., The standard enthalpies of formation of the triphenyl compounds of the group V elements. 2. Triphenylbismuth and the Ph-Bi mean bond-dissociation energy, J. Chem. Thermodynam., 1979, 11, 187-192. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal energy studies. II. Phenyl derivatives of metals, J. Am. Chem. Soc., 1931, 53, 3661-3667. [all data]

Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J., Physical Properties of Triphenyl Compounds of Group VB Elements, J. Chem. Soc., 1949, 1949, 121-6. [all data]

Smith and Andrews, 1931, 2
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Skinner H.A., 1964
Skinner H.A., In Advances in Organometallic Chemistry; Vol. 2, Academic Press, New York, 1964. [all data]


Notes

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