β-Mannopyranose, TMS
- Formula: C21H52O6Si5
- Molecular weight: 541.0615
- IUPAC Standard InChI: InChI=1S/C21H52O6Si5/c1-28(2,3)22-16-17-18(24-29(4,5)6)19(25-30(7,8)9)20(26-31(10,11)12)21(23-17)27-32(13,14)15/h17-21H,16H2,1-15H3/t17-,18-,19+,20+,21+/m0/s1
- IUPAC Standard InChIKey: PPFHNIVPOLWPCF-WRTQPQOASA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- α-D-Mannopyranose, 5TMS derivative
- β-D-Glucopyranose, 5TMS derivative
- α-D-Glactopyranose, 5TMS derivative
- β-Galactopyranose, TMS
- α-D-Glucopyranose, 5TMS derivative
- α-D-Galactose, TMS
- β-Gulopyranose, TMS
- [2H]Mannose, TMS
- Galactose, TMS
- A-Psicopyranose, TMS
- A-Sorbopyranose, TMS
- B-Psicopyranose, TMS
- B-Sorbopyranose, TMS
- α-Mannose, TMS
- α-Mannopyranose, TMS
- D(+)-Talose, aldol, TMS
- D-Altrose, aldol, TMS
- α-Allopyranose, TMS
- α-Altropyranose, TMS
- α-Gulopyranose, TMS
- α-Idopyranose, TMS
- α-Talopyranose, TMS
- β-Allopyranose, TMS
- β-Altropyranose, TMS
- β-Idopyranose, TMS
- β-Talopyranose, TMS
- D-Glucopyranose, penta-TMS
- α-Glucopyranoside, TMS
- Glucose, TMS # 2
- β-D-(+)-Mannopyranose, 5TMS derivative
- D-(+)-Galactopyranose, 5TMS derivative (isomer 1)
- D-(+)-Galactopyranose, 5TMS derivative (isomer 2)
- β-D-Allopyranose, 5TMS derivative
- α-D-(+)-Talopyranose, 5TMS derivative
- β-D-(+)-Talopyranose, 5TMS derivative
- α-D-Allopyranose, 5TMS derivative
- Other names: β-Mannose, TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | SE-54 | 180. | 1937. | Martinez-Castro, Paez, et al., 1989 | Supelcoport; Column length: 40. m; Column diameter: 0.18 mm |
| Packed | SE-30 | 210. | 1945. | Saura-Calixto, Cañellas, et al., 1984 | N2, Supelcoport (80-100mesh); Column length: 3. m |
Kovats' RI, polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | Carbowax 20M | 160. | 1862. | Martinez-Castro, Paez, et al., 1989 | Chrompack; Column length: 25. m; Column diameter: 0.22 mm |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinez-Castro, Paez, et al., 1989
Martinez-Castro, I.; Paez, M.I.; Sanz, J.; Garcia-Raso, A.,
Gas Chromatographic Behaviour of Carbohydrate Trimethylsilyl Ethers. II. Aldohexoses,
J. Chromatogr., 1989, 462, 49-60, https://doi.org/10.1016/S0021-9673(00)91335-9
. [all data]
Saura-Calixto, Cañellas, et al., 1984
Saura-Calixto, F.; Cañellas, J.; García-Raso, A.,
Gas chromatograph analysis of surgars and sugar-alcohols in the mesocarp, endocarp, and kernel of almond fruit,
J. Agric. Food Chem., 1984, 32, 5, 1018-1020, https://doi.org/10.1021/jf00125a017
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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