Toluene
- Formula: C7H8
- Molecular weight: 92.1384
- IUPAC Standard InChIKey: YXFVVABEGXRONW-UHFFFAOYSA-N
- CAS Registry Number: 108-88-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Benzene, methyl; Methacide; Methylbenzene; Methylbenzol; Phenylmethane; Antisal 1a; Toluol; Methane, phenyl-; NCI-C07272; Tolueen; Toluen; Toluolo; Rcra waste number U220; Tolu-sol; UN 1294; Dracyl; Monomethyl benzene; CP 25; NSC 406333; methylbenzene (toluene)
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 50.1 ± 1.1 | kJ/mol | Review | Roux, Temprado, et al., 2008 | There are sufficient high-quality literature values to make a good evaluation with a high degree of confidence. In general, the evaluated uncertainty limits are on the order of (0.5 to 2.5) kJ/mol.; DRB |
ΔfH°gas | 50.00 ± 0.63 | kJ/mol | Ccb | Prosen, Gilmont, et al., 1945 | Hf by Prosen, Johnson, et al., 1946; ALS |
ΔfH°gas | 48.0 | kJ/mol | N/A | Schmidlin, 1906 | Value computed using ΔfHliquid° value of 10.0 kj/mol from Schmidlin, 1906 and ΔvapH° value of 38.0 kj/mol from Prosen, Gilmont, et al., 1945.; DRB |
Constant pressure heat capacity of gas
Cp,gas (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
69.85 | 200. | Draeger, 1985 | Recommended values agree better with experimental heat capacities than results of calculation [ Chao J., 1984]. All other statistically calculated values [ Pitzer K.S., 1943, Taylor W.J., 1946, Scott D.W., 1962] are in close agreement with selected ones, except for high temperatures.; GT |
94.68 | 273.15 | ||
103.7 ± 0.4 | 298.15 | ||
104.4 | 300. | ||
139.9 | 400. | ||
170.8 | 500. | ||
196.2 | 600. | ||
217.0 | 700. | ||
234.3 | 800. | ||
248.9 | 900. | ||
261.2 | 1000. | ||
271.8 | 1100. | ||
280.8 | 1200. | ||
288.5 | 1300. | ||
295.2 | 1400. | ||
301.0 | 1500. |
Constant pressure heat capacity of gas
Cp,gas (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
130.08 ± 0.26 | 371.20 | Scott D.W., 1962 | Please also see Montgomery J.B., 1942, Pitzer K.S., 1943, Taylor W.J., 1946.; GT |
140.2 | 390. | ||
137.2 ± 1.3 | 393. | ||
138.87 ± 0.27 | 396.20 | ||
146.4 | 410. | ||
149.16 ± 0.30 | 427.20 | ||
149.4 ± 1.7 | 428. | ||
160.33 ± 0.32 | 462.20 | ||
159.0 ± 1.7 | 463. | ||
171.46 ± 0.34 | 500.20 |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | 12. ± 1.1 | kJ/mol | Review | Roux, Temprado, et al., 2008 | There are sufficient high-quality literature values to make a good evaluation with a high degree of confidence. In general, the evaluated uncertainty limits are on the order of (0.5 to 2.5) kJ/mol.; DRB |
ΔfH°liquid | 12.0 ± 0.63 | kJ/mol | Ccb | Prosen, Gilmont, et al., 1945 | Hf by Prosen, Johnson, et al., 1946; ALS |
ΔfH°liquid | Ccb | Schmidlin, 1906 | uncertain value: 10. kJ/mol; Undetermine error; ALS | ||
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -3920. ± 20. | kJ/mol | AVG | N/A | Average of 5 out of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 220.96 | J/mol*K | N/A | Scott, Guthrie, et al., 1962 | DH |
S°liquid | 219.2 | J/mol*K | N/A | Kelley, 1929 | DH |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
157.09 | 298.15 | Grolier, Roux-Desgranges, et al., 1993 | DH |
