GA62, MeTMS
- Formula: C23H32O5Si
- Molecular weight: 416.5827
- IUPAC Standard InChI: InChI=1S/C23H32O5Si/c1-13-11-22-12-14(13)7-8-15(22)23-16(28-29(4,5)6)9-10-21(2,20(25)27-23)18(23)17(22)19(24)26-3/h9-10,14-18H,1,7-8,11-12H2,2-6H3/t14-,15?,16-,17-,18?,21-,22+,23+/m0/s1
- IUPAC Standard InChIKey: OWKLDICCFUHXEP-CIDOZKHUSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: GA62 methyl ester TMS ether
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 2424. | Davis, Kobayashi, et al., 1999 | 25. m/0.2 mm/0.25 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | BP-1 | 2419. | MacMillan and Gaskin, 1996 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | DB-1 | 2439. | Pearce, Koshioka, et al., 1994 | 15. m/0.22 mm/0.25 μm; Program: 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min |
| Capillary | SE-52 | 2418. | Hedden, Hoad, et al., 1993 | 25. m/0.22 mm/0.25 μm, He; Program: 50C => 15C/min => 240C => 4C/min => 300C |
| Capillary | SE-52 | 2420. | Hedden, Hoad, et al., 1993 | 25. m/0.22 mm/0.25 μm, He; Program: 50C => 15C/min => 240C => 4C/min => 300C |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2422. | Oyama, Yamauchi, et al., 1996 | 160. C @ 2. min, 16. K/min; Column length: 15. m; Column diameter: 0.258 mm; Tend: 280. C |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Davis, Kobayashi, et al., 1999
Davis, G.; Kobayashi, M.; Phinney, B.O.; Lange, T.; Croker, S.J.; Gaskin, P.; MacMillan, J.,
Gibberellin biosynthesis in maize. Metabolic studies with GA15, GA24, GA25, GA7, and 2,3-dehydro-GA9,
Plant Physiol., 1999, 121, 3, 1037-1045, https://doi.org/10.1104/pp.121.3.1037
. [all data]
MacMillan and Gaskin, 1996
MacMillan, J.; Gaskin, P.,
Gibberellins in endosperm and embryos of Marah macrocarpus,
Phytochemistry, 1996, 42, 5, 1263-1266, https://doi.org/10.1016/0031-9422(96)00179-3
. [all data]
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Hedden, Hoad, et al., 1993
Hedden, P.; Hoad, G.V.; Gaskin, P.; Lewis, M.J.; Green, J.R.; Furber, M.; Mander, L.N.,
Kaurenoids and gibberellins, including the newly characterized gibberellin A88, in developing apple seeds,
Phytochemistry, 1993, 32, 2, 231-237, https://doi.org/10.1016/S0031-9422(00)94973-2
. [all data]
Oyama, Yamauchi, et al., 1996
Oyama, N.; Yamauchi, T.; Yamane, H.; Murofushi, N.; Agatsuma, M.; Pour, M.; Mander, L.N.,
Identification of gibberellins and 9,15-cyclogibberellins in developing apple seeds,
Biosci. Biotechnol. Biochem., 1996, 60, 2, 305-308, https://doi.org/10.1271/bbb.60.305
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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