GA86, MeTMSi
- Formula: C32H58O8Si4
- Molecular weight: 683.1401
- IUPAC Standard InChI: InChI=1S/C32H58O8Si4/c1-20-26(39-43(10,11)12)30-19-32(20,40-44(13,14)15)23(38-42(7,8)9)18-21(30)31-17-16-22(37-41(4,5)6)29(2,28(34)36-31)25(31)24(30)27(33)35-3/h21-26H,1,16-19H2,2-15H3/t21?,22-,23-,24+,25?,26+,29+,30+,31+,32-/m1/s1
- IUPAC Standard InChIKey: QYEAQQUMULDDTF-VWTZYVOOSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Permanent link for this species. Use this link for bookmarking this species for future reference.
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2974. | Nakayama, Yokota, et al., 1996 | He; Column length: 15. m; Column diameter: 0.258 mm; Program: 130C (2min) => 32C/min => 220C (4min) => 8C/min => 270C (5min) |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | XTI-5 | 2996. | Blake, Browning G., et al., 2000 | 30. m/0.25 mm/0.25 μm, He; Program: 60C(1min) => 20C/min => 220C => 4C/min => 300C |
| Capillary | CP Sil 5 CB | 2984. | Blake and Browning, 1994 | He; Column length: 25. m; Column diameter: 0.25 mm; Program: 50C(1min) => 15C/min => 220C => 2C/min => 300C |
| Capillary | DB-1 | 2975. | Pearce, Koshioka, et al., 1994 | 15. m/0.22 mm/0.25 μm; Program: 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nakayama, Yokota, et al., 1996
Nakayama, M.; Yokota, T.; Sohma, R.; Mander, L.N.; Twitchin, B.; Komatsu, H.; Matsui, H.; Bukovac, M.J.,
Gibberellins in immature seed of Prunus cerasus: structure determination and synthesis of gibberellin, GA95 (1,2-didehydro-GA20),
Phytochemistry, 1996, 42, 4, 913-920, https://doi.org/10.1016/0031-9422(96)00035-0
. [all data]
Blake, Browning G., et al., 2000
Blake, P.S.; Browning G.; Benjamin, L.J.; Mander, L.N.,
Gibberellins in seedlings and flowering trees of Prunus avium L.,
Phytochemistry, 2000, 53, 4, 519-528, https://doi.org/10.1016/S0031-9422(99)00597-X
. [all data]
Blake and Browning, 1994
Blake, P.S.; Browning, G.,
Gibberellins in developing fruits of Prunus avium,
Phytochemistry, 1994, 35, 6, 1383-1386, https://doi.org/10.1016/S0031-9422(00)86860-0
. [all data]
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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