Californine-M (nor-), acetylated
- Formula: C20H17NO5
- Molecular weight: 351.3527
- IUPAC Standard InChI: InChI=1S/C20H17NO5/c1-10(22)21-15-2-11-4-17-19(25-8-23-17)6-13(11)16(21)3-12-5-18-20(7-14(12)15)26-9-24-18/h4-7,15-16H,2-3,8-9H2,1H3
- IUPAC Standard InChIKey: HCMZTUUUKUXOFC-UHFFFAOYSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Californine-M (nor-) AC
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Cross-Linked Methylsilicone | 3090. | Paul and Maurer, 2003 | 12. m/0.2 mm/0.33 μm, He, 100. C @ 3. min, 30. K/min, 310. C @ 8. min |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Cross-Linked Methylsilicone | 3090. | Paul, Springer, et al., 2004 | 12. m/0.2 mm/0.33 μm, He, 100. C @ 3. min, 30. K/min, 310. C @ 8. min |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Paul and Maurer, 2003
Paul, L.D.; Maurer, H.H.,
Studies on the metabolism and toxicological detection of the Eschscholtzia californica alkaloids californine and protopine in urine using gas chromatography-mass spectrometry,
J. Chromatogr. B, 2003, 789, 1, 43-57, https://doi.org/10.1016/S1570-0232(03)00124-7
. [all data]
Paul, Springer, et al., 2004
Paul, L.D.; Springer, D.; Staack, R.F.; Kraemer, T.; Maurer, H.H.,
Cytochrome P450 isoenzymes involved in rat liver microsomal metabolism of californine and protopine,
Eur. J. Pharmacol., 2004, 485, 1-3, 69-79, https://doi.org/10.1016/j.ejphar.2003.11.051
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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