155.96 | 298.15 | Shiohama, Ogawa, et al., 1988 | DH |
159.9 | 303.15 | Reddy, 1986 | T = 303.15, 313.15 K.; DH |
157.08 | 298.15 | Roux-Dexgranges, Grolier, et al., 1986 | DH |
158.70 | 298.15 | Tardajos, Aicart, et al., 1986 | DH |
158.7 | 298.15 | Stephens and Olson, 1984 | T = 266 to 318 K. Cp given as 0.4117 cal g-1 C-1.; DH |
157.0 | 298.15 | Grolier, Inglese, et al., 1982 | DH |
157.15 | 298.15 | Wilhelm, Faradjzadeh, et al., 1982 | DH |
156.0 | 293.15 | Atalla, El-Sharkawy, et al., 1981 | DH |
157.0 | 294.71 | Andolenko and Grigor'ev, 1979 | T = 293 to 373 K. Unsoothed experimental datum given as 1.704 KJ/kg*K.; DH |
157.057 | 298.15 | Fortier and Benson, 1979 | DH |
157.081 | 298.15 | Fortier and Benson, 1977 | DH |
156.94 | 298.15 | Wilhelm, Grolier, et al., 1977 | DH |
157.026 | 298.15 | Fortier and Benson, 1976 | DH |
156.99 | 298.15 | Holzhauer and Ziegler, 1975 | T = 165 to 312 K. Cp = 187.43814 - 0.73026493T + 0.0029613602T2 - 2.8661704x10-6T3 J/mol*K.; DH |
158.4 | 298.15 | Pedersen, Kay, et al., 1975 | T = 298 to 348 K. Cp(liq) = 154.73 + 0.0981(T/K-273.15) + 0.001949(T/K-273.15)2 J/mol*K (298 to 348 K).; DH |
156.8 | 298.15 | Rajagopal and Subrahmanyam, 1974 | T = 298.15 to 323.15 K.; DH |
156.5 | 298. | Deshpande and Bhatagadde, 1971 | T = 298 to 318 K.; DH |
158.6 | 293. | Rastorguev and Ganiev, 1967 | T = 293 to 373 K.; DH |
157.33 | 298.711 | Hwa and Ziegler, 1966 | T = 181 to 304 K. Unsmoothed experimental datum.; DH |
157.23 | 298.15 | Scott, Guthrie, et al., 1962 | T = 10 to 360 K.; DH |
166.9 | 324. | Swietoslawski and Zielenkiewicz, 1958 | Mean value 21 to 81 C.; DH |
140. | 295. | Tschamler, 1948 | DH |
158.6 | 298. | Kurbatov, 1947 | T = -76 to 60 C, mean Cp, four temperatures.; DH |
156.9 | 298.1 | Zhdanov, 1941 | T = 5 to 47 C.; DH |
157.07 | 298.2 | Burlew, 1940 | T = 281 to 383 K.; DH |
156.5 | 298. | Vold, 1937 | DH |
142.7 | 227.8 | Aoyama and Kanda, 1935 | T = 78 to 228 K. Value is unsmoothed experimental datum.; DH |
156.5 | 298.1 | Richards and Wallace, 1932 | T = 293 to 333 K.; DH |
161.9 | 298.15 | Smith and Andrews, 1931 | T = 102 to 299 K. Value is unsmoothed experimental datum.; DH |
153.09 | 28.444 | Kelley, 1929 | T = 14 to 284 K. Value is unsmoothed experimental datum.; DH |
151.0 | 293.2 | Williams and Daniels, 1925 | T = 20 to 60 C.; DH |
153.6 | 303. | Willams and Daniels, 1924 | T = 303 to 343 K. Equation only.; DH |
158.2 | 298. | von Reis, 1881 | T = 292 to 390 K.; DH |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 383.8 ± 0.2 | K | AVG | N/A | Average of 110 out of 132 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 178.1 ± 0.6 | K | AVG | N/A | Average of 24 out of 25 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 178.15 | K | N/A | Scott, Guthrie, et al., 1962, 2 | Uncertainty assigned by TRC = 0.05 K; TRC |
Ttriple | 178.00 | K | N/A | Ziegler and Andrews, 1942 | Uncertainty assigned by TRC = 0.2 K; TRC |
Ttriple | 177.9 | K | N/A | Stull, 1937 | Uncertainty assigned by TRC = 0.2 K; TRC |
