GA13, MeTMS
- Formula: C26H40O7Si
- Molecular weight: 492.6771
- IUPAC Standard InChIKey: KCLVZLRNSUVMTD-LNNHUYSYSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: GA13 methyl ester TMS ether; GA13, methyl ester TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Ultra-2 | 2567. | Talon M., Koornneef M., et al., 1990 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 6C/min => 280C |
Capillary | Ultra-2 | 2564. | Talon, Koornneef, et al., 1990 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 6C/min => 280C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | PE-1HT | 2586. | Frisse, Pimenta, et al., 2003 | 30. m/0.32 mm/0.1 μm, He; Program: 60C => 45C/min => 220C => 4C/min => 300C |
Capillary | BP-1 | 2596. | MacMillan and Gaskin, 1996 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
Capillary | OV-1 | 2592. | Santes, Hedden, et al., 1995 | 25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
Capillary | OV-1 | 2596. | Santes, Hedden, et al., 1995 | 25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
Capillary | DB-1 | 2597. | Pearce, Koshioka, et al., 1994 | 15. m/0.22 mm/0.25 μm; Program: 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-1 | 2614. | Lange, Hedden, et al., 1993 | 25. m/0.32 mm/0.33 μm, He; Program: 50C(1min) => 20C/min => 240C => 4C/min => 295C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Talon M., Koornneef M., et al., 1990
Talon M.; Koornneef M.; Zeevaart J.A.D.,
Accumulation of C19-gibberelins in the gibbrellin-insensitive dwarf mutant gai if Arabidopsis thaliana (L.) Heynh,
Planta, 1990, 182, 4, 501-505, https://doi.org/10.1007/BF02341024
. [all data]
Talon, Koornneef, et al., 1990
Talon, M.; Koornneef, M.; Zeevaart, J.A.D.,
Endogenous gibberellins in Arabidopsis thaliana and possible steps blocked in the biosynthetic pathways of the semidwarf ga4 and ga5 mutants,
Proc. Nat. Acad. Sci. U.S.A., 1990, 87, 20, 7983-7987, https://doi.org/10.1073/pnas.87.20.7983
. [all data]
Frisse, Pimenta, et al., 2003
Frisse, A.; Pimenta, M.J.; Lange, T.,
Expression studies of gibberellin oxidases in developing pumpkin seeds,
Plant Physiol., 2003, 131, 3, 1220-1227, retrieved from http://www.plantphysiol.org, https://doi.org/10.1104/pp.015206
. [all data]
MacMillan and Gaskin, 1996
MacMillan, J.; Gaskin, P.,
Gibberellins in endosperm and embryos of Marah macrocarpus,
Phytochemistry, 1996, 42, 5, 1263-1266, https://doi.org/10.1016/0031-9422(96)00179-3
. [all data]
Santes, Hedden, et al., 1995
Santes, C.M.; Hedden, P.; Gaskin, P.; Garcia-Martinez, J.L.,
Gibberellins and related compounds in young fruits of pea and their relationship to fruit-set,
Phytochemistry, 1995, 40, 5, 1347-1355, https://doi.org/10.1016/0031-9422(95)00489-T
. [all data]
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Lange, Hedden, et al., 1993
Lange, T.; Hedden, P.; Graebe, J.E.,
Biosynthesis of 12α- and 13-hydroxylated gibberellins in a cell-free system from Cucurbita maxima endosperm and the identification of new endogenous gibberellins,
Planta, 1993, 189, 3, 340-349, https://doi.org/10.1007/BF00194430
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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