GA37, MeTMS
- Formula: C24H36O5Si
- Molecular weight: 432.6251
- IUPAC Standard InChI: InChI=1S/C24H36O5Si/c1-14-11-24-12-15(14)7-8-16(24)23-10-9-17(29-30(4,5)6)22(2,21(26)28-13-23)19(23)18(24)20(25)27-3/h15-19H,1,7-13H2,2-6H3/t15-,16?,17+,18-,19?,22-,23-,24+/m0/s1
- IUPAC Standard InChIKey: OLGFJVXOAJRNEZ-KTRYJUSISA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: GA37, methyl ester TMS; Gibberellin GA37, methyl ester trimethylsilyl ether; GA37 methyl ester TMS ether
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Ultra-2 | 2763. | Talon M., Koornneef M., et al., 1990 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 6C/min => 280C |
| Capillary | Ultra-2 | 2763. | Talon, Koornneef, et al., 1990 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 6C/min => 280C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | PE-1HT | 2739. | Frisse, Pimenta, et al., 2003 | 30. m/0.32 mm/0.1 μm, He; Program: 60C => 45C/min => 220C => 4C/min => 300C |
| Capillary | DB-1 | 2759. | Hisamatsu, Koshioka, et al., 1998 | 15. m/0.25 mm/0.33 μm; Program: 120(2min) => (16C/min) => 216(5min) => (8C/min) => 280C |
| Capillary | BP-1 | 2753. | MacMillan and Gaskin, 1996 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | DB-1 | 2773. | Pearce, Koshioka, et al., 1994 | 15. m/0.22 mm/0.25 μm; Program: 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2732. | Nishijima, Murakami, et al., 1993 | 15; Column diameter: 0.257 mm; Phase thickness: 0.25 μm; Program: not specified |
| Capillary | OV-1 | 2747. | Yamane, Fujioka, et al., 1988 | 25. m/0.20 mm/0.25 μm; Program: not specified |
| Capillary | OV-1 | 2747. | Yamane, Fujioka, et al., 1988 | 25. m/0.20 mm/0.25 μm; Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Talon M., Koornneef M., et al., 1990
Talon M.; Koornneef M.; Zeevaart J.A.D.,
Accumulation of C19-gibberelins in the gibbrellin-insensitive dwarf mutant gai if Arabidopsis thaliana (L.) Heynh,
Planta, 1990, 182, 4, 501-505, https://doi.org/10.1007/BF02341024
. [all data]
Talon, Koornneef, et al., 1990
Talon, M.; Koornneef, M.; Zeevaart, J.A.D.,
Endogenous gibberellins in Arabidopsis thaliana and possible steps blocked in the biosynthetic pathways of the semidwarf ga4 and ga5 mutants,
Proc. Nat. Acad. Sci. U.S.A., 1990, 87, 20, 7983-7987, https://doi.org/10.1073/pnas.87.20.7983
. [all data]
Frisse, Pimenta, et al., 2003
Frisse, A.; Pimenta, M.J.; Lange, T.,
Expression studies of gibberellin oxidases in developing pumpkin seeds,
Plant Physiol., 2003, 131, 3, 1220-1227, retrieved from http://www.plantphysiol.org, https://doi.org/10.1104/pp.015206
. [all data]
Hisamatsu, Koshioka, et al., 1998
Hisamatsu, T.; Koshioka, M.; Kubota, S.; Nishijima, T.; Yamane, H.; King, R.W.; Mander, L.N.,
Isolation and identification of GA112 (12β-hydroxy-GA12) in Matthiola incana,
Phytochemistry, 1998, 47, 1, 3-6, https://doi.org/10.1016/S0031-9422(97)00543-8
. [all data]
MacMillan and Gaskin, 1996
MacMillan, J.; Gaskin, P.,
Gibberellins in endosperm and embryos of Marah macrocarpus,
Phytochemistry, 1996, 42, 5, 1263-1266, https://doi.org/10.1016/0031-9422(96)00179-3
. [all data]
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Nishijima, Murakami, et al., 1993
Nishijima, T.; Murakami, F.; Koshioka, M.; Yamazaki, H.,
Endogenous gibberellins in Aralia cordata,
Japan Society for Biosci. Biotechnol. Agrochem., 1993, 57, 1, 1953-1954, https://doi.org/10.1271/bbb.57.1953
. [all data]
Yamane, Fujioka, et al., 1988
Yamane, H.; Fujioka, S.; Spray, C.R.; Phinney, B.O.; MacMillan, J.; Gaskin, P.; Takahashi, N.,
Endogenous Gibberellines from Sporophytes of Two Tree Ferns, Cibotium glaucum and Dicksonia antarctica,
Plant Phisiol., 1988, 86, 3, 857-862, https://doi.org/10.1104/pp.86.3.857
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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