GA53, MeTMS

• Formula: C₂₅H₄₀O₅Si
• Molecular weight: 448.6676
• IUPAC Standard InChI: InChI=1S/C25H40O5Si/c1-16-14-24-15-25(16,30-31(6,7)8)13-10-17(24)22(2)11-9-12-23(3,21(27)29-5)19(22)18(24)20(26)28-4/h17-19H,1,9-15H2,2-8H3/t17?,18-,19?,22+,23-,24+,25+/m0/s1 Copy

  
• IUPAC Standard InChIKey: TVWDMRKJNXNYSE-KAHVLJCKSA-N Copy
• Chemical structure:
  This structure is also available as a 2d Mol file
• Stereoisomers:
  • OH GA12-like, methyl ester TMS ether
• Other names: GA53, methyl ester TMS ether; Gibberellin GA53, methyl ester trimethylsilyl ether
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Van Den Dool and Kratz RI, non-polar column, custom temperature program
  • References
  • Notes
• Other data available:
  • Gas Chromatography
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Van Den Dool and Kratz RI, non-polar column, custom temperature program

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kim, Lee, et al., 2003
Kim, S.-K.; Lee, S.-C.; Shin, D.-H.; Jang, S.-W.; Nam, J.-W.; Park, T.-S.; Lee, I.-J., Quantification of endogenous gibberellins in leaves and tubers of Chinese yam, Dioscorea opposita Thunb. cv. Tsukune during tuber enlargement, Plant Growth Regul., 2003, 39, 2, 125-130, https://doi.org/10.1023/A:1022569506883 . [all data]

Kobayashi, MacMillan, et al., 2000
Kobayashi, M.; MacMillan, J.; Phinney, B.; Gaskin, P.; Spray, C.R.; Hedden, P., Gibberellin biosynthesis: metabolic evidence for three steps in the early 13-hydroxylation pathway of rice, Phytochemistry, 2000, 55, 4, 317-321, https://doi.org/10.1016/S0031-9422(00)00265-X . [all data]

Hisamatsu, Koshioka, et al., 1998
Hisamatsu, T.; Koshioka, M.; Kubota, S.; Nishijima, T.; Yamane, H.; King, R.W.; Mander, L.N., Isolation and identification of GA₁₁₂ (12β-hydroxy-GA₁₂) in Matthiola incana, Phytochemistry, 1998, 47, 1, 3-6, https://doi.org/10.1016/S0031-9422(97)00543-8 . [all data]

Webb, Appleford, et al., 1998
Webb, S.E.; Appleford, N.E.J.; Gaskin, P.; Lenton, J.R., Gibberellins in internodes and ears of wheat containing different dwarfing alleles, Phytochemistry, 1998, 47, 5, 671-677, https://doi.org/10.1016/S0031-9422(97)00684-5 . [all data]

Grünzweig, Rabinowitch, et al., 1997
Grünzweig, J.M.; Rabinowitch, H.D.; Katan, J.; Wodner, M.; Ben-Tal, Y., Endogenous gibberellins in foliage of tomato (Lycopersicon esculentum), Phytochemistry, 1997, 46, 5, 811-815, https://doi.org/10.1016/S0031-9422(97)00383-X . [all data]

Kappers, Jordi, et al., 1997
Kappers, I.F.; Jordi, W.; Maas, F.M.; van der Plas, L.H.W., Gibberellins in leaves of Alstroemeria hybrida: identification and quantification in relation to leaf age, J. Plant Growth Regul., 1997, 16, 4, 219-225, https://doi.org/10.1007/PL00007000 . [all data]

Rijnders, Yang, et al., 1997
Rijnders, J.G.H.M.; Yang, Y.-Y.; Kamiya, Y.; Takahashi, N.; Barendse, G.W.M.; Blom, C.W.P.M.; Voesenek, L.A.C.J., Ethylene enhances gibberellin levels and petiole sensitivity in flooding-tolerant Rumex palustris but not in flooding-intolerant R. acetosa, Planta, 1997, 203, 1, 20-25, https://doi.org/10.1007/s00050160 . [all data]

Kobayashi, Spray, et al., 1996
Kobayashi, M.; Spray, C.R.; Phinney, B.O.; Gaskin, P.; MacMillan, J., Gibberellin metabolism in maize. The stepwise conversion of gibberellin A₁₂-aldehyde to gibberellin A₂₀, Plant Physiol., 1996, 110, 413-418. [all data]

Talo, Spray, et al., 1995
Talo, A.; Spray, C.R.; Somers, D.A.; Donovan, C.M.; Gaskin, P.; Macmillian, J.; Phinney, B.O., Endogenous gibberellins from callus cultures of maize, Phytochemistry, 1995, 40, 1, 11-15, https://doi.org/10.1016/0031-9422(95)00000-W . [all data]

Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P., Chromatography of gibberellins, J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3 . [all data]

Hedden, Hoad, et al., 1993
Hedden, P.; Hoad, G.V.; Gaskin, P.; Lewis, M.J.; Green, J.R.; Furber, M.; Mander, L.N., Kaurenoids and gibberellins, including the newly characterized gibberellin A₈₈, in developing apple seeds, Phytochemistry, 1993, 32, 2, 231-237, https://doi.org/10.1016/S0031-9422(00)94973-2 . [all data]

Waycott, Smith, et al., 1991
Waycott, W.; Smith, V.A.; Gaskin, P.; MacMillan, J.; Taiz, L., The endogenous gibberellins of dwarf mutants of lettuce, Plant Physiol., 1991, 95, 4, 1169-1173, https://doi.org/10.1104/pp.95.4.1169 . [all data]

Heupel R.C., Phinney B.O., et al., 1985
Heupel R.C.; Phinney B.O.; Spray C.R.; Gaskin P.; MacMillan J.; Hedden P.; Graebe J.E., Native gibberellins and the metabolism of [14C] gibberellin A53 and of [17-C-13,17-3H)] gibberellin A-20 in tassels of Zea-mays, Phytochemistry, 1985, 24, 1, 47-53, https://doi.org/10.1016/S0031-9422(00)80805-5 . [all data]

Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, custom temperature program, References

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