GA71, MeTMS
- Formula: C26H42O6Si2
- Molecular weight: 506.7791
- IUPAC Standard InChI: InChI=1S/C26H42O6Si2/c1-15-13-25-14-16(15)17(31-33(4,5)6)12-18(25)26-11-10-19(32-34(7,8)9)24(2,23(28)30-26)21(26)20(25)22(27)29-3/h16-21H,1,10-14H2,2-9H3/t16-,17-,18?,19+,20-,21?,24-,25+,26-/m0/s1
- IUPAC Standard InChIKey: YJIAMACEKPLATL-AFRSLNTBSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: GA71 methyl ester TMS ether; GA71, MeTMSi
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Ultra-2 | 2686. | Talon M., Koornneef M., et al., 1990 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 6C/min => 280C |
| Capillary | Ultra-2 | 2686. | Talon M., Koornneef M., et al., 1990 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 6C/min => 280C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2695. | Pearce, Koshioka, et al., 1994 | 15. m/0.22 mm/0.25 μm; Program: 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min |
| Capillary | OV-1 | 2693. | Kobayashi, Gaskin, et al., 1993 | 25. m/0.2 mm/0.25 μm; Program: 50C(2min) => 10C/min => 150C => 3C/min => 300C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 2683. | Yamane, Fujioka, et al., 1988 | 25. m/0.20 mm/0.25 μm; Program: not specified |
| Capillary | OV-1 | 2683. | Yamane, Fujioka, et al., 1988 | 25. m/0.20 mm/0.25 μm; Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Talon M., Koornneef M., et al., 1990
Talon M.; Koornneef M.; Zeevaart J.A.D.,
Accumulation of C19-gibberelins in the gibbrellin-insensitive dwarf mutant gai if Arabidopsis thaliana (L.) Heynh,
Planta, 1990, 182, 4, 501-505, https://doi.org/10.1007/BF02341024
. [all data]
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Kobayashi, Gaskin, et al., 1993
Kobayashi, M.; Gaskin, P.; Spray, C.R.; Suzuki, Y.; Phinney, B.O.; MacMillan, J.,
Metabolism and biological activity of Gibberellin A4 in vegetative shoots of Zea mays, Oryza sativa, and Arabidopsis thaliana,
Plant Physiol., 1993, 102, 379-386. [all data]
Yamane, Fujioka, et al., 1988
Yamane, H.; Fujioka, S.; Spray, C.R.; Phinney, B.O.; MacMillan, J.; Gaskin, P.; Takahashi, N.,
Endogenous Gibberellines from Sporophytes of Two Tree Ferns, Cibotium glaucum and Dicksonia antarctica,
Plant Phisiol., 1988, 86, 3, 857-862, https://doi.org/10.1104/pp.86.3.857
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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