Methyl 3-indolylacetate, TMS derivative
- Formula: C14H19NO2Si
- Molecular weight: 261.3917
- IUPAC Standard InChI: InChI=1S/C14H19NO2Si/c1-17-14(16)9-11-10-15(18(2,3)4)13-8-6-5-7-12(11)13/h5-8,10H,9H2,1-4H3
- IUPAC Standard InChIKey: OVBJETHPLUQCEW-UHFFFAOYSA-N
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: N-Trimethylsilylindoleacetic acid, methyl ester; IAA, MeTMS; Indole-3-acetic acid, (Me,TMS)
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Mass spectrum (electron ionization)
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | G.C. MARTIN, DEP. POMOL., CALIF. UNIV., DAVIS. CALIF., USA |
| NIST MS number | 101027 |
Gas Chromatography
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 1860. | Santes, Hedden, et al., 1995 | 25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | OV-1 | 1869. | Santes, Hedden, et al., 1995 | 25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Polydimethyl siloxane | 1853. | Fujioka, Yamane, et al., 1988 | 200. C @ 2. min, 5. K/min; Tend: 320. C |
References
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Santes, Hedden, et al., 1995
Santes, C.M.; Hedden, P.; Gaskin, P.; Garcia-Martinez, J.L.,
Gibberellins and related compounds in young fruits of pea and their relationship to fruit-set,
Phytochemistry, 1995, 40, 5, 1347-1355, https://doi.org/10.1016/0031-9422(95)00489-T
. [all data]
Fujioka, Yamane, et al., 1988
Fujioka, S.; Yamane, H.; Spray, C.R.; Gaskin, P.; Macmillan, J.; Phinney, B.O.; Takahashi, N.,
Qualitative and quantitative analyses of gibberellins in vegetative shoots of normal, dwarf-1, dwarf-2, dwarf-3, and dwarf-5 seedlings of Zea mays L.,
Plant Physiol., 1988, 88, 4, 1367-1372, https://doi.org/10.1104/pp.88.4.1367
. [all data]
Notes
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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