Glucose, MO-TMS, II
- Formula: C22H55NO6Si5
- Molecular weight: 570.1027
- IUPAC Standard InChI: InChI=1S/C22H55NO6Si5/c1-24-23-17-19(26-31(5,6)7)21(28-33(11,12)13)22(29-34(14,15)16)20(27-32(8,9)10)18-25-30(2,3)4/h17,19-22H,18H2,1-16H3/t19-,20+,21+,22+/m0/s1
- IUPAC Standard InChIKey: LLVFXXKDPAPSCJ-DXBBTUNJSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Species with the same structure:
- Stereoisomers:
- d-Mannose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, o-methyloxyme, (1E)-
- d-Galactose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, o-methyloxyme, (1E)-
- d-Mannose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, o-methyloxyme, (1Z)-
- d-Galactose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, o-methyloxyme, (1Z)-
- d-Glucose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, o-methyloxyme, (1Z)-
- d-Glucose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, o-methyloxyme, (1E)-
- galactose methoxyamine, TMS
- Galactose, MO-TMS, I
- Galactose, MO-TMS, II
- MANNOSE MEOX 5TMS-1
- MANNOSE MEOX 5TMS-2
- Galactose, MEOX-5TMS
- Mannose, MEOX-5TMS
- D-(+)-Talose, pentakis(trimethylsilyl) ether, methyloxime (syn)
- D-(+)-Talose, pentakis(trimethylsilyl) ether, methyloxime (anti)
- D-Allose, pentakis(trimethylsilyl) ether, methyloxime (syn)
- D-Allose, pentakis(trimethylsilyl) ether, methyloxime (anti)
- Other names: GLUCOSE (MEOX 5TMS)-2; Glucose, 1-MO, 5TMS, MP
- Information on this page:
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-5MS | 1904.5 | Jonsson, Johansson, et al., 2005 | 10. m/0.18 mm/0.18 μm, 70. C @ 2. min, 40. K/min, 320. C @ 2. min |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Polydimethyl siloxane with 5 % phenyl groups | 1881. | Kempa, Hummel, et al., 2009 | Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Jonsson, Johansson, et al., 2005
Jonsson, P.; Johansson, A.I.; Gullberg, J.; Trygg, J.; Jiye, A.; Grung, B.; Marklund, S.; Sjöström, M.; Antti, H.; Moritz, T.,
High-throughput data analysis for detecting and identifying differences between samples in GC/MS-based metabolomic analyses,
Anal. Chem., 2005, 77, 17, 5635-5642, https://doi.org/10.1021/ac050601e
. [all data]
Kempa, Hummel, et al., 2009
Kempa, S.; Hummel, J.; Schwemmer, T.; Pietzke, M.; Strehmel, N.; Wienkoop, S.; Kopka, J.; Weckwerth, W.,
An automated GCxGC-TOF-MS protocol for batch-wise extraction and alinmebt of mass isotopomer matrixes from differential 13C-labeling experiments: a case study for photoautotrophic-mixotrophic grown Chlamydomonas reinhardtii cells,
J. Basic Microbiol., 2009, 49, 1, 82-91, https://doi.org/10.1002/jobm.200800337
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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