ent-6α,7α-Dihydroxy-kaurenoic acid, Me-TMS
- Formula: C27H48O4Si2
- Molecular weight: 492.8386
- IUPAC Standard InChI: InChI=1S/C27H48O4Si2/c1-18-16-27-17-19(18)12-13-20(27)25(2)14-11-15-26(3,24(28)29-4)22(25)21(30-32(5,6)7)23(27)31-33(8,9)10/h19-23H,1,11-17H2,2-10H3/t19?,20-,21-,22-,23-,25-,26+,27-/m0/s1
- IUPAC Standard InChIKey: CKTNFGJOVXLXMW-CMXDAODCSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: ent-6α,7α-(OH)2 KA, MeTMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 2581. | Santes, Hedden, et al., 1995 | 25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | OV-1 | 2588. | Santes, Hedden, et al., 1995 | 25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Polydimethyl siloxane | 2582. | Fujioka, Yamane, et al., 1988 | 200. C @ 2. min, 5. K/min; Tend: 320. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | 5 % Phenyl methyl siloxane | 2593. | Davidson, Elliott, et al., 2003 | Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Santes, Hedden, et al., 1995
Santes, C.M.; Hedden, P.; Gaskin, P.; Garcia-Martinez, J.L.,
Gibberellins and related compounds in young fruits of pea and their relationship to fruit-set,
Phytochemistry, 1995, 40, 5, 1347-1355, https://doi.org/10.1016/0031-9422(95)00489-T
. [all data]
Fujioka, Yamane, et al., 1988
Fujioka, S.; Yamane, H.; Spray, C.R.; Gaskin, P.; Macmillan, J.; Phinney, B.O.; Takahashi, N.,
Qualitative and quantitative analyses of gibberellins in vegetative shoots of normal, dwarf-1, dwarf-2, dwarf-3, and dwarf-5 seedlings of Zea mays L.,
Plant Physiol., 1988, 88, 4, 1367-1372, https://doi.org/10.1104/pp.88.4.1367
. [all data]
Davidson, Elliott, et al., 2003
Davidson, S.E.; Elliott, R.C.; Helliwell, C.A.; Poole, A.T.; Reid, J.B.,
The PEa gene NA encodes ent-Kaurenoic acid oxidase,
Plant Physiol., 2003, 131, 1, 335-344, https://doi.org/10.1104/pp.012963
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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