2'-Deoxyadenosine, 3TMS derivative
- Formula: C19H37N5O3Si3
- Molecular weight: 467.7853
- IUPAC Standard InChI: InChI=1S/C19H37N5O3Si3/c1-28(2,3)23-18-17-19(21-12-20-18)24(13-22-17)16-10-14(27-30(7,8)9)15(26-16)11-25-29(4,5)6/h12-16H,10-11H2,1-9H3,(H,20,21,23)
- IUPAC Standard InChIKey: PSEZCYIEJIOFHY-UHFFFAOYSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: 2'-Deoxyadenosine, N-trimethylsilyl-, bis(trimethylsilyl) ether; deoxyadenosine, TMS; Adenine, deoxyriboside, TMS; 2'-Deoxyadenosine, 3',5',N6-tris(O-TMSi); N6-TMS-2'-Deoxyadenosine, 3',5'-bis-O-TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | OV-1 | 230. | 2607. | Quilliam, Ogilvie, et al., 1980 | N2, Gas-Chrom Q |
| Packed | OV-1 | 230. | 2607. | Quilliam and Westmore, 1978 | Gas Chrom Q; Column length: 1. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Packed | OV-1 | 2618. | Butts, 1972 | He, Chromosorb W HP (80-100 mesh), 10. K/min; Column length: 2. m; Tstart: 100. C; Tend: 325. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | VF-5MS | 2619. | Tretyakov, 2011 | 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C |
| Packed | SE-30 | 2591. | Butts, 1970 | He, Chromosorb W; Column length: 2. m; Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quilliam, Ogilvie, et al., 1980
Quilliam, M.A.; Ogilvie, K.K.; Sadana, K.L.; Westmore, J.B.,
Gas chromatographic retention data for silyl and acyl derivatives of nucleosides,
J. Chromatogr., 1980, 196, 3, 367-378, https://doi.org/10.1016/S0021-9673(00)84739-1
. [all data]
Quilliam and Westmore, 1978
Quilliam, M.A.; Westmore, J.B.,
Sterically crowded trialkylsilyl derivatives for chromatography and mass spectrometry of biologically-important compounds,
Anal. Chem., 1978, 50, 1, 59-68, https://doi.org/10.1021/ac50023a020
. [all data]
Butts, 1972
Butts, W.C.,
Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds,
Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3
. [all data]
Tretyakov, 2011
Tretyakov, K.V.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2011. [all data]
Butts, 1970
Butts, W.C.,
Gas chromatographic separation of trimethylsilyl (TMS)-nucleosides: TMS-methoxime derivatives of cytidine and deoxycytidine,
J. Chromatogr. Sci., 1970, 8, 8, 474-476, https://doi.org/10.1093/chromsci/8.8.474
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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