GA2, Me-TMS
- Formula: C26H44O6Si2
- Molecular weight: 508.7950
- IUPAC Standard InChI: InChI=1S/C26H44O6Si2/c1-23(32-34(7,8)9)15-25-14-16(23)10-11-17(25)26-13-12-18(31-33(4,5)6)24(2,22(28)30-26)20(26)19(25)21(27)29-3/h16-20H,10-15H2,1-9H3/t16-,17?,18+,19?,20?,23-,24-,25-,26-/m0/s1
- IUPAC Standard InChIKey: UNSOQWMOWIREFY-WGYAJBHMSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: GA2 methyl ester TMS ether; GA2, MeTMSi
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2761. | Pearce, Koshioka, et al., 1994 | 15. m/0.22 mm/0.25 μm; Program: 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min |
| Capillary | OV-1 | 2762. | Kobayashi, Gaskin, et al., 1993 | 25. m/0.2 mm/0.25 μm; Program: 50C(2min) => 10C/min => 150C => 3C/min => 300C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2745. | Koshioka, Nishijama, et al., 1995 | 15. m/0.25 mm/0.25 μm; Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Kobayashi, Gaskin, et al., 1993
Kobayashi, M.; Gaskin, P.; Spray, C.R.; Suzuki, Y.; Phinney, B.O.; MacMillan, J.,
Metabolism and biological activity of Gibberellin A4 in vegetative shoots of Zea mays, Oryza sativa, and Arabidopsis thaliana,
Plant Physiol., 1993, 102, 379-386. [all data]
Koshioka, Nishijama, et al., 1995
Koshioka, M.; Nishijama, T.; Mander, L.N.,
Gibberellin metabolism in suspension cultured cells of Raphanus Sativus,
Phytochemistry, 1995, 38, 2, 359-363, https://doi.org/10.1016/0031-9422(94)00624-3
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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