GA81, Me-TMS

Formula: C₂₆H₄₂O₆Si₂
Molecular weight: 506.7791
IUPAC Standard InChI: InChI=1S/C26H42O6Si2/c1-16-12-24-15-25(16,32-34(7,8)9)11-10-18(24)26-14-17(31-33(4,5)6)13-23(2,22(28)30-26)20(26)19(24)21(27)29-3/h17-20H,1,10-15H2,2-9H3/t17-,18?,19+,20?,23+,24-,25-,26+/m1/s1
IUPAC Standard InChIKey: AINOJINHOWCGRJ-LCQZQDNUSA-N
Chemical structure:
This structure is also available as a 2d Mol file
Stereoisomers:
Other names: GA81, MeTMSi
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Gas Chromatography

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, custom temperature program

Column type	Active phase	I	Reference	Comment
Capillary	DB-1	2666.	Ridoutt, Pharis, et al., 1995	15. m/0.25 mm/0.25 μm, He; Program: 60C(1min) => 20C/min => 200C => 4C/min => 260C
Capillary	OV-1	2673.	Santes, Hedden, et al., 1995	25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C
Capillary	OV-1	2682.	Santes, Hedden, et al., 1995	25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C
Capillary	DB-1	2681.	Pearce, Koshioka, et al., 1994	15. m/0.22 mm/0.25 μm; Program: 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	HP-1	2694.	Fos, Nuez, et al., 2000	25. m/0.20 mm/0.33 μm, Helium; Program: 60 0C (1 min) 20 0C/min -> 240 0C 4 0C/min -> 300 0C
Capillary	HP-1	2698.	Fos, Nuez, et al., 2000	25. m/0.20 mm/0.33 μm, Helium; Program: 60 0C (1 min) 20 0C/min -> 240 0C 4 0C/min -> 300 0C
Capillary	Methyl Silicone	2683.	Garcia-Martinez, Santes, et al., 1991	Program: not specified
Capillary	Methyl Silicone	2687.	Garcia-Martinez, Santes, et al., 1991	Program: not specified

References

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Ridoutt, Pharis, et al., 1995
Ridoutt, B.G.; Pharis, R.P.; Sands, R., Identification and quantification of cambial region hormones of Eucalyptus globulus, Plant Cell Physiol., 1995, 36, 6, 1143-1147. [all data]

Santes, Hedden, et al., 1995
Santes, C.M.; Hedden, P.; Gaskin, P.; Garcia-Martinez, J.L., Gibberellins and related compounds in young fruits of pea and their relationship to fruit-set, Phytochemistry, 1995, 40, 5, 1347-1355, https://doi.org/10.1016/0031-9422(95)00489-T . [all data]

Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P., Chromatography of gibberellins, J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3 . [all data]

Fos, Nuez, et al., 2000
Fos, M.; Nuez, F.; Garcia-Martinez, J.L., The gene pat-2, which induces natural partenocarpy, alters the gibberellin content in unpollinated tomato ovaries, Plant Physiol., 2000, 122, 2, 471-479, https://doi.org/10.1104/pp.122.2.471 . [all data]

Garcia-Martinez, Santes, et al., 1991
Garcia-Martinez, J.L.; Santes, C.; Croker, S.J.; Hedden, P., Identification, quantitation and distribution of gibberellins in fruits of Pisum sativum L. cv. Alaska during pod development, Planta, 1991, 184, 1, 53-60, https://doi.org/10.1007/BF00208236 . [all data]

Notes

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Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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