Ttriple | 177.95 | K | N/A | Kelley, 1929, 2 | Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 593. ± 2. | K | AVG | N/A | Average of 20 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 41. ± 1. | bar | AVG | N/A | Average of 11 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.316 | l/mol | N/A | Tsonopoulos and Ambrose, 1995 | |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 3.17 ± 0.010 | mol/l | N/A | Tsonopoulos and Ambrose, 1995 | |
ρc | 3.16 | mol/l | N/A | Chirico and Steele, 1994 | Uncertainty assigned by TRC = 0.04 mol/l; TRC |
ρc | 3.15 | mol/l | N/A | Goodwin, 1989 | Uncertainty assigned by TRC = 0.05 mol/l; TRC |
ρc | 3.16 | mol/l | N/A | Steele, Chirico, et al., 1988 | Uncertainty assigned by TRC = 0.05 mol/l; TRC |
ρc | 3.162 | mol/l | N/A | Simon, 1957 | Uncertainty assigned by TRC = 0.05 mol/l; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 37. ± 3. | kJ/mol | AVG | N/A | Average of 9 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 43.1 | kJ/mol | B | Lenchitz and Velicky, 1970 | AC |
Reduced pressure boiling point
Tboil (K) | Pressure (bar) | Reference | Comment |
---|---|---|---|
287.7 | 0.020 | Weast and Grasselli, 1989 | BS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
33.18 | 383.8 | N/A | Majer and Svoboda, 1985 | |
35.7 | 346. | N/A | Lee and Holder, 1993 | Based on data from 331. to 496. K.; AC |
40.6 | 264. | A | Stephenson and Malanowski, 1987 | Based on data from 210. to 279. K.; AC |
34.4 | 398. | A | Stephenson and Malanowski, 1987 | Based on data from 383. to 445. K.; AC |
33.2 | 455. | A | Stephenson and Malanowski, 1987 | Based on data from 440. to 531. K.; AC |
33.3 | 545. | A | Stephenson and Malanowski, 1987 | Based on data from 530. to 592. K.; AC |
38.9 | 284. | A | Stephenson and Malanowski, 1987 | Based on data from 273. to 295. K.; AC |
37.0 | 323. | N/A | Stephenson and Malanowski, 1987 | Based on data from 308. to 386. K. See also Forziati, Norris, et al., 1949.; AC |
33.5 ± 0.1 | 380. | C | Natarajan and Viswanath, 1985 | AC |
32.1 ± 0.1 | 403. | C | Natarajan and Viswanath, 1985 | AC |
29.4 ± 0.1 | 441. | C | Natarajan and Viswanath, 1985 | AC |
27.1 ± 0.1 | 470. | C | Natarajan and Viswanath, 1985 | AC |
24.0 ± 0.1 | 505. | C | Natarajan and Viswanath, 1985 | AC |
35.4 | 333. | N/A | Eubank, Cediel, et al., 1984 | AC |
33.4 | 373. | N/A | Eubank, Cediel, et al., 1984 | AC |
31.4 | 413. | N/A | Eubank, Cediel, et al., 1984 | AC |
28.4 | 453. | N/A | Eubank, Cediel, et al., 1984 | AC |
24.0 | 493. | N/A | Eubank, Cediel, et al., 1984 | AC |
35.4 | 360. | N/A | Rivenq, 1975 | Based on data from 343. to 383. K.; AC |
37.3 | 318. | N/A | Gaw and Swinton, 1968 | Based on data from 303. to 343. K.; AC |
36.9 | 303. | N/A | Van Ness, Soczek, et al., 1967 | Based on data from 288. to 348. K.; AC |
35.65 | 341.27 | V | Scott, Gutherie, et al., 1962 | low T and vapor flow calorimetry; ALS |
37.8 | 278. | N/A | Milazzo, 1956 | Based on data from 210. to 293. K.; AC |
37.8 | 301. | N/A | Thomson, 1946 | Based on data from 286. to 362. K.; AC |
37.0 | 323. | MM | Willingham, Taylor, et al., 1945 | Based on data from 308. to 384. K.; AC |
38.8 | 288. | N/A | Pitzer and Scott, 1943 | Based on data from 273. to 323. K.; AC |
Enthalpy of vaporization
ΔvapH =
A exp(-βTr) (1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kJ/mol)
