GA85, MeTMSi
- Formula: C29H50O7Si3
- Molecular weight: 594.9596
- IUPAC Standard InChI: InChI=1S/C29H50O7Si3/c1-18-16-27-17-29(18,36-39(10,11)12)21(35-38(7,8)9)15-19(27)28-14-13-20(34-37(4,5)6)26(2,25(31)33-28)23(28)22(27)24(30)32-3/h19-23H,1,13-17H2,2-12H3/t19?,20-,21-,22+,23?,26+,27-,28+,29-/m1/s1
- IUPAC Standard InChIKey: JIRSVBWLAGYHGP-MFBNQEKNSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: GA85, methyl ester TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | XTI-5 | 2858. | Blake, Browning G., et al., 2000 | 30. m/0.25 mm/0.25 μm, He; Program: 60C(1min) => 20C/min => 220C => 4C/min => 300C |
| Capillary | CP Sil 5 CB | 2831. | Blake and Browning, 1994 | He; Column length: 25. m; Column diameter: 0.25 mm; Program: 50C(1min) => 15C/min => 220C => 2C/min => 300C |
| Capillary | DB-1 | 2817. | Pearce, Koshioka, et al., 1994 | 15. m/0.22 mm/0.25 μm; Program: 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | BP-1 | 2831. | Lange, Hedden, et al., 1993 | 25. m/0.25 mm/0.33 μm, He; Program: 60C(1min) => 20C/min => 240C => 4C/min => 300C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Blake, Browning G., et al., 2000
Blake, P.S.; Browning G.; Benjamin, L.J.; Mander, L.N.,
Gibberellins in seedlings and flowering trees of Prunus avium L.,
Phytochemistry, 2000, 53, 4, 519-528, https://doi.org/10.1016/S0031-9422(99)00597-X
. [all data]
Blake and Browning, 1994
Blake, P.S.; Browning, G.,
Gibberellins in developing fruits of Prunus avium,
Phytochemistry, 1994, 35, 6, 1383-1386, https://doi.org/10.1016/S0031-9422(00)86860-0
. [all data]
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Lange, Hedden, et al., 1993
Lange, T.; Hedden, P.; Graebe, J.E.,
Gibberellin biosynthesis in cell-free extracts from developing Cucurbita maxima embryos and the identification of new endogenous gibberellins,
Planta, 1993, 189, 3, 350-358, https://doi.org/10.1007/BF00194431
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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