L-Fucitol, 5TMS derivative
- Formula: C21H54O5Si5
- Molecular weight: 527.0780
- IUPAC Standard InChI: InChI=1S/C21H54O5Si5/c1-18(23-28(5,6)7)20(25-30(11,12)13)21(26-31(14,15)16)19(24-29(8,9)10)17-22-27(2,3)4/h18-21H,17H2,1-16H3
- IUPAC Standard InChIKey: YCLDNNFGQOEZPF-UHFFFAOYSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: L-Fucitol, pentakis(trimethylsilyl) ether; fucitol, TMS; L-Fucitol TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | OV-101 | 200. | 1837.6 | Adam, 1981 | Column length: 50. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | VF-5MS | 1769.8 | Tretyakov, 2011 | 30. m/0.25 mm/0.25 μm, He; Tstart: 60. C; Tend: 270. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 1832. | Yang and Cashman, 1992 | 30. m/0.32 mm/1.0 μm, He; Program: 3 min at 100 0C; 100 - 200 0C at 8 deg/min; 1 min at 200 0C; 200 - 280 0C at 5 deg/min; 30 min at 280 0C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Adam, 1981
Adam, S.,
Separation of mono- and di-saccharide derivatives by high-resolution gas chromatography,
Z. Lebensm. Unters. Forsch., 1981, 173, 2, 109-112, https://doi.org/10.1007/BF01042273
. [all data]
Tretyakov, 2011
Tretyakov, K.V.,
Retention Data (March 2011). NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2011. [all data]
Yang and Cashman, 1992
Yang, Z.C.; Cashman, J.R.,
Structure-retention index relationships for derivatized monosaccharides on non-polar gas chromatography columns,
J. Chromatogr., 1992, 596, 1, 79-84, https://doi.org/10.1016/0021-9673(92)80205-9
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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