Tr = reduced temperature (T / Tc)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A (kJ/mol) | β | Tc (K) | Reference | Comment |
---|---|---|---|---|---|
298. to 410. | 53.09 | 0.2774 | 591.7 | Majer and Svoboda, 1985 |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
273.13 to 297.89 | 4.23679 | 1426.448 | -45.957 | Besley and Bottomley, 1974 | Coefficents calculated by NIST from author's data. |
303. to 343. | 4.08245 | 1346.382 | -53.508 | Gaw and Swinton, 1968, 2 | Coefficents calculated by NIST from author's data. |
420.00 to 580.00 | 4.54436 | 1738.123 | 0.394 | Ambrose, Broderick, et al., 1967 | Coefficents calculated by NIST from author's data. |
308.52 to 384.66 | 4.07827 | 1343.943 | -53.773 | Williamham, Taylor, et al., 1945 | |
273. to 323. | 4.14157 | 1377.578 | -50.507 | Pitzer and Scott, 1943 | Coefficents calculated by NIST from author's data. |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
6.636 | 178.15 | Scott, Guthrie, et al., 1962 | DH |
6.619 | 177.95 | Kelley, 1929 | DH |
6.548 | 178.0 | Ziegler and Andrews, 1942, 2 | DH |
6.61 | 178. | Domalski and Hearing, 1996 | See also Southard and Andrews, 1930.; AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
37.25 | 178.15 | Scott, Guthrie, et al., 1962 | DH |
37.20 | 177.95 | Kelley, 1929 | DH |
36.79 | 178.0 | Ziegler and Andrews, 1942, 2 | DH |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Roux, Temprado, et al., 2008
Roux, M.V.; Temprado, M.; Chickos, J.S.; Nagano, Y.,
Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons,
J. Phys. Chem. Ref. Data, 2008, 37, 4, 1855-1996. [all data]
Prosen, Gilmont, et al., 1945
Prosen, E.J.; Gilmont, R.; Rossini, F.D.,
Heats of combustion of benzene, toluene, ethyl-benzene, o-xylene, m-xylene, p-xylene, n-propylbenzene, and styrene,
J. Res. NBS, 1945, 34, 65-70. [all data]
Prosen, Johnson, et al., 1946
Prosen, E.J.; Johnson, W.H.; Rossini, F.D.,
Heats of combustion and formation at 25°C of the alkylbenzenes through C10H14, and of the higher normal monoalkylbenzenes,
J. Res. NBS, 1946, 36, 455-461. [all data]
Schmidlin, 1906
Schmidlin, M.J.,
Recherches chimiques et thermochimiques sur la constitution des rosanilines,
Ann. Chim. Phys., 1906, 1, 195-256. [all data]
Draeger, 1985
Draeger, J.A.,
The methylbenzenes II. Fundamental vibrational shifts, statistical thermodynamic functions, and properties of formation,
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Chao J., 1984
Chao J.,
Chemical thermodynamic properties of toluene, o-, m- and p-xylenes,
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Pitzer K.S., 1943
Pitzer K.S.,
The thermodynamics and molecular structure of benzene and its methyl derivatives,
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Taylor W.J., 1946
Taylor W.J.,
Heats, equilibrium constants, and free energies of formation of the alkylbenzenes,
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Scott D.W., 1962
Scott D.W.,
Toluene: thermodynamic properties, molecular vibrations, and internal rotation,
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Montgomery J.B., 1942
Montgomery J.B.,
The heat capacity of organic vapors. IV. Benzene, fluorobenzene, toluene, cyclohexane, methylcyclohexane and cyclohexene,
