OH GA12-like, methyl ester TMS ether
- Formula: C25H40O5Si
- Molecular weight: 448.6676
- IUPAC Standard InChI: InChI=1S/C25H40O5Si/c1-16-14-24-15-25(16,30-31(6,7)8)13-10-17(24)22(2)11-9-12-23(3,21(27)29-5)19(22)18(24)20(26)28-4/h17-19H,1,9-15H2,2-8H3/t17-,18+,19-,22-,23+,24-,25-/m1/s1
- IUPAC Standard InChIKey: TVWDMRKJNXNYSE-SCDURKMASA-N
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: [2H2]GA53, MeTMS; [2H2]GA53, MeTMSi
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | CP Sil 5 CB | 2556. | Blake, Taylor, et al., 2002 | 25. m/0.25 mm/0.25 μm, He; Program: 60C (1min) => 20C/min => 170C => 4C/min => 290C |
| Capillary | HP-1 | 2588. | Pearce, Hutt, et al., 2002 | Column length: 12. m; Column diameter: 0.22 mm; Program: 60C(0.5min) => 20C/min => 200C => 5C/min => 300C |
| Capillary | DB-5 | 2584. | Pearce, Hutt, et al., 2002 | Column length: 15. m; Column diameter: 0.25 mm; Program: 60C(0.5min) => 20C/min => 200C => 5C/min => 300C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Blake, Taylor, et al., 2002
Blake, P.S.; Taylor, J.M.; Finch-Savage, W.E.,
Identification of abscisic acid, indole-3-acetic acid, jasmonic acid, indole-3-acetonitrile, methyl jasmonate and gibberellins in developing, dormant and startified seeds of ash (Fraxinus excelsior),
Plant Growth Regul., 2002, 37, 2, 119-125, https://doi.org/10.1023/A:1020504610172
. [all data]
Pearce, Hutt, et al., 2002
Pearce, D.W.; Hutt, O.E.; Rood, S.B.; Mander, L.N.,
Gibberellins in shoots and developing capsules of Populus species,
Phytochemistry, 2002, 59, 6, 679-687, https://doi.org/10.1016/S0031-9422(02)00009-2
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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