GA43 methyl ester TMS ether
- Formula: C29H48O8Si2
- Molecular weight: 580.8576
- IUPAC Standard InChI: InChI=1S/C29H48O8Si2/c1-17-14-28-15-18(17)12-13-20(28)29(26(32)35-5)16-19(36-38(6,7)8)23(37-39(9,10)11)27(2,25(31)34-4)22(29)21(28)24(30)33-3/h18-23H,1,12-16H2,2-11H3/t18-,19+,20?,21-,22?,23+,27+,28+,29-/m0/s1
- IUPAC Standard InChIKey: UBBCCUZQBDRSGY-MIQKMETOSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: GA43, MeTMS; GA43, methyl ester TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | BP-1 | 2714. | MacMillan and Gaskin, 1996 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | OV-1 | 2722. | Santes, Hedden, et al., 1995 | 25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | OV-1 | 2723. | Santes, Hedden, et al., 1995 | 25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | DB-1 | 2725. | Pearce, Koshioka, et al., 1994 | 15. m/0.22 mm/0.25 μm; Program: 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2728. | Lange, Hedden, et al., 1993 | 25. m/0.32 mm/0.33 μm, He; Program: 50C(1min) => 20C/min => 240C => 4C/min => 295C |
| Capillary | BP-1 | 2744. | Lange, Hedden, et al., 1993, 2 | 25. m/0.25 mm/0.33 μm, He; Program: 60C(1min) => 20C/min => 240C => 4C/min => 300C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
MacMillan and Gaskin, 1996
MacMillan, J.; Gaskin, P.,
Gibberellins in endosperm and embryos of Marah macrocarpus,
Phytochemistry, 1996, 42, 5, 1263-1266, https://doi.org/10.1016/0031-9422(96)00179-3
. [all data]
Santes, Hedden, et al., 1995
Santes, C.M.; Hedden, P.; Gaskin, P.; Garcia-Martinez, J.L.,
Gibberellins and related compounds in young fruits of pea and their relationship to fruit-set,
Phytochemistry, 1995, 40, 5, 1347-1355, https://doi.org/10.1016/0031-9422(95)00489-T
. [all data]
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Lange, Hedden, et al., 1993
Lange, T.; Hedden, P.; Graebe, J.E.,
Biosynthesis of 12α- and 13-hydroxylated gibberellins in a cell-free system from Cucurbita maxima endosperm and the identification of new endogenous gibberellins,
Planta, 1993, 189, 3, 340-349, https://doi.org/10.1007/BF00194430
. [all data]
Lange, Hedden, et al., 1993, 2
Lange, T.; Hedden, P.; Graebe, J.E.,
Gibberellin biosynthesis in cell-free extracts from developing Cucurbita maxima embryos and the identification of new endogenous gibberellins,
Planta, 1993, 189, 3, 350-358, https://doi.org/10.1007/BF00194431
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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