J. Am. Chem. Soc., 1942, 64, 2375-2377. [all data]
Scott, Guthrie, et al., 1962
Scott, D.W.; Guthrie, G.B.; Messerly, J.F.; Todd, S.S.; Berg, W.T.; Hossenlopp, I.A.; McCullough, J.P.,
Toluene: thermodynamic properties, molecular vibrations, and internal rotation,
J. Phys. Chem., 1962, 66, 911-914. [all data]
Kelley, 1929
Kelley, K.K.,
The heat capacity of toluene from 14K to 298K. The entropy and the free energy of formation,
J. Am. Chem. Soc., 1929, 51, 2738-2741. [all data]
Grolier, Roux-Desgranges, et al., 1993
Grolier, J.-P.E.; Roux-Desgranges, G.; Berkane, M.; Jimenez, E.; Wilhelm, E.,
Heat capacities and densities of mixtures of very polar substances 2. Mixtures containing N,N-dimethylformamide,
J. Chem. Thermodynam., 1993, 25(1), 41-50. [all data]
Shiohama, Ogawa, et al., 1988
Shiohama, Y.; Ogawa, H.; Murakami, S.; Fujihara, I.,
Excess molar isobaric heat capacities and isentropic compressibilities of (cis- or trans-decalin + benzene or toluene or iso-octane or n-heptane) at 298.15 K,
J. Chem. Thermodynam., 1988, 20, 1183-1189. [all data]
Reddy, 1986
Reddy, K.S.,
Isentropic compressibilities of binary liquid mixtures at 303.15 and 313.15 K,
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Roux-Dexgranges, Grolier, et al., 1986
Roux-Dexgranges, G.; Grolier, J.-P.E.; Villamanan, M.A.; Casanova, C.,
Role of alcohol in microemulsions. III. Volumes and heat capacities in the continuious phase water-n-butanol-toluene of reverse micelles,
Fluid Phase Equilibria, 1986, 25, 209-230. [all data]
Tardajos, Aicart, et al., 1986
Tardajos, G.; Aicart, E.; Costas, M.; Patterson, D.,
Liquid structure and second-order mixing functions for benzene, toluene, and p-xylene with n-alkanes, J. Chem. Soc.,
Faraday Trans., 1986, 1 82, 2977-2987. [all data]
Stephens and Olson, 1984
Stephens, M.; Olson, J.D.,
Measurement of excess heat capacities by differential scanning calorimetry,
Thermochim. Acta, 1984, 76, 79-85. [all data]
Grolier, Inglese, et al., 1982
Grolier, J.-P.E.; Inglese, A.; Wilhelm, E.,
Excess volumes and excess heat capacities of tetrachloroethene + cyclohexane, + methylcyclohexane, + benzene, and + toluene at 298.15 K,
J. Chem. Thermodynam., 1982, 14, 523-529. [all data]
Wilhelm, Faradjzadeh, et al., 1982
Wilhelm, E.; Faradjzadeh, A.; Grolier, J.-P.E.,
Excess volumes and excess heat capacities of 2,3-dimethylbutane + butane and + toluene,
J. Chem. Thermodynam., 1982, 14, 1199-1200. [all data]
Atalla, El-Sharkawy, et al., 1981
Atalla, S.R.; El-Sharkawy, A.A.; Gasser, F.A.,
Measurement of thermal properties of liquids with an AC heated-wire technique,
Inter. J. Thermophys., 1981, 2(2), 155-162. [all data]
Andolenko and Grigor'ev, 1979
Andolenko, R.A.; Grigor'ev, B.A.,
Investigation of isobaric heat capacity of aromatic hydrocarbons at atmospheric pressure, Iaz. Vyssh. Ucheb. Zaved.,
Neft i Gaz (11), 1979, 78, 90. [all data]
Fortier and Benson, 1979
Fortier, J.-L.; Benson, G.C.,
Heat capacities of some binary aromatic hydrocarbon mixtures containing benzene or toluene,
J. Chem. Eng. Data, 1979, 24(1), 34-37. [all data]
Fortier and Benson, 1977
Fortier, J.-L.; Benson, G.C.,
