16α, 17-H2 (OH)2 GA12, MeTMS
- Formula: C28H50O6Si2
- Molecular weight: 538.8640
- IUPAC Standard InChI: InChI=1S/C28H50O6Si2/c1-25-14-11-15-26(2,24(30)32-4)22(25)21(23(29)31-3)27-16-19(12-13-20(25)27)28(17-27,34-36(8,9)10)18-33-35(5,6)7/h19-22H,11-18H2,1-10H3/t19?,20-,21+,22-,25-,26+,27+,28-/m1/s1
- IUPAC Standard InChIKey: ZZFWQNAQASSFEN-WIEZBTDDSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: 16α,17-di-(OH)-16,17-dihydroGA12, Me-TMS; 16α,17-H2(OH)2 GA12, MeTMSi
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 2789. | Santes, Hedden, et al., 1995 | 25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | OV-1 | 2789. | Santes, Hedden, et al., 1995 | 25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | SE-52 | 2784. | Hedden, Hoad, et al., 1993 | 25. m/0.22 mm/0.25 μm, He; Program: 50C => 15C/min => 240C => 4C/min => 300C |
| Capillary | SE-52 | 2785. | Hedden, Hoad, et al., 1993 | 25. m/0.22 mm/0.25 μm, He; Program: 50C => 15C/min => 240C => 4C/min => 300C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 2780. | Yamane, Fujioka, et al., 1988 | 25. m/0.20 mm/0.25 μm; Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Santes, Hedden, et al., 1995
Santes, C.M.; Hedden, P.; Gaskin, P.; Garcia-Martinez, J.L.,
Gibberellins and related compounds in young fruits of pea and their relationship to fruit-set,
Phytochemistry, 1995, 40, 5, 1347-1355, https://doi.org/10.1016/0031-9422(95)00489-T
. [all data]
Hedden, Hoad, et al., 1993
Hedden, P.; Hoad, G.V.; Gaskin, P.; Lewis, M.J.; Green, J.R.; Furber, M.; Mander, L.N.,
Kaurenoids and gibberellins, including the newly characterized gibberellin A88, in developing apple seeds,
Phytochemistry, 1993, 32, 2, 231-237, https://doi.org/10.1016/S0031-9422(00)94973-2
. [all data]
Yamane, Fujioka, et al., 1988
Yamane, H.; Fujioka, S.; Spray, C.R.; Phinney, B.O.; MacMillan, J.; Gaskin, P.; Takahashi, N.,
Endogenous Gibberellines from Sporophytes of Two Tree Ferns, Cibotium glaucum and Dicksonia antarctica,
Plant Phisiol., 1988, 86, 3, 857-862, https://doi.org/10.1104/pp.86.3.857
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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