Excess heat capacities of binary mixtures of tetrachloromethane witlh some aromatic liquids at 298.15 K,
J. Chem. Thermodynam., 1977, 9, 1181-1188. [all data]
Wilhelm, Grolier, et al., 1977
Wilhelm, E.; Grolier, J.-P.E.; Karbalai Ghassemi, M.H.,
Molar heat capacities of binary liquid mixtures: 1,2-dichloroethane + benzene, + toluene, and + p-xylene,
Ber. Bunsenges. Phys. Chem., 1977, 81, 925-930. [all data]
Fortier and Benson, 1976
Fortier, J.-L.; Benson, G.C.,
Excess heat capacities of binary liquid mixtures determined with a Picker flow calorimeter,
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Holzhauer and Ziegler, 1975
Holzhauer, J.K.; Ziegler, W.T.,
Temperature dependence of excess thermodynamic properties of n-heptane-toluene, methylcyclohexane-toluene, and n-heptane-methylcyclohexane systems,
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Pedersen, Kay, et al., 1975
Pedersen, M.J.; Kay, W.B.; Hershey, H.C.,
Excess enthalpies, heat capacities, and excess heat capacities as a function of temperature in liquid mixtures of ethanol + toluene, ethanol + hexamethyldisiloxane, and hexamethyldisiloxane + toluene,
J. Chem. Thermodynam., 1975, 7, 1107-1118. [all data]
Rajagopal and Subrahmanyam, 1974
Rajagopal, E.; Subrahmanyam, S.V.,
Excess function of VE,(dVE/dp)T, and CpE of isooctane + benzene and + toluene,
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Deshpande and Bhatagadde, 1971
Deshpande, D.D.; Bhatagadde, L.G.,
Heat capacities at constant volume, free volumes, and rotational freedom in some liquids,
Aust. J. Chem., 1971, 24, 1817-1822. [all data]
Rastorguev and Ganiev, 1967
Rastorguev, Yu.L.; Ganiev, Yu.A.,
Study of the heat capacity of selected solvents,
Izv. Vyssh. Uchebn. Zaved. Neft Gaz. 10, 1967, No.1, 79-82. [all data]
Hwa and Ziegler, 1966
Hwa, S.C.P.; Ziegler, W.T.,
Temperature dependence of excess thermodynamic properties of ethanol-methylcyclohexane and ethanol-toluene systems,
J. Phys. Chem., 1966, 70(8), 2572-2593. [all data]
Swietoslawski and Zielenkiewicz, 1958
Swietoslawski, W.; Zielenkiewicz, A.,
Mean specific heats of binary positive azeotropes,
Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1958, 6, 367-369. [all data]
Tschamler, 1948
Tschamler, H.,
Uber binare flussige Mischungen I. Mischungswarment, Volumseffekte und Zustandsdiagramme von chlorex mit benzol und n-alkylbenzolen,
Monatsh. Chem., 1948, 79, 162-177. [all data]
Kurbatov, 1947
Kurbatov, V.Ya.,
Specific heat of liquids. I. Specific heat of benzenoid hydrocarbons,
Zhur. Obshch. Khim., 1947, 17, 1999-2003. [all data]
Zhdanov, 1941
Zhdanov, A.K.,
Specific heats of some liquids and azeotropic mixtures,
Zhur. Obshch. Khim., 1941, 11, 471-482. [all data]
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Notes
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- Symbols used in this document:
Cp,gas Constant pressure heat capacity of gas Cp,liquid Constant pressure heat capacity of liquid Pc Critical pressure S°liquid Entropy of liquid at standard conditions Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature Vc Critical